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C-Stoff ( [t͡seːʃtɔf] ; "substance C") was a reductant used in bipropellant rocket fuels (as a fuel itself) developed by Hellmuth Walter Kommanditgesellschaft in Germany during World War II. It was developed for use with T-Stoff (a high-test peroxide) as an oxidizer, which together with C-Stoff as the fuel, forms a hypergolic mixture.
Methanol | CH3OH | ~57% by weight |
Hydrazine hydrate | N2H4 · H2O | ~30% by weight |
Water | H2O | ~13% by weight |
Catalyst 431 | K3[Cu(CN)4] | potassium tetracyanocuprate(I) |
The proportions of the components in C-Stoff were developed to catalyse the decomposition of T-Stoff, promote combustion with the oxygen released by the decomposition, and sustain uniform combustion through sufficient quantity of the highly reactive hydrazine. The combination of the C-Stoff, used as a rocket fuel, with the T-Stoff used as the oxidizer, often resulted in spontaneous explosion from their combined nature as a hypergolic fuel combination, necessitating strict hygiene in fueling operations; there were numerous catastrophic explosions of the Messerschmitt Me 163 aircraft that employed this fuel system. Another hazard was toxicity to humans of each of the propellants. [1]
After the war, Allied studies into rocket propellants continued with engines such as the Armstrong Siddeley Beta, under the name "C-fuel".
A hybrid-propellant rocket is a rocket with a rocket motor that uses rocket propellants in two different phases: one solid and the other either gas or liquid. The hybrid rocket concept can be traced back to the early 1930s.
A hypergolic propellant is a rocket propellant combination used in a rocket engine, whose components spontaneously ignite when they come into contact with each other.
Unsymmetrical dimethylhydrazine (UDMH; 1,1-dimethylhydrazine, heptyl or codenamed Geptil) is a chemical compound with the formula H2NN(CH3)2 that is used as a rocket propellant. It is a colorless liquid, with a sharp, fishy, ammonia-like smell typical for organic amines. Samples turn yellowish on exposure to air and absorb oxygen and carbon dioxide. It is miscible with water, ethanol, and kerosene. In concentration between 2.5% and 95% in air, its vapors are flammable. It is not sensitive to shock. Symmetrical dimethylhydrazine (1,2-dimethylhydrazine) is also known but is not as useful. UDMH can be oxidized in air to form many different substances, including toxic ones.
Monopropellants are propellants consisting of chemicals that release energy through exothermic chemical decomposition. The molecular bond energy of the monopropellant is released usually through use of a catalyst. This can be contrasted with bipropellants that release energy through the chemical reaction between an oxidizer and a fuel. While stable under defined storage conditions, monopropellants decompose very rapidly under certain other conditions to produce a large volume of its own energetic (hot) gases for the performance of mechanical work. Although solid deflagrants such as nitrocellulose, the most commonly used propellant in firearms, could be thought of as monopropellants, the term is usually reserved for liquids in engineering literature.
Dinitrogen tetroxide, commonly referred to as nitrogen tetroxide (NTO), and occasionally (usually among ex-USSR/Russia rocket engineers) as amyl, is the chemical compound N2O4. It is a useful reagent in chemical synthesis. It forms an equilibrium mixture with nitrogen dioxide. Its molar mass is 92.011 g/mol.
A rocket engine uses stored rocket propellants as the reaction mass for forming a high-speed propulsive jet of fluid, usually high-temperature gas. Rocket engines are reaction engines, producing thrust by ejecting mass rearward, in accordance with Newton's third law. Most rocket engines use the combustion of reactive chemicals to supply the necessary energy, but non-combusting forms such as cold gas thrusters and nuclear thermal rockets also exist. Vehicles propelled by rocket engines are commonly used by ballistic missiles and rockets. Rocket vehicles carry their own oxidiser, unlike most combustion engines, so rocket engines can be used in a vacuum to propel spacecraft and ballistic missiles.
T-Stoff (; 'substance T') was a stabilised high test peroxide used in Germany during World War II. T-Stoff was specified to contain 80% (occasionally 85%) hydrogen peroxide (H2O2), remainder water, with traces (<0.1%) of stabilisers. Stabilisers used included 0.0025% phosphoric acid, a mixture of phosphoric acid, sodium phosphate and 8-oxyquinoline, and sodium stannate.
A liquid-propellant rocket or liquid rocket utilizes a rocket engine burning liquid propellants. (Alternate approaches use gaseous or solid propellants.) Liquids are desirable propellants because they have reasonably high density and their combustion products have high specific impulse (Isp). This allows the volume of the propellant tanks to be relatively low.
Aerozine 50 is a 50:50 mix by weight of hydrazine and unsymmetrical dimethylhydrazine (UDMH), originally developed in the late 1950s by Aerojet General Corporation as a storable, high-energy, hypergolic fuel for the Titan II ICBM rocket engines. Aerozine continues in wide use as a rocket fuel, typically with dinitrogen tetroxide as the oxidizer, with which it is hypergolic. Aerozine 50 is more stable than hydrazine alone, and has a higher density and boiling point than UDMH alone.
The highest specific impulse chemical rockets use liquid propellants. They can consist of a single chemical or a mix of two chemicals, called bipropellants. Bipropellants can further be divided into two categories; hypergolic propellants, which ignite when the fuel and oxidizer make contact, and non-hypergolic propellants which require an ignition source.
UH 25 is a fuel mixture for rockets. It was developed for the European Ariane 2–4 launch vehicles.
Taifun was a German World War II anti-aircraft unguided rocket system. Waves of small, relatively cheap, Taifun flak rockets were to be launched en masse into Allied bomber formations. Although never deployed operationally, the Taifun was further developed in the US as the 76mm HEAA T220 "Loki" Rocket.
Devil's venom was a nickname coined by Soviet rocket scientists for a liquid rocket fuel composed of a dangerous combination of red fuming nitric acid and hydrazine—specifically, hypergolic UDMH-nitric acid. Both propellants are extremely dangerous individually: Nitric acid is highly corrosive and causes offgassing of toxic nitrogen dioxide during reactions, or even simply while exposed to air in its highly concentrated "red fuming" form used as rocket propellant. UDMH is both toxic and corrosive. Despite these dangers, the pairing has been used in rocketry because this combination of fuel and oxidizer is hypergolic, which makes rockets using these materials simpler. Further, both the fuel and oxidizer have high boiling points compared to other rocket fuels and oxidizers, allowing rockets to be stored ready for launch for long periods without the fuel or oxidizer boiling off and needing to be replenished.
The Walter HWK 109-509 was a German liquid-fuel bipropellant rocket engine that powered the Messerschmitt Me 163 Komet and Bachem Ba 349 aircraft. It was produced by Hellmuth Walter Kommanditgesellschaft (HWK) commencing in 1943, with licensed production by the Heinkel firm's facilities in Jenbach, Austria.
Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical rocket, or from an external source, as with ion engines.
The BMW 109-718 was a liquid-fuelled rocket engine developed by BMW at their Bruckmühl facility, in Germany during the Second World War.
The Walter HWK 109-500 was a liquid-fuelled rocket engine developed by Walter in Germany during the Second World War.
A liquid apogee engine (LAE), or apogee engine, refers to a type of chemical rocket engine typically used as the main engine in a spacecraft.
The HWK 109-507 was a liquid-propellant rocket engine developed by Germany during World War II. It was used to propel the Hs 293 anti-ship guided missile.