Carbazide

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Carbohydrazide.png
Carbohydrazide, the simplest carbazide
Diphenylcarbazide.svg
Diphenylcarbazide

In chemistry, a carbazide is a functional group with the general formula RNH-NH(C=O)NH-NHR. They can be derived from the condensation of carbonic acid with a hydrazine. Carbohydrazide is the simplest carbazide, with another common carbazide being diphenylcarbazide, which is used as an analytical reagent. [1]

Contents

Diphenylcarbazide forms an intense blue color with chromium in the hexavalent state. It has an absorptivity coefficient about 3400. That means very small amounts of chromium can be detected; 25 micrograms in 25 mL of solution are too dark to read on a spectral device, so concentrations well below that can be detected.

Thiocarbazide

The sulfur analog is called a thiocarbazide, of which thiocarbohydrazide is the simplest example.

Carbazone and thiocarbazone

A carbazone is a partially oxidized carbazide with the general formula R=NNH(C=O)NH-NHR. The sulfur analog is called a thiocarbazone, of which dithizone is an example.

See also

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Acid–base reaction Chemical reaction

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An alum is a type of chemical compound, usually a hydrated double sulfate salt of aluminium with the general formula XAl(SO
4
)
2
·12H
2
O
, where X is a monovalent cation such as potassium or ammonium. By itself, "alum" often refers to potassium alum, with the formula KAl(SO
4
)
2
·12H
2
O
. Other alums are named after the monovalent ion, such as sodium alum and ammonium alum.

Chromic acid chemical compound

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Pyridinium chlorochromate chemical compound

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Amidine derivatives of oxoacids RnE(=O)OH in which the hydroxy group is replaced by an amino group and the oxo group is replaced by =NR

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Chromium(III) oxide chemical compound

Chromium(III) oxide is an inorganic compound with the formula Cr
2
O
3
. It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite.

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Indium(III) sulfate (In2(SO4)3) is a sulfate salt of the metal indium. It is a sesquisulfate, meaning that the sulfate group occurs 11/2 times as much as the metal. It may be formed by the reaction of indium, its oxide, or its carbonate with sulfuric acid. An excess of strong acid is required, otherwise insoluble basic salts are formed. As a solid indium sulfate can be anhydrous, or take the form of a pentahydrate with five water molecules or a nonahydrate with nine molecules of water. Indium sulfate is used in the production of indium or indium containing substances. Indium sulfate also can be found in basic salts, acidic salts or double salts including indium alum.

Thiirane chemical compound

Thiirane, more commonly known as ethylene sulfide, is the cyclic chemical compound with the formula C2H4S. It is the smallest sulfur-containing heterocycle and the simplest episulfide. Like many organosulfur compounds, this species has a stench. Thiirane is also used to describe any derivative of the parent ethylene sulfide.

Chromium(III) sulfate chemical compound

Chromium(III) sulfate usually refers to the inorganic compounds with the formula Cr2(SO4)3.x(H2O), where x can range from 0 to 18. Additionally, ill-defined but commercially important "basic chromium sulfates" are known. These salts are usually either violet or green solids that are soluble in water. It is commonly used in tanning leather.

Alkanolamines are chemical compounds that contain both hydroxyl (-OH) and amino (-NH2, -NHR, and -NR2) functional groups on an alkane backbone. The term alkanolamine is a broad class term that is sometimes used as a subclassification.

Azane any acyclic inorganic compound composed of nitrogen and hydrogen atoms bonded by single bonds

Azanes are acyclic, saturated hydronitrogens, which means that they consist only of hydrogen and nitrogen atoms and all bonds are single bonds. They are therefore pnictogen hydrides. Because cyclic hydronitrogens are excluded by definition, the azanes comprise a homologous series of inorganic compounds with the general chemical formula N
n
H
n+2
.

Sulfonamide class of chemical compounds

In chemistry, the sulfonamide functional group (also spelled sulphonamide) is -S(=O)2-NH2, a sulfonyl group connected to an amine group. Relatively speaking this group is unreactive. The amine center is no longer basic. The S-N bond is cleaved only with difficulty. Because of the rigidity of the functional group, sulfonamides are typically crystalline. For this reason, the formation of a sulfonamide is a classic method to convert an amine into a crystalline derivative which can be identified by its melting point. Many important drugs contain the sulfonamide group.

Diphenylcarbazide chemical compound

1,5-Diphenylcarbazide is a chemical compound from the group of the carbazides. It has a structural formula similar to that of diphenylcarbazone and can be easily converted into it by oxidation.

References

  1. Crossley, H. E. (1936). "Diphenylcarbazide. An internal indicator for use in the titration of iron with dichromate". The Analyst. 61 (720): 164. Bibcode:1936Ana....61..164C. doi:10.1039/AN9366100164.