Woodhouseite | |
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General | |
Category | Phosphate minerals |
Formula (repeating unit) | CaAl3(SO4)(PO4)(OH)6 |
IMA symbol | Wdh [1] |
Strunz classification | 8.BL.05 |
Dana classification | 43.04.01.08 |
Crystal system | Trigonal |
Crystal class | Hexagonal scalenohedral (3 2/m) |
Space group | R3m (no. 166) |
Identification | |
Formula mass | 414.10 g/mol |
Color | White, flesh-pink or colorless |
Crystal habit | Crystals small, pseudocubic rhombohedral {1012}; tabular at times {0001}, with curved and striated faces. |
Cleavage | Excellent on {0001} |
Mohs scale hardness | 4.5 |
Luster | Vitreous, pearly on {0001} |
Streak | White |
Diaphaneity | Transparent to translucent |
Specific gravity | (measured): 3.012 (calculated): 3.00 |
Optical properties | Uniaxial (+), 2V = 0° to 20° |
Refractive index | (AM22) nω = 1.636 nε = 1.647 |
Birefringence | δ = 0.011 |
Solubility | Soluble in acids only after driving off the water in a closed tube. |
Other characteristics | Not radioactive. |
References | [2] [3] [4] |
Woodhouseite belongs to the beudantite group AB3(XO4)(SO4)(OH)6 where A = Ba, Ca, Pb or Sr, B = Al or Fe and X = S, As or P. Minerals in this group are isostructural with each other and also with minerals in the crandallite and alunite groups. They crystallise in the rhombohedral system with space group R3m and crystals are usually either tabular {0001} or pseudo-cubic to pseudo-cuboctahedral. Woodhouseite was named after Professor Charles Douglas Woodhouse [5] (1888–1975), an American mineralogist and mineral collector from the University of California, Santa Barbara, US, and one-time General Manager of Champion Sillimanite, Inc.
Woodhouseite is a secondary mineral found where wall rock alteration occurred in hydrothermal and disseminated ore deposits; rare in cave deposits, formed from guano. At the type locality it occurs in vugs in quartz veins in an andalusite, Al2OSiO4, deposit. This is in pre-Cambrian meta-quartzite that has been intruded by late Jurassic granitic rocks. Woodhouseite is found only near masses of lazulite, MgAl2(PO4)2(OH)2. Associated Minerals at the type locality include topaz, Al2SiO4F2, quartz, SiO2, augelite, Al2PO4(OH)3, lazulite, MgAl2(PO4)2(OH)2, tourmaline, baryte, BaSO4, muscovite, KAl2(Si3Al)O10(OH)2, and pyrophyllite, Al2Si4O10(OH)2, all of which formed before the woodhouseite, which is a late-forming mineral. [6]
The type locality is the Champion Mine (White Mountain Mine), White Mountain, Laws, White Mountains, Mono County, California, US. This is a former sillimanite mine located near Laws; mineralisation is a metamorphic sillimanite deposit hosted in quartzite.
Space Group: R3 2/m
Unit Cell Parameters: a = 6.993 Å, c = 16.386 Å, Z: 3
Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.
Lazulite ((Mg,Fe2+)Al2(PO4)2(OH)2) is a blue, phosphate mineral containing magnesium, iron, and aluminium phosphate. Lazulite forms one endmember of a solid solution series with the darker iron rich scorzalite.
Pumpellyite is a group of closely related sorosilicate minerals:
Robertsite, Ca3(Mn3+)4[(OH)3| (PO4)2]2·3(H2O) (alternatively formulated Ca2(Mn3(PO4)3O2)(H2O)3), is a secondary phosphate mineral named for Willard Lincoln Roberts (1923–1987), mineralogist and professor at South Dakota School of Mines in Rapid City, South Dakota.
Aheylite is a rare phosphate mineral with formula (Fe2+Zn)Al6[(OH)4|(PO4)2]2·4(H2O). It occurs as pale blue to pale green triclinic crystal masses. Aheylite was made the newest member of the turquoise group in 1984 by International Mineralogical Association Commission on New Minerals and Mineral Names.
Aliettite is a complex phyllosilicate mineral of the smectite group with a formula of (Ca0.2Mg6(Si,Al)8O20(OH)4·4H2O) or [Mg3Si4O10(OH)2](Ca0.5,Na)0.33(Al,Mg,Fe2+)2-3(Si,Al)4O10(OH)2·n(H2O).
Scorzalite ((Fe2+,Mg)Al2(OH,PO4)2) is a dark blue phosphate mineral containing iron, magnesium, and aluminium phosphate. Scorzalite forms one endmember of a solid solution series with the lighter, more magnesium-rich lazulite.
Gedrite is a crystal belonging to the orthorhombic ferromagnesian subgroup of the amphibole supergroup of the double chain inosilicate minerals with the ideal chemical formula Mg2(Mg3Al2)(Si6Al2)O22(OH)2.
Berlinite (aluminium phosphate, chemical formula AlPO4 or Al(PO4)) is a rare high-temperature hydrothermal or metasomatic phosphate mineral. It has the same crystal structure as quartz with a low temperature polytype isostructural with α–quartz and a high temperature polytype isostructural with β–quartz. Berlinite can vary from colorless to greyish or pale pink and has translucent crystals.
Dollaseite-(Ce) is a sorosilicate end-member epidote rare-earth mineral which was discovered by Per Geijer (1927) in the Ostanmossa mine, Norberg district, Sweden. Dollaseite-(Ce), although not very well known, is part of a broad epidote group of minerals which are primarily silicates, the most abundant type of minerals on earth. Dollaseite-(Ce) forms as dark-brown subhedral crystals primarily in Swedish mines. With the ideal chemical formula, CaREE3+
Mg
2AlSi
3O
11,(OH)F, dollaseite-(Ce) can be partially identified by its content of the rare earth element cerium.
Népouite is a rare nickel silicate mineral which has the apple green colour typical of such compounds. It was named by the French mining engineer Edouard Glasser in 1907 after the place where it was first described, the Népoui Mine, Népoui, Poya Commune, North Province, New Caledonia. The ideal formula is Ni3(Si2O5)(OH)4, but most specimens contain some magnesium, and (Ni,Mg)3(Si2O5)(OH)4 is more realistic. There is a similar mineral called lizardite in which all of the nickel is replaced by magnesium, formula Mg3(Si2O5)(OH)4. These two minerals form a series; intermediate compositions are possible, with varying proportions of nickel to magnesium.
Hureaulite is a manganese phosphate with the formula Mn2+5(PO3OH)2(PO4)2·4H2O. It was discovered in 1825 and named in 1826 for the type locality, Les Hureaux, Saint-Sylvestre, Haute-Vienne, Limousin, France. It is sometimes written as huréaulite, but the IMA does not recommend this for English language text.
Lulzacite is a strontium-containing phosphate mineral with the chemical formula Sr2Fe2+(Fe2+,Mg)2Al4(PO4)4(OH)10.
Whiteite is a rare hydrated hydroxyphosphate mineral.
Pimelite was discredited as a mineral species by the International Mineralogical Association (IMA) in 2006, in an article which suggests that “pimelite” specimens are probably willemseite, or kerolite. This was a mass discreditation, and not based on any re-examination of the type material. Nevertheless, a considerable number of papers have been written, verifying that pimelite is a nickel-dominant smectite. It is always possible to redefine a mineral wrongly discredited.
Minnesotaite is an iron silicate mineral with formula: (Fe2+,Mg)3Si4O10(OH)2. It crystallizes in the triclinic crystal system and occurs as fine needles and platelets with other silicates. It is isostructural with the pyrophyllite-talc mineral group.
Franklinphilite is a phyllosilicate of the stilpnomelane group. Known from only two localities It was found exclusively from the Franklin and Sterling Hill mines in Franklin, Sussex County, New Jersey. until 2013, when a locality in Wales was confirmed
Ferronigerite-2N1S is an iron, tin, alumino-hydroxide mineral that naturally occurs around sillimanite-quartz veins. Ferronigerite-2N1S belongs to the nigerite group, högbomite supergroup. The other constituents of the nigerite group are ferronigerite-6N6S, magnesionigerite-2N1S, magnesionigerite-6N6S, zinconigerite-2N1S and zinconigerite-6N6S. The 2N1S ending stands for the nolanite and spinel structural layers.