Zirconium iodate

Last updated
Zirconium iodate
4.svg Iodat-Ion.svg Zr4+.svg
Identifiers
3D model (JSmol)
  • InChI=1S/4HIO3.Zr/c4*2-1(3)4;/h4*(H,2,3,4);/q;;;;+4/p-4
    Key: HONKFXPQYSOIMS-UHFFFAOYSA-J
  • anhydrous:[O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[Zr+4]
  • trihydrate:[O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[Zr+4].O.O.O
Properties
I4O12Zr
Molar mass 790.830 g·mol−1
Appearancewhite solid
Density 4.99
Structure
tetragonal
P4/n
a = 8.38, c = 7.49 Å [1]
526 Å3
2
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Zirconium iodate is an inorganic compound with the chemical formula Zr(IO3)4. It can be prepared by reacting sodium iodate and zirconium sulfate tetrahydrate in an aqueous solution. The resulting precipitate is dried and refluxed in concentrated nitric acid. [1] Zirconium iodate trihydrate can be obtained by reacting hydrated zirconium oxide and iodine pentoxide (1.4~3.3% concentration) in water. [2] Its basic salt Zr(OH)n(IO3)4−n is known. [3]

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<span class="mw-page-title-main">Iodate</span> Polyatomic anion (IO3) with charge -1

An iodate is the polyatomic anion with the formula IO−3. It is the most common form of iodine in nature, as it comprises the major iodine-containing ores. Iodate salts are often colorless. They are the salts of iodic acid.

<span class="mw-page-title-main">Zirconium hydride</span> Alloy of zirconium and hydrogen

Zirconium hydride describes an alloy made by combining zirconium and hydrogen. Hydrogen acts as a hardening agent, preventing dislocations in the zirconium atom crystal lattice from sliding past one another. Varying the amount of hydrogen and the form of its presence in the zirconium hydride controls qualities such as the hardness, ductility, and tensile strength of the resulting zirconium hydride. Zirconium hydride with increased hydrogen content can be made harder and stronger than zirconium, but such zirconium hydride is also less ductile than zirconium.

<span class="mw-page-title-main">Zirconium carbide</span> Chemical compound

Zirconium carbide (ZrC) is an extremely hard refractory ceramic material, commercially used in tool bits for cutting tools. It is usually processed by sintering.

<span class="mw-page-title-main">Zirconium(IV) chloride</span> Chemical compound

Zirconium(IV) chloride, also known as zirconium tetrachloride, is an inorganic compound frequently used as a precursor to other compounds of zirconium. This white high-melting solid hydrolyzes rapidly in humid air.

<span class="mw-page-title-main">Silver iodate</span> Chemical compound

Silver iodate (AgIO3) is a light-sensitive, white crystal composed of silver, iodine and oxygen. Unlike most metal iodates, it is practically insoluble in water.

<span class="mw-page-title-main">Sodium iodate</span> Chemical compound

Sodium iodate (NaIO3) is the sodium salt of iodic acid. Sodium iodate is an oxidizing agent. It has several uses.

<span class="mw-page-title-main">Zirconium tetrafluoride</span> Chemical compound

Zirconium(IV) fluoride describes members of a family inorganic compounds with the formula (ZrF4(H2O)x. All are colorless, diamagnetic solids. Anhydrous Zirconium(IV) fluoride' is a component of ZBLAN fluoride glass.

<span class="mw-page-title-main">Lithium iodate</span> Chemical compound

Lithium iodate (LiIO3) is a negative uniaxial crystal for nonlinear, acousto-optical and piezoelectric applications. It has been utilized for 347 nm ruby lasers.

<span class="mw-page-title-main">Zirconium perchlorate</span> Chemical compound

Zirconium perchlorate is an inorganic compound with the formula Zr(ClO4)4. It is a hygroscopic colorless solid that sublimes in a vacuum at 70 °C. These properties show that the compound is covalently bonded molecule, rather than a salt. It is an example of a transition metal perchlorate complex.

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Thulium(II) fluoride is one of the fluoride salts of the lanthanide metal thulium, with the chemical compound of TmF2. It can react with zirconium tetrafluoride at 900 °C to form TmZrF6, which has a hexagonal structure. In addition, low-temperature Mössbauer spectroscopy and some theoretical studies of thulium(II) fluoride have also been reported.

Lanthanum(III) iodate is an inorganic compound with the chemical formula La(IO3)3.

Praseodymium(III) iodate is an inorganic compound with the chemical formula Pr(IO3)3.

Erbium iodate is an inorganic compound with the chemical formula Er(IO3)3.

Ytterbium(III) iodate is an inorganic compound with the chemical formula Yb(IO3)3. Its dihydrate can be prepared by reacting ytterbium sulfate and iodic acid in water at 200 °C. It crystallizes in the P21/c space group, with unit cell parameters a=8.685, b=6.066, c=16.687 Å, β=115.01°.

Samarium iodate is an inorganic compound with the chemical formula Sm(IO3)3.

Europium(III) iodate is an inorganic compound with the chemical formula Eu(IO3)3. It can be produced by hydrothermal reaction of europium(III) nitrate or europium(III) oxide and iodic acid in water at 230 °C. It can be thermally decomposed as follows:

Bismuth iodate is an inorganic compound with the chemical formula Bi(IO3)3. Its anhydrate can be obtained by reacting bismuth nitrate and iodic acid, dissolving the resulting precipitate in 7.8 mol/L nitric acid, and heating to volatilize and crystallize at 70 °C; The dihydrate can be obtained by reacting bismuth nitrate and potassium iodate or sodium iodate. It is obtained by evaporation and crystallization in 7 mol/L nitric acid at 50 °C. Its basic salt BiOIO3 is known.

References

  1. 1 2 A. C. Larson, D. T. Cromer (1961-02-10). "The crystal structure of Zr(IO3)4". Acta Crystallographica. 14 (2): 128–132. Bibcode:1961AcCry..14..128L. doi:10.1107/S0365110X6100053X. Archived from the original on 2018-06-04. Retrieved 2021-06-01.
  2. ↑ "Passage de la nappe du Jotun aux arcs de Bergen". Bulletin de la Société Géologique de France. S7-XXII (3): 290–291. 1980. doi:10.2113/gssgfbull.s7-xxii.3.290. ISSN   0037-9409.
  3. ↑ Gysler, A.; Lindigkeit, J.; Lütjering, G. (1979), "Correlation Between Microstructure and Fatigue Fracture", Strength of Metals and Alloys, Elsevier, pp. 1113–1118, doi:10.1016/b978-1-4832-8412-5.50185-5, ISBN   978-1-4832-8412-5 , retrieved 2024-03-20
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