Titan was a family of United States expendable rockets used between 1959 and 2005. The Titan I and Titan II were part of the US Air Force's intercontinental ballistic missile (ICBM) fleet until 1987. The space launch vehicle versions contributed the majority of the 368 Titan launches, including all the Project Gemini crewed flights of the mid-1960s. Titan vehicles were also used to lift US military payloads as well as civilian agency reconnaissance satellites and to send interplanetary scientific probes throughout the Solar System.
Hydrazine is an inorganic compound with the chemical formula N2H4. It is a simple pnictogen hydride, and is a colourless flammable liquid with an ammonia-like odour. Hydrazine is highly toxic unless handled in solution as, for example, hydrazine hydrate.
A hypergolic propellant is a rocket propellant combination used in a rocket engine, whose components spontaneously ignite when they come into contact with each other.
A propellant is a mass that is expelled or expanded in such a way as to create a thrust or another motive force in accordance with Newton's third law of motion, and "propel" a vehicle, projectile, or fluid payload. In vehicles, the engine that expels the propellant is called a reaction engine. Although technically a propellant is the reaction mass used to create thrust, the term "propellant" is often used to describe a substance which contains both the reaction mass and the fuel that holds the energy used to accelerate the reaction mass. For example, the term "propellant" is often used in chemical rocket design to describe a combined fuel/propellant, although the propellants should not be confused with the fuel that is used by an engine to produce the energy that expels the propellant. Even though the byproducts of substances used as fuel are also often used as a reaction mass to create the thrust, such as with a chemical rocket engine, propellant and fuel are two distinct concepts.
Monomethylhydrazine is a highly toxic, volatile hydrazine derivative with the chemical formula CH6N2. It is used as a rocket propellant in bipropellant rocket engines because it is hypergolic with various oxidizers such as nitrogen tetroxide and nitric acid. As a propellant, it is described in specification MIL-PRF-27404.
RP-1 (alternatively, Rocket Propellant-1 or Refined Petroleum-1) is a highly refined form of kerosene outwardly similar to jet fuel, used as rocket fuel. RP-1 provides a lower specific impulse than liquid hydrogen (H2), but is cheaper, is stable at room temperature, and presents a lower explosion hazard. RP-1 is far denser than H2, giving it a higher energy density (though its specific energy is lower). RP-1 also has a fraction of the toxicity and carcinogenic hazards of hydrazine, another room-temperature liquid fuel.
A liquid-propellant rocket or liquid rocket utilizes a rocket engine burning liquid propellants. (Alternate approaches use gaseous or solid propellants.) Liquids are desirable propellants because they have reasonably high density and their combustion products have high specific impulse (Isp). This allows the volume of the propellant tanks to be relatively low.
Aerozine 50 is a 50:50 mix by weight of hydrazine and unsymmetrical dimethylhydrazine (UDMH), originally developed in the late 1950s by Aerojet General Corporation as a storable, high-energy, hypergolic fuel for the Titan II ICBM rocket engines. Aerozine continues in wide use as a rocket fuel, typically with dinitrogen tetroxide as the oxidizer, with which it is hypergolic. Aerozine 50 is more stable than hydrazine alone, and has a higher density and boiling point than UDMH alone.
The highest specific impulse chemical rockets use liquid propellants. They can consist of a single chemical or a mix of two chemicals, called bipropellants. Bipropellants can further be divided into two categories; hypergolic propellants, which ignite when the fuel and oxidizer make contact, and non-hypergolic propellants which require an ignition source.
Cora was a French experimental rocket. It was the largest rocket ever launched in Western Europe. It was primarily used for testing the second (Coralie) and third stages (Astris) of the multinational Europa Rocket, which was developed and produced by the European Launcher Development Organisation, the predecessor to the present day European Space Agency.
Dimethylamine is an organic compound with the formula (CH3)2NH. This secondary amine is a colorless, flammable gas with an ammonia-like odor. Dimethylamine is commonly encountered commercially as a solution in water at concentrations up to around 40%. An estimated 270,000 tons were produced in 2005.
Diethylenetriamine (abbreviated Dien or DETA) and also known as 2,2’-Iminodi(ethylamine)) is an organic compound with the formula HN(CH2CH2NH2)2. This colourless hygroscopic liquid is soluble in water and polar organic solvents, but not simple hydrocarbons. Diethylenetriamine is structural analogue of diethylene glycol. Its chemical properties resemble those for ethylene diamine, and it has similar uses. It is a weak base and its aqueous solution is alkaline. DETA is a byproduct of the production of ethylenediamine from ethylene dichloride.
Hydrazines (R2N−NR2) are a class of chemical compounds with two nitrogen atoms linked via a covalent bond and which carry from one up to four alkyl or aryl substituents. Hydrazines can be considered as derivatives of the inorganic hydrazine (H2N−NH2), in which one or more hydrogen atoms have been replaced by hydrocarbon groups.
Tonka is the name given to a German-designed rocket propellant first used in the Wasserfall missile, and recently used by North Korea. It was used in the Soviet Union under the name TG-02, for example in the engine designs of the A.M. Isayev Chemical Engineering Design Bureau.
Devil's venom was a nickname coined by Soviet rocket scientists for a liquid rocket fuel composed of a dangerous combination of red fuming nitric acid and a hydrazine derivative — specifically, hypergolic UDMH-nitric acid. Both propellants are extremely dangerous individually: Nitric acid is highly corrosive and causes offgassing of toxic nitrogen dioxide during reactions, or even simply while exposed to air in its highly concentrated "red fuming" form used as rocket propellant. UDMH is both toxic and corrosive. Despite these dangers, the pairing has been used in rocketry because this combination of fuel and oxidizer is hypergolic, which makes rockets using these materials simpler. Further, both the fuel and oxidizer have high boiling points compared to other rocket fuels and oxidizers, allowing rockets to be stored ready for launch for long periods without the fuel or oxidizer boiling off and needing to be replenished.
RD-270 (Russian: Раке́тный дви́гатель 270, Rocket Engine 270, 8D420) was a single-chamber liquid-bipropellant rocket engine designed by Energomash (USSR) in 1960–1970. It was to be used on the first stages of proposed heavy-lift UR-700 and UR-900 rocket families, as well as on the N1. It has the highest thrust among single-chamber engines of the USSR, 640 metric tons at the surface of Earth. The propellants used are unsymmetrical dimethylhydrazine (UDMH) and nitrogen tetroxide (N2O4). The chamber pressure was among the highest considered, being about 26 MPa. This was achieved by applying full-flow staged combustion cycle for all the incoming mass of fuel, which is turned into a gas and passes through multiple turbines before being burned in the combustion chamber. This allowed the engine to achieve a specific impulse of 301 s (2.95 km/s) at the Earth's surface.
Hydyne is a mixture of 60% unsymmetrical dimethylhydrazine (UDMH) and 40% diethylenetriamine (DETA), developed in 1957 at Rocketdyne for use in liquid-fuel rockets. Hydyne was used as the fuel for the first stage of the Juno I rocket that launched Explorer 1, the first successful satellite launch conducted by the United States.
The LR87 was an American liquid-propellant rocket engine used on the first stages of Titan intercontinental ballistic missiles and launch vehicles. Composed of twin motors with separate combustion chambers and turbopump machinery, it is considered a single unit and was never flown as a single combustion chamber engine or designed for this. The LR87 first flew in 1959.
Symmetrical dimethylhydrazine, or 1,2-dimethylhydrazine, is the organic compound with the formula (CH3NH)2. It is one of the two isomers of dimethylhydrazine. Both isomers are colorless liquids at room temperature, with properties similar to those of methylamines. Symmetrical dimethylhydrazine is a potent carcinogen that acts as a DNA methylating agent. The compound has no commercial value, in contrast to its isomer unsymmetrical dimethylhydrazine (1,1-dimethylhydrazine), which is used as a rocket fuel.
Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical rocket, or from an external source, as with ion engines.
