Corkite | |
---|---|
General | |
Category | Phosphate minerals |
Formula (repeating unit) | Pb Fe 3[(O H)6:SO4:PO4] |
IMA symbol | Cok [1] |
Strunz classification | 8.BL.05 |
Dana classification | 43.4.1.2 |
Crystal system | Trigonal |
Crystal class | Ditrigonal pyramidal (3/m) (same H-M symbol) |
Space group | R3m |
Unit cell | a = 7.3065(5) Å, c = 16.897(2) Å; V = 781.2 ų; Z = 3 |
Identification | |
Formula mass | 667.82 g/mol |
Color | Brown to light yellowish brown, pale yellow, yellowish green to dark green |
Crystal habit | Crystals pseudocubic rhombohedral with prominent {1011}. Commonly in crusts and massive |
Cleavage | Perfect on {0001} |
Mohs scale hardness | 3.5–4.5 |
Luster | Vitreous, resinous |
Diaphaneity | transparent |
Specific gravity | 4.295 (measured), 4.31 (calculated) |
Optical properties | Uniaxial (−), may appear anomalously biaxial |
Refractive index | nω = 1.930 nε = 1.930 n = 1.93 – 1.96 |
Birefringence | δ = 0.000 |
Other characteristics | Readily soluble in warm HCl |
References | [2] [3] [4] [5] [6] |
Corkite is a phosphate mineral in the beudantite subgroup of the alunite group. Corkite is the phosphate analogue of beudantite and with it, a complete solid solution range exists. Corkite will also form a solid solution with kintoreite.
Corkite is named after County Cork, Ireland; the location where the first notable amount was discovered in 1869. [3] Like many of the other minerals in the beudantite group, corkite is a relatively uncommon, secondary mineral that occurs in oxidation zones near hydrothermal base metal deposits. [3] It occurs associated with pyromorphite, malachite, plumbojarosite, limonite and quartz. [6]
Zinkenite is a steel-gray metallic sulfosalt mineral composed of lead antimony sulfide Pb9Sb22S42. Zinkenite occurs as acicular needle-like crystals.
Fayalite is the iron-rich end-member of the olivine solid-solution series. In common with all minerals in the olivine group, fayalite crystallizes in the orthorhombic system with cell parameters a 4.82 Å, b 10.48 Å and c 6.09 Å.
Tephroite is the manganese endmember of the olivine group of nesosilicate minerals with the formula Mn2SiO4. A solid solution series exists between tephroite and its analogues, the group endmembers fayalite and forsterite. Divalent iron or magnesium may readily replace manganese in the olivine crystal structure.
Adamite is a zinc arsenate hydroxide mineral, Zn2AsO4OH. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with copper substitutions in the mineral structure. Olivenite is a copper arsenate that is isostructural with adamite and there is considerable substitution between zinc and copper resulting in an intermediate called cuproadamite. Zincolivenite is a recently discovered mineral being an intermediate mineral with formula CuZn(AsO4)(OH). Manganese, cobalt, and nickel also substitute in the structure. An analogous zinc phosphate, tarbuttite, is known.
Diadochite is a phospho-sulfate mineral. It is a secondary mineral formed by the weathering and hydration of other minerals. Its formula is Fe2(PO4)(SO4)OH·5H2O. Well crystallized forms are referred to as destinezite, which has been given official recognition by the International Mineralogical Association with diadochite being the poorly formed to amorphous variety.
Warwickite is an iron magnesium titanium borate mineral with the chemical formula (MgFe)3Ti(O, BO3)2orMg(Ti,Fe3+, Al)(BO3)O. It occurs as brown to black prismatic orthorhombic crystals which are vitreous and transparent. It has a Mohs hardness of 3 to 4 and a specific gravity of 3.36.
Cerite is a complex silicate mineral group containing cerium, formula (Ce,La,Ca)
9(Mg,Fe3+
)(SiO
4)
6(SiO
3OH)(OH)
3. The cerium and lanthanum content varies with the Ce rich species and the La rich species. Analysis of a sample from the Mountain Pass carbonatite gave 35.05% Ce
2O
3 and 30.04% La
2O
3.
Beryllonite is a rare sodium beryllium phosphate mineral with formula NaBePO4. The tabular to prismatic monoclinic crystals vary from colorless to white or pale yellowish, and are transparent with a vitreous luster. Twinning is common and occurs in several forms. It exhibits perfect cleavage in one direction. The hardness is 5.5 to 6 and the specific gravity is 2.8. Refractive indices are nα = 1.552, nβ = 1.558 and nγ = 1.561. A few crystals have been cut and faceted, but, as the refractive index is no higher than that of quartz, they do not make very brilliant gemstones.
Libethenite is a rare copper phosphate hydroxide mineral. It forms striking, dark green orthorhombic crystals. It was discovered in 1823 in Ľubietová, Slovakia and is named after the German name of that locality (Libethen). Libethenite has also been found in the Miguel Vacas Mine, Conceição, Vila Viçosa, Évora District, Portugal, and in Tier des Carrières, Cahai, Vielsaim, Stavelot Massif, Luxembourg Province, Belgium.
Clausthalite is a lead selenide mineral, PbSe. It forms a solid solution series with galena PbS.
Hafnon is a hafnium nesosilicate mineral, chemical formula (Hf,Zr)SiO4 or (Hf,Zr,Th,U,Y)SiO4. In natural zircon ZrSiO4 part of the zirconium is replaced by the very similar hafnium and so natural zircon is never pure ZrSiO4. A zircon with 100% hafnium substitution can be made synthetically and is hafnon.
Gedrite is a crystal belonging to the orthorhombic ferromagnesian subgroup of the amphibole supergroup of the double chain inosilicate minerals with the ideal chemical formula Mg2(Mg3Al2)(Si6Al2)O22(OH)2.
Duftite is a relatively common arsenate mineral with the formula CuPb(AsO4)(OH), related to conichalcite. It is green and often forms botryoidal aggregates. It is a member of the adelite-descloizite Group, Conichalcite-Duftite Series. Duftite and conichalcite specimens from Tsumeb are commonly zoned in color and composition. Microprobe analyses and X-ray powder-diffraction studies indicate extensive substitution of Zn for Cu, and Ca for Pb in the duftite structure. This indicates a solid solution among conichalcite, CaCu(AsO4 )(OH), austinite, CaZn(AsO4)(OH) and duftite PbCu(AsO4)(OH), all of them belonging to the adelite group of arsenates. It was named after Mining Councilor G Duft, Director of the Otavi Mine and Railroad Company, Tsumeb, Namibia. The type locality is the Tsumeb Mine, Tsumeb, Otjikoto Region, Namibia.
Kaersutite is a dark brown to black double chain calcic titanium bearing amphibole mineral with formula: NaCa2(Mg3Ti4+Al)(Si6Al2)O22(O)2.
Bergenite is a rare uranyl phosphate of the more specific phosphuranylite group. The phosphuranylite-type sheet in bergenite is a new isomer of the group, with the uranyl phosphate tetrahedra varying in an up-up-down, same-same-opposite (uuduudSSOSSO) orientation. All bergenite samples have been found in old mine dump sites. Uranyl minerals are a large constituent of uranium deposits.
Cyrilovite (NaFe33+(PO4)2(OH)4·2(H2O)) is a hydrous sodium iron phosphate mineral. It is isomorphous and isostructural with wardite, the sodium aluminium counterpart.
Fluellite is a mineral with the chemical formula Al2(PO4)F2(OH)•7H2O. The name is from its chemical composition, being a fluate of alumine (French).
Banalsite is a rare barium, sodium aluminium silicate mineral with formula: BaNa2Al4Si4O16. Banalsite is a tectosilicate of the feldspar group.
Beudandite is a secondary mineral occurring in the oxidized zones of polymetallic deposits. It is a lead, iron, arsenate, sulfate with endmember formula: PbFe3(OH)6SO4AsO4.
Segnitite is a lead iron(III) arsenate mineral. Segnitite was first found in the Broken Hill ore deposit in Broken Hill, New South Wales, Australia. In 1991, segnitite was approved as a new mineral. Segnitite has since been found worldwide near similar locality types where rocks are rich in zinc and lead especially. it was named for Australian mineralogist, gemologist and petrologist Edgar Ralph Segnit. The mineral was named after E. R. Segnit due to his contributions to Australian mineralogy.