Lazulite | |
---|---|
General | |
Category | Phosphate mineral |
Formula (repeating unit) | (Mg,Fe2+)Al2(PO4)2(OH)2 |
IMA symbol | Lzl [1] |
Strunz classification | 8.BB.40 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | P21/c |
Unit cell | a = 7.144(1), b = 7.278(1) c = 7.228(1) [Å]; β = 120.5(1)°; Z = 2 |
Identification | |
Color | Azure-blue, sky-blue, bluish white, yellow-green, blue-green, rarely green |
Crystal habit | Tabular, acute to stubby bipyramidal crystals; granular, massive |
Twinning | Common by several twin laws |
Cleavage | Poor to good on {110}, indistinct on {101} |
Fracture | Uneven, splintery |
Tenacity | Brittle |
Mohs scale hardness | 5.5–6.0 |
Luster | Vitreous |
Streak | White |
Diaphaneity | Transparent to translucent to nearly opaque |
Specific gravity | 3.122–3.240 |
Optical properties | Biaxial (−) |
Refractive index | nα = 1.604 – 1.626 nβ = 1.626 – 1.654 nγ = 1.637 – 1.663 |
Birefringence | δ = 0.033 – 0.037 |
Pleochroism | Strong: X = colorless, Y = blue, Z = darker blue |
2V angle | Measured: 61° to 70° |
Fusibility | Infusible |
Solubility | Insoluble |
References | [2] [3] [4] [5] |
Lazulite ((Mg,Fe2+)Al2(PO4)2(OH)2) [3] is a blue, phosphate mineral containing magnesium, iron, and aluminium phosphate. Lazulite forms one endmember of a solid solution series with the darker iron rich scorzalite. [3] [5]
Lazulite crystallizes in the monoclinic system. Crystal habits include steep bipyramidal or wedge-shaped crystals. [6] Lazulite has a Mohs hardness of 5.5 to 6 and a specific gravity of 3.0 to 3.1. It is infusible and insoluble. [5]
It forms by high grade metamorphism of high silica quartz rich rocks and in pegmatites. It occurs in association with quartz, andalusite, rutile, kyanite, corundum, muscovite, pyrophyllite, dumortierite, wagnerite, svanbergite and berlinite in metamorphic terrains; and with albite, quartz, muscovite, tourmaline and beryl in pegmatites. [2] It may be confused with lazurite, lapis lazuli or azurite.
The type locality is in Freßnitzgraben in Krieglach, it's also found in Salzburg, Austria; Zermatt, Switzerland; Minas Gerais, Brazil; Lincoln County, Georgia; Inyo County, California; the Yukon in Canada; and elsewhere.
It was first described in 1795 for deposits in Styria, Austria. [3] Its name comes from the German lazurstein, for 'blue stone' [2] or from the Arabic for heaven. [3] [5]
Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally indicates metamorphism deep in the Earth's crust. Kyanite is also known as disthene or cyanite.
Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(AlSi3O10)(F,OH)2, or (KF)2(Al2O3)3(SiO2)6(H2O). It has a highly perfect basal cleavage yielding remarkably thin laminae (sheets) which are often highly elastic. Sheets of muscovite 5 meters × 3 meters (16.5 feet × 10 feet) have been found in Nellore, India.
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than 1 cm (0.4 in) and sometimes greater than 1 meter (3 ft). Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic composition to granite. However, rarer intermediate composition and mafic pegmatites are known.
Lazurite is a tectosilicate mineral with sulfate, sulfur and chloride with formula (Na,Ca)8[(S,Cl,SO4,OH)2|(Al6Si6O24)]. It is a feldspathoid and a member of the sodalite group. Lazurite crystallizes in the isometric system although well‐formed crystals are rare. It is usually massive and forms the bulk of the gemstone lapis lazuli.
Lepidolite is a lilac-gray or rose-colored member of the mica group of minerals with chemical formula K(Li,Al)3(Al,Si,Rb)4O10(F,OH)2. It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is the major source of the alkali metal rubidium.
Nepheline, also called nephelite (from Ancient Greek νεφέλη (nephélē) 'cloud'), is a rock-forming mineral in the feldspathoid group – a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium.
Vivianite (Fe2+
3(PO
4)
2·8H
2O) is a hydrated iron phosphate mineral found in a number of geological environments. Small amounts of manganese Mn2+, magnesium Mg2+, and calcium Ca2+ may substitute for iron Fe2+ in the structure. Pure vivianite is colorless, but the mineral oxidizes very easily, changing the color, and it is usually found as deep blue to deep bluish green prismatic to flattened crystals.
Vivianite crystals are often found inside fossil shells, such as those of bivalves and gastropods, or attached to fossil bone.
Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.
Dumortierite is a fibrous variably colored aluminium boro-silicate mineral, Al7BO3(SiO4)3O3. Dumortierite crystallizes in the orthorhombic system typically forming fibrous aggregates of slender prismatic crystals. The crystals are vitreous and vary in color from brown, blue, and green to more rare violet and pink. Substitution of iron and other tri-valent elements for aluminium result in the color variations. It has a Mohs hardness of 7 and a specific gravity of 3.3 to 3.4. Crystals show pleochroism from red to blue to violet. Dumortierite quartz is blue colored quartz containing abundant dumortierite inclusions.
Lithiophilite is a mineral containing the element lithium. It is lithium manganese(II) phosphate with chemical formula LiMnPO4. It occurs in pegmatites often associated with triphylite, the iron end member in a solid solution series. The mineral with intermediate composition is known as sicklerite and has the chemical formula Li(Mn,Fe)PO4). The name lithiophilite is derived from the Greek philos (φιλός) "friend", as lithiophilite is usually found with lithium.
Pollucite is a zeolite mineral with the formula (Cs,Na)2Al2Si4O12·2H2O with iron, calcium, rubidium and potassium as common substituting elements. It is important as a significant ore of caesium and sometimes rubidium. It forms a solid solution series with analcime. It crystallizes in the isometric–hexoctahedral crystal system as colorless, white, gray, or rarely pink and blue masses. Well formed crystals are rare. It has a Mohs hardness of 6.5 and a specific gravity of 2.9. It has a brittle fracture and no cleavage.
Zanazziite is a complex hydrated phosphate mineral from the roscherite group. It is a magnesium beryllium phosphate mineral. Zanazziite arises as barrel-shaped crystals and can reach up to 4 mm. It grows alongside quartz minerals. It is found in the crevices of Lavra da Ilha pegmatite, near Taquaral, in northeastern Minas Gerais, Brazil. Zanazziite is named after Pier F. Zanazzi. Zanazziite has an ideal chemical formula of Ca2Mg5Be4(PO4)6(OH)4·6H2O.
Scorzalite ((Fe2+,Mg)Al2(OH,PO4)2) is a dark blue phosphate mineral containing iron, magnesium, and aluminium phosphate. Scorzalite forms one endmember of a solid solution series with the lighter, more magnesium-rich lazulite.
Eosphorite is a brown (occasionally pink) manganese hydrous phosphate mineral with chemical formula: MnAl(PO4)(OH)2·H2O. It is used as a gemstone.
Berlinite (aluminium phosphate, chemical formula AlPO4 or Al(PO4)) is a rare high-temperature hydrothermal or metasomatic phosphate mineral. It has the same crystal structure as quartz with a low temperature polytype isostructural with α–quartz and a high temperature polytype isostructural with β–quartz. Berlinite can vary from colorless to greyish or pale pink and has translucent crystals.
Beraunite is an iron phosphate mineral. It was first described by August Breithaupt for an occurrence in Beraun currently in the Czech Republic. Beraunite occurs as a secondary mineral in iron ore deposits, and as an alteration product of primary phosphate minerals in granite pegmatites.
Whiteite is a rare hydrated hydroxyphosphate mineral.
Serrabrancaite is a mineral with the chemical formula MnPO4•H2O and which is named for the locality where it was found, the Alto Serra Branca Pegmatite. The Alto Serra Branca mine has been in operation since the 1940s. It is located in Paraiba, Brazil near a village named Pedra Lavrada. Tantalite is the main mineral mined here. Specimens of serrabrancaite are kept in the Mineralogical Collections of both the Bergakademie Freiberg, Germany and the Martin-Luther Universität Halle, Institut für Geologische Wissenschaften.
Kosnarite is an alkali zirconium phosphate mineral (KZr2(PO4)3) named after an expert of pegmatites Richard A. Kosnar. Kosnarite contains potassium, oxygen, phosphorus, and zirconium with sodium, rubidium, hafnium, manganese and fluorine (Na, Rb, Hf, Mn, and F) being common impurities found in kosnarite. It was discovered in nature for the first time in 1991 by Vandall T. King. Samples that were found in granitic pegmatites from the Mount Mica Quarry, Paris, Oxford County, Maine, USA were sent to Eugene E. Foord for study. This became the first recorded case of naturally occurring kosnarite.
Foitite is a mineral in the tourmaline group, it is a vacancy-dominant member of the group. Foitite is in the 'vacancy' group, due to the absence of atoms in the X site.