Decane

Last updated
Decane
Decane-2D-Skeletal.svg
DecaneFull.png
Decane 3D ball.png
Names
Preferred IUPAC name
Decane [1]
Other names
Decyl hydride
Identifiers
3D model (JSmol)
1696981
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.004.262 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 204-686-4
MeSH decane
PubChem CID
RTECS number
  • HD6550000
UNII
UN number 2247
  • InChI=1S/C10H22/c1-3-5-7-9-10-8-6-4-2/h3-10H2,1-2H3 Yes check.svgY
    Key: DIOQZVSQGTUSAI-UHFFFAOYSA-N Yes check.svgY
  • CCCCCCCCCC
Properties
C10H22
Molar mass 142.286 g·mol−1
AppearanceColorless liquid
Odor Gasoline-like (in high concentrations)
Density 0.730 g mL−1
Melting point −30.5 to −29.2 °C; −22.8 to −20.6 °F; 242.7 to 243.9 K
Boiling point 173.8 to 174.4 °C; 344.7 to 345.8 °F; 446.9 to 447.5 K
log P 5.802
Vapor pressure 195 Pa [2]
2.1 nmol Pa−1 kg−1
-119.74·10−6 cm3/mol
Thermal conductivity 0.1381 W m−1 K−1 (300 K) [3]
1.411–1.412
Viscosity
  • 0.850 mPa·s (25 °C) [4]
  • 0.920 mPa·s (20 °C)
Thermochemistry
315.46 J K−1 mol−1
Std molar
entropy
(S298)
425.89 J K−1 mol−1
−302.1–−299.9 kJ mol−1
−6779.21–−6777.45 kJ mol−1
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Flammable, moderately toxic
GHS labelling:
GHS-pictogram-flamme.svg GHS-pictogram-silhouette.svg
Danger
H226, H302, H304, H305
P301+P310, P331
NFPA 704 (fire diamond)
NFPA 704.svgHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 2: Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Flash point between 38 and 93 °C (100 and 200 °F). E.g. diesel fuelInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
2
0
Flash point 46.0 °C (114.8 °F; 319.1 K)
210.0 °C (410.0 °F; 483.1 K)
Explosive limits 0.8–2.6%
Lethal dose or concentration (LD, LC):
  • >2 g kg−1(dermal, rabbit)
  • 601 mg/kg−1(oral, rat)
Safety data sheet (SDS) hazard.com
Related compounds
Related alkanes
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Decane is an alkane hydrocarbon with the chemical formula C10H22. Although 75 structural isomers are possible for decane, the term usually refers to the normal-decane ("n-decane"), with the formula CH3(CH2)8CH3. All isomers, however, exhibit similar properties and little attention is paid to the composition. [5] These isomers are flammable liquids. Decane is present in small quantities (less than 1%) in gasoline (petrol) and kerosene. [6] [7] Like other alkanes, it is a nonpolar solvent, and does not dissolve in water, and is readily combustible. Although it is a component of fuels, it is of little importance as a chemical feedstock, unlike a handful of other alkanes. [8]

Contents

Reactions

Decane undergoes combustion, just like other alkanes. In the presence of sufficient oxygen, it burns to form water and carbon dioxide.

2 C10H22 + 31 O2 → 20 CO2 + 22 H2O

With insufficient oxygen, carbon monoxide is also formed.

It can be manufactured in the laboratory without fossil fuels. [9]

Physical properties

It has a surface tension of 0.0238 N·m−1. [10]

See also

Related Research Articles

<span class="mw-page-title-main">Alkane</span> Type of saturated hydrocarbon compound

In organic chemistry, an alkane, or paraffin, is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. Alkanes have the general chemical formula CnH2n+2. The alkanes range in complexity from the simplest case of methane, where n = 1, to arbitrarily large and complex molecules, like pentacontane or 6-ethyl-2-methyl-5-(1-methylethyl) octane, an isomer of tetradecane.

<span class="mw-page-title-main">Aliphatic compound</span> Hydrocarbon compounds without aromatic rings

In organic chemistry, hydrocarbons are divided into two classes: aromatic compounds and aliphatic compounds. Aliphatic compounds can be saturated like hexane, or unsaturated, like hexene and hexyne. Open-chain compounds, whether straight or branched, and which contain no rings of any type, are always aliphatic. Cyclic compounds can be aliphatic if they are not aromatic.

<span class="mw-page-title-main">Alkene</span> Hydrocarbon compound containing one or more C=C bonds

In organic chemistry, an alkene, or olefin, is a hydrocarbon containing a carbon–carbon double bond. The double bond may be internal or in the terminal position. Terminal alkenes are also known as α-olefins.

<span class="mw-page-title-main">Hydrocarbon</span> Organic compound consisting entirely of hydrogen and carbon

In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic; their odor is usually faint, and may be similar to that of gasoline or lighter fluid. They occur in a diverse range of molecular structures and phases: they can be gases, liquids, low melting solids or polymers.

<span class="mw-page-title-main">Octane</span> Hydrocarbon compound with the formula C8H18

Octane is a hydrocarbon and an alkane with the chemical formula C8H18, and the condensed structural formula CH3(CH2)6CH3. Octane has many structural isomers that differ by the location of branching in the carbon chain. One of these isomers, 2,2,4-trimethylpentane (commonly called iso-octane), is used as one of the standard values in the octane rating scale.

<span class="mw-page-title-main">Heptane</span> Chemical compound

Heptane or n-heptane is the straight-chain alkane with the chemical formula H3C(CH2)5CH3 or C7H16. When used as a test fuel component in anti-knock test engines, a 100% heptane fuel is the zero point of the octane rating scale (the 100 point is 100% iso-octane). Octane number equates to the anti-knock qualities of a comparison mixture of heptane and iso-octane which is expressed as the percentage of iso-octane in heptane, and is listed on pumps for gasoline (petrol) dispensed globally.

<span class="mw-page-title-main">Isobutane</span> Chemical compound

Isobutane, also known as i-butane, 2-methylpropane or methylpropane, is a chemical compound with molecular formula HC(CH3)3. It is an isomer of butane. Isobutane is a colorless, odorless gas. It is the simplest alkane with a tertiary carbon atom. Isobutane is used as a precursor molecule in the petrochemical industry, for example in the synthesis of isooctane.

Undecane (also known as hendecane) is a liquid alkane hydrocarbon with the chemical formula CH3(CH2)9CH3. It is used as a mild sex attractant for various types of moths and cockroaches, and an alert signal for a variety of ants. It has 159 isomers.

<span class="mw-page-title-main">Pentane</span> Alkane with 5 carbon atoms

Pentane is an organic compound with the formula C5H12—that is, an alkane with five carbon atoms. The term may refer to any of three structural isomers, or to a mixture of them: in the IUPAC nomenclature, however, pentane means exclusively the n-pentane isomer, in which case pentanes refers to a mixture of them; the other two are called isopentane (methylbutane) and neopentane (dimethylpropane). Cyclopentane is not an isomer of pentane because it has only 10 hydrogen atoms where pentane has 12.

<span class="mw-page-title-main">Nonane</span> Chemical compound

Nonane is a linear alkane hydrocarbon with the chemical formula C9H20. It is a colorless, flammable liquid, occurring primarily in the component of the petroleum distillate fraction commonly called kerosene, which is used as a heating, tractor, and jet fuel. Nonane is also used as a solvent, distillation chaser, fuel additive, and a component in biodegradable detergents. It is also a minor component of diesel fuel.

<span class="mw-page-title-main">Propyne</span> Hydrocarbon compound (HC≡C–CH3)

Propyne (methylacetylene) is an alkyne with the chemical formula CH3C≡CH. It is a component of MAPD gas—along with its isomer propadiene (allene), which was commonly used in gas welding. Unlike acetylene, propyne can be safely condensed.

Dodecane (also known as dihexyl, bihexyl, adakane 12, or duodecane) is an oily liquid n-alkane hydrocarbon with the chemical formula C12H26 (which has 355 isomers).

The Fischer–Tropsch process (FT) is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen, known as syngas, into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperatures of 150–300 °C (302–572 °F) and pressures of one to several tens of atmospheres. The Fischer–Tropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons.

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The Glossary of fuel cell terms lists the definitions of many terms used within the fuel cell industry. The terms in this fuel cell glossary may be used by fuel cell industry associations, in education material and fuel cell codes and standards to name but a few.

<span class="mw-page-title-main">Butane</span> Organic compound

Butane is an alkane with the formula C4H10. Butane exists as two isomers, n-butane with connectivity CH3CH2CH2CH3 and iso-butane with the formula (CH3)3CH. Both isomers are highly flammable, colorless, easily liquefied gases that quickly vaporize at room temperature and pressure. Butanes are a trace components of natural gases (NG gases). The other hydrocarbons in NG include propane, ethane, and especially methane, which are more abundant. Liquefied petroleum gas is a mixture of propane and some butanes.

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<span class="mw-page-title-main">2,3-Dimethylpentane</span> Chemical compound

2,3-Dimethylpentane is an organic compound of carbon and hydrogen with formula C
7
H
16
, more precisely CH
3
CH(CH
3
)
CH(CH
3
)
CH
2
CH
3
: a molecule of pentane with methyl groups –CH
3
replacing hydrogen atoms on carbon atoms 2 and 3. It is an alkane, a fully saturated hydrocarbon; specifically, one of the isomers of heptane.

2-Methyloctane is a branched alkane hydrocarbon with the chemical formula C9H20. It is a colorless, flammable liquid

References

  1. "decane - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 16 September 2004. Identification and Related Records. Retrieved 5 January 2012.
  2. Yaws, Carl L. (1999). Chemical Properties Handbook. New York: McGraw-Hill. pp. 159–179. ISBN   0-07-073401-1.
  3. Touloukian, Y.S., Liley, P.E., and Saxena, S.C. Thermophysical properties of matter - the TPRC data series. Volume 3. Thermal conductivity - nonmetallic liquids and gases. Data book. 1970.
  4. Dymond, J. H.; Oye, H. A. (1994). "Viscosity of Selected Liquid n-Alkanes". Journal of Physical and Chemical Reference Data. 23 (1): 41–53. Bibcode:1994JPCRD..23...41D. doi:10.1063/1.555943. ISSN   0047-2689.
  5. "75 Isomers of Decane". The Third Millennium Online! (in Latin). Retrieved 26 July 2021.
  6. "Petroleum - Chemistry Encyclopedia - reaction, water, uses, elements, examples, gas, number, name". www.chemistryexplained.com. Retrieved 2016-01-28.
  7. "n-Decane (Annotation)". Hazardous Substances Data Bank (HSDB). National Center for Biotechnology Information. Retrieved 7 July 2022.
  8. Griesbaum, Karl; Behr, Arno; Biedenkapp, Dieter; Voges, Heinz-Werner; Garbe, Dorothea; Paetz, Christian; Collin, Gerd; Mayer, Dieter; Höke, Hartmut (15 June 2000), "Hydrocarbons", Ullmann's Encyclopedia of Industrial Chemistry, Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, doi:10.1002/14356007.a13_227, ISBN   3527306730
  9. https://patents.google.com/patent/CN101987805A/en
  10. Website of Krüss Archived 2013-12-01 at the Wayback Machine (8.10.2009)