Lazulite

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Lazulite
Lazulite-tmix07-168a.jpg
Lazulite specimen found near Rapid Creek, Yukon, Canada
General
Category Phosphate mineral
Formula
(repeating unit)
(Mg,Fe2+)Al2(PO4)2(OH)2
IMA symbol Lzl [1]
Strunz classification 8.BB.40
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H–M symbol)
Space group P21/c
Unit cell a = 7.144(1), b = 7.278(1)
c = 7.228(1) [Å]; β = 120.5(1)°; Z = 2
Identification
Color Azure, sky blue, bluish white, yellow-green, blue-green, rarely green
Crystal habit Tabular, acute to stubby bipyramidal crystals; granular, massive
Twinning Common by several twin laws
Cleavage Poor to good on {110}, indistinct on {101}
Fracture Uneven, splintery
Tenacity Brittle
Mohs scale hardness5.5–6.0
Luster Vitreous
Streak White
Diaphaneity Transparent to translucent to nearly opaque
Specific gravity 3.122–3.240
Optical propertiesBiaxial (−)
Refractive index nα = 1.604–1.626
nβ = 1.626–1.654
nγ = 1.637–1.663
Birefringence δ = 0.033–0.037
Pleochroism Strong: X = colorless, Y = blue, Z = darker blue
2V angle Measured: 61–70°
Fusibility Infusible
Solubility Insoluble
References [2] [3] [4] [5]

Lazulite is a transparent to semi-opaque, blue mineral that is a phosphate of magnesium, iron, and aluminium, with the chemical formula (Mg,Fe2+)Al2(PO4)2(OH)2. [3] Lazulite forms one endmember of a solid solution series with the darker, iron-rich scorzalite. [3] [5]

Lazulite crystallizes in the monoclinic system. Its crystal habits include steep bipyramidal or wedge-shaped crystals. [6] Lazulite has a Mohs hardness of 5.5–6.0 and a specific gravity of 3.0–3.1. It is infusible and insoluble. [5]

Occurrence and discovery

Lazulite from Laila, Gilgit District, Gilgit-Baltistan, Pakistan. Size: 2.4 cm x 1.7 cm x 0.8 cm (0.94 in x 0.67 in x 0.31 in). Lazulite-dtn2a.jpg
Lazulite from Laila, Gilgit District, Gilgit-Baltistan, Pakistan. Size: 2.4 cm × 1.7 cm × 0.8 cm (0.94 in × 0.67 in × 0.31 in).

Lazulite forms by high-grade metamorphism of silica-rich rocks and in pegmatites. It occurs in association with quartz, andalusite, rutile, kyanite, corundum, muscovite, pyrophyllite, dumortierite, wagnerite, svanbergite and berlinite in metamorphic terrains; and with albite, quartz, muscovite, tourmaline and beryl in pegmatites. [2] It may be confused with lazurite, lapis lazuli or azurite.

The type locality is in Freßnitzgraben in Krieglach, it's also found in Salzburg, Austria; Zermatt, Switzerland; Minas Gerais, Brazil; Lincoln County, Georgia; Inyo County, California; the Yukon in Canada; and elsewhere.

It was first described in 1795 for deposits in Styria, Austria. [3] Its name comes from the German lazurstein, for 'blue stone' [2] or from the Arabic for heaven. [3] [5]

Related Research Articles

<span class="mw-page-title-main">Amblygonite</span>

Amblygonite is a fluorophosphate mineral, (Li,Na)AlPO4(F,OH), composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage and flame test for lithium are diagnostic. Amblygonite forms a series with montebrasite, the low fluorine endmember. Geologic occurrence is in granite pegmatites, high-temperature tin veins, and greisens. Amblygonite occurs with spodumene, apatite, lepidolite, tourmaline, and other lithium-bearing minerals in pegmatite veins. It contains about 10% lithium, and has been utilized as a source of lithium. The chief commercial sources have historically been the deposits of California and France.

<span class="mw-page-title-main">Kyanite</span> Aluminosilicate mineral

Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally indicates metamorphism deep in the Earth's crust. Kyanite is also known as disthene or cyanite.

<span class="mw-page-title-main">Muscovite</span> Hydrated phyllosilicate mineral

Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(AlSi3O10)(F,OH)2, or (KF)2(Al2O3)3(SiO2)6(H2O). It has a highly perfect basal cleavage yielding remarkably thin laminae (sheets) which are often highly elastic. Sheets of muscovite 5 meters × 3 meters (16.5 feet × 10 feet) have been found in Nellore, India.

<span class="mw-page-title-main">Pegmatite</span> Igneous rock with very large interlocked crystals

A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than 1 cm (0.4 in) and sometimes greater than 1 meter (3 ft). Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic composition to granite. However, rarer intermediate composition and mafic pegmatites are known.

<span class="mw-page-title-main">Lazurite</span> Alumino-silicate mineral whose blue colour is due to a sulfide species and not copper

Lazurite is a tectosilicate mineral with sulfate, sulfur and chloride with formula (Na,Ca)8[(S,Cl,SO4,OH)2|(Al6Si6O24)]. It is a feldspathoid and a member of the sodalite group. Lazurite crystallizes in the isometric system although well‐formed crystals are rare. It is usually massive and forms the bulk of the gemstone lapis lazuli.

<span class="mw-page-title-main">Lepidolite</span> Light micas with substantial lithium

Lepidolite is a lilac-gray or rose-colored member of the mica group of minerals with chemical formula K(Li,Al)3(Al,Si,Rb)4O10(F,OH)2. It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is the major source of the alkali metal rubidium.

<span class="mw-page-title-main">Nepheline</span> Silica-undersaturated aluminosilicate mineral

Nepheline, also called nephelite (from Ancient Greek νεφέλη (nephélē) 'cloud'), is a rock-forming mineral in the feldspathoid group – a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium.

<span class="mw-page-title-main">Vivianite</span> Phosphate mineral

Vivianite (Fe2+
3
(PO
4
)
2
·8H
2
O
) is a hydrated iron phosphate mineral found in a number of geological environments. Small amounts of manganese Mn2+, magnesium Mg2+, and calcium Ca2+ may substitute for iron Fe2+ in the structure. Pure vivianite is colorless, but the mineral oxidizes very easily, changing the color, and it is usually found as deep blue to deep bluish green prismatic to flattened crystals. Vivianite crystals are often found inside fossil shells, such as those of bivalves and gastropods, or attached to fossil bone. Vivianite can also appear on the iron coffins or on the corpses of humans as a result of a chemical reaction of the decomposing body with the iron enclosure.

<span class="mw-page-title-main">Jadeite</span> Pyroxene mineral

Jadeite is a pyroxene mineral with composition NaAlSi2O6. It is hard (Mohs hardness of about 6.5 to 7.0), very tough, and dense, with a specific gravity of about 3.4. It is found in a wide range of colors, but is most often found in shades of green or white. Jadeite is formed only in the subduction zones of continental margins, where rock undergoes metamorphism at high pressure but relatively low temperature.

<span class="mw-page-title-main">Brazilianite</span> Yellow-green phosphate mineral

Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.

<span class="mw-page-title-main">Dumortierite</span> Aluminum boro-silicate mineral

Dumortierite is a fibrous variably colored aluminium boro-silicate mineral, Al7BO3(SiO4)3O3. Dumortierite crystallizes in the orthorhombic system typically forming fibrous aggregates of slender prismatic crystals. The crystals are vitreous and vary in color from brown, blue, and green to more rare violet and pink. Substitution of iron and other tri-valent elements for aluminium result in the color variations. It has a Mohs hardness of 7 and a specific gravity of 3.3 to 3.4. Crystals show pleochroism from red to blue to violet. Dumortierite quartz is blue colored quartz containing abundant dumortierite inclusions.

<span class="mw-page-title-main">Pollucite</span> Zeolite mineral

Pollucite is a zeolite mineral with the formula (Cs,Na)2Al2Si4O12·2H2O with iron, calcium, rubidium and potassium as common substituting elements. It is important as a significant ore of caesium and sometimes rubidium. It forms a solid solution series with analcime. It crystallizes in the isometric-hexoctahedral crystal system as colorless, white, gray, or rarely pink and blue masses. Well-formed crystals are rare. It has a Mohs hardness of 6.5 and a specific gravity of 2.9. It has a brittle fracture and no cleavage.

<span class="mw-page-title-main">Zanazziite</span>

Zanazziite is a complex hydrated phosphate mineral from the roscherite group. It is a magnesium beryllium phosphate mineral. Zanazziite arises as barrel-shaped crystals and can reach up to 4 mm. It grows alongside quartz minerals. It is found in the crevices of Lavra da Ilha pegmatite, near Taquaral, in northeastern Minas Gerais, Brazil. Zanazziite is named after Pier F. Zanazzi. Zanazziite has an ideal chemical formula of Ca2Mg5Be4(PO4)6(OH)4·6H2O.

<span class="mw-page-title-main">Scorzalite</span>

Scorzalite ((Fe2+,Mg)Al2(OH,PO4)2) is a dark blue phosphate mineral containing iron, magnesium, and aluminium phosphate. Scorzalite forms one endmember of a solid solution series with the lighter, more magnesium-rich lazulite.

<span class="mw-page-title-main">Bazzite</span> Blue mineral

Bazzite is a beryllium scandium cyclosilicate mineral with chemical formula Be3Sc2Si6O18. It crystallizes in the hexagonal crystal system typically as small blue hexagonal crystals up to 2 cm length. It has a Mohs hardness of 6.5–7 and a specific gravity of 2.77 to 2.85.

<span class="mw-page-title-main">Eosphorite</span> Phosphate mineral

Eosphorite is a brown (occasionally pink) manganese hydrous phosphate mineral with chemical formula: MnAl(PO4)(OH)2·H2O. It is used as a gemstone.

<span class="mw-page-title-main">Berlinite</span>

Berlinite (aluminium phosphate, chemical formula AlPO4 or Al(PO4)) is a rare high-temperature hydrothermal or metasomatic phosphate mineral. It has the same crystal structure as quartz with a low temperature polytype isostructural with α–quartz and a high temperature polytype isostructural with β–quartz. Berlinite can vary from colorless to greyish or pale pink and has translucent crystals.

<span class="mw-page-title-main">Woodhouseite</span>

Woodhouseite belongs to the beudantite group AB3(XO4)(SO4)(OH)6 where A = Ba, Ca, Pb or Sr, B = Al or Fe and X = S, As or P. Minerals in this group are isostructural with each other and also with minerals in the crandallite and alunite groups. They crystallise in the rhombohedral system with space group R3m and crystals are usually either tabular {0001} or pseudo-cubic to pseudo-cuboctahedral. Woodhouseite was named after Professor Charles Douglas Woodhouse (1888–1975), an American mineralogist and mineral collector from the University of California, Santa Barbara, US, and one-time General Manager of Champion Sillimanite, Inc.

<span class="mw-page-title-main">Whiteite</span>

Whiteite is a rare hydrated hydroxyphosphate mineral.

<span class="mw-page-title-main">Foitite</span> Tourmaline mineral

Foitite is a mineral in the tourmaline group, it is a vacancy-dominant member of the group. Foitite is in the 'vacancy' group, due to the absence of atoms in the X site.

References

  1. Warr, L. N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine . 85 (3). Mineralogical Society of Great Britain and Ireland: 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 "Lazulite" (PDF). Handbook of Mineralogy. RRUFF. Archived (PDF) from the original on Jul 5, 2021.
  3. 1 2 3 4 5 Lazulite, Mindat.org
  4. Lazulite Mineral Data, WebMineral.com
  5. 1 2 3 4 Hurlbut, Cornelius S.; Klein, Cornelius (1985). Manual of Mineralogy (20th ed.). Wiley. ISBN   0-471-80580-7.
  6. "Lazulite". Minerals.net.