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Radiometric dating, radioactive dating or radioisotope dating is a technique which is used to date materials such as rocks or carbon, in which trace radioactive impurities were selectively incorporated when they were formed. The method compares the abundance of a naturally occurring radioactive isotope within the material to the abundance of its decay products, which form at a known constant rate of decay. The use of radiometric dating was first published in 1907 by Bertram Boltwood and is now the principal source of information about the absolute age of rocks and other geological features, including the age of fossilized life forms or the age of Earth itself, and can also be used to date a wide range of natural and man-made materials.
Uranium is a chemical element with symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium radioactively decays by emitting an alpha particle. The half-life of this decay varies between 159,200 and 4.5 billion years for different isotopes, making them useful for dating the age of the Earth. The most common isotopes in natural uranium are uranium-238 and uranium-235. Uranium has the highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead, and slightly lower than that of gold or tungsten. It occurs naturally in low concentrations of a few parts per million in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite.
Nucleosynthesis is the process that creates new atomic nuclei from pre-existing nucleons and nuclei. According to current theories, the first nuclei were formed a few minutes after the Big Bang, through nuclear reactions in a process called Big Bang nucleosynthesis. After about 20 minutes, the universe had expanded and cooled to a point at which these high-energy collisions among nucleons ended, so only the fastest and simplest reactions occurred, leaving our universe containing hydrogen and helium. The rest is traces of other elements such as lithium and the hydrogen isotope deuterium. Nucleosynthesis in stars and their explosions later produced the variety of elements and isotopes that we have today, in a process called cosmic chemical evolution. The amounts of total mass in elements heavier than hydrogen and helium remains small, so that the universe still has approximately the same composition.
Presolar grains are interstellar solid matter in the form of tiny solid grains that originated at a time before the Sun was formed. Presolar stardust grains formed within outflowing and cooling gases from earlier presolar stars.
The slow neutron-capture process, or s-process, is a series of reactions in nuclear astrophysics that occur in stars, particularly asymptotic giant branch stars. The s-process is responsible for the creation (nucleosynthesis) of approximately half the atomic nuclei heavier than iron.
The abundance of the chemical elements is a measure of the occurrence of the chemical elements relative to all other elements in a given environment. Abundance is measured in one of three ways: by mass fraction, by mole fraction, or by volume fraction. Volume fraction is a common abundance measure in mixed gases such as planetary atmospheres, and is similar in value to molecular mole fraction for gas mixtures at relatively low densities and pressures, and ideal gas mixtures. Most abundance values in this article are given as mass fractions.
A natural nuclear fission reactor is a uranium deposit where self-sustaining nuclear chain reactions occur. The conditions under which a natural nuclear reactor could exist had been predicted in 1956 by Paul Kuroda. The remnants of an extinct or fossil nuclear fission reactor, where self-sustaining nuclear reactions have occurred in the past, can be verified by analysis of isotope ratios of uranium and of the fission products. An example of this phenomenon was discovered in 1972 in Oklo, Gabon by Francis Perrin under conditions very similar to Kuroda's predictions.
Uranium-238 is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it is fissionable by fast neutrons, and is fertile, meaning it can be transmuted to fissile plutonium-239. 238U cannot support a chain reaction because inelastic scattering reduces neutron energy below the range where fast fission of one or more next-generation nuclei is probable. Doppler broadening of 238U's neutron absorption resonances, increasing absorption as fuel temperature increases, is also an essential negative feedback mechanism for reactor control.
Cosmic dust – also called extraterrestrial dust, space dust, or star dust – is dust that occurs in outer space or has fallen onto Earth. Most cosmic dust particles measure between a few molecules and 0.1 mm (100 μm), such as micrometeoroids. Larger particles are called meteoroids. Cosmic dust can be further distinguished by its astronomical location: intergalactic dust, interstellar dust, interplanetary dust, and circumplanetary dust. There are several methods to obtain space dust measurement.
Uranium (92U) is a naturally occurring radioactive element that has no stable isotope. It has two primordial isotopes, uranium-238 and uranium-235, that have long half-lives and are found in appreciable quantity in the Earth's crust. The decay product uranium-234 is also found. Other isotopes such as uranium-233 have been produced in breeder reactors. In addition to isotopes found in nature or nuclear reactors, many isotopes with far shorter half-lives have been produced, ranging from 214U to 242U. The standard atomic weight of natural uranium is 238.02891(3).
Plutonium-244 (244Pu) is an isotope of plutonium that has a half-life of 80 million years. This is longer than any of the other isotopes of plutonium and longer than any other actinide isotope except for the three naturally abundant ones: uranium-235, uranium-238, and thorium-232. Although studies are in conflict, given the mathematics of the decay of plutonium-244, an exceedingly small amount should still be present in the Earth's composition, making plutonium a likely although unproven candidate as the shortest lived primordial element.
An extinct radionuclide is a radionuclide that was formed by nucleosynthesis before the formation of the Solar System, about 4.6 billion years ago, but has since decayed to virtually zero abundance and is no longer detectable as a primordial nuclide. Extinct radionuclides were generated by various processes in the early Solar system, and became part of the composition of meteorites and protoplanets. All widely documented extinct radionuclides have half-lives shorter than 100 million years.
Extraterrestrial material refers to natural objects now on Earth that originated in outer space. Such materials include cosmic dust and meteorites, as well as samples brought to Earth by sample return missions from the Moon, asteroids and comets, as well as solar wind particles.
Aluminium-26 is a radioactive isotope of the chemical element aluminium, decaying by either positron emission or electron capture to stable magnesium-26. The half-life of 26Al is 717,000 years. This is far too short for the isotope to survive as a primordial nuclide, but a small amount of it is produced by collisions of atoms with cosmic ray protons.
Isotopes are distinct nuclear species of the same element. They have the same atomic number and position in the periodic table, but differ in nucleon numbers due to different numbers of neutrons in their nuclei. While all isotopes of a given element have almost the same chemical properties, they have different atomic masses and physical properties.
In geochemistry, geophysics and nuclear physics, primordial nuclides, also known as primordial isotopes, are nuclides found on Earth that have existed in their current form since before Earth was formed. Primordial nuclides were present in the interstellar medium from which the solar system was formed, and were formed in, or after, the Big Bang, by nucleosynthesis in stars and supernovae followed by mass ejection, by cosmic ray spallation, and potentially from other processes. They are the stable nuclides plus the long-lived fraction of radionuclides surviving in the primordial solar nebula through planet accretion until the present; 286 such nuclides are known.
Nuclear transmutation is the conversion of one chemical element or an isotope into another chemical element. Nuclear transmutation occurs in any process where the number of protons or neutrons in the nucleus of an atom is changed.
Donald Delbert Clayton is an American astrophysicist whose most visible achievement was the prediction from nucleosynthesis theory that supernovae are intensely radioactive. That earned Clayton the NASA Exceptional Scientific Achievement Medal (1992) for “theoretical astrophysics related to the formation of (chemical) elements in the explosions of stars and to the observable products of these explosions”. Supernovae thereafter became the most important stellar events in astronomy owing to their profoundly radioactive nature. Not only did Clayton discover radioactive nucleosynthesis during explosive silicon burning in stars but he also predicted a new type of astronomy based on it, namely the associated gamma-ray line radiation emitted by matter ejected from supernovae. That paper was selected as one of the fifty most influential papers in astronomy during the twentieth century for the Centennial Volume of the American Astronomical Society. He gathered support from influential astronomers and physicists for a new NASA budget item for a gamma-ray-observatory satellite, achieving successful funding for Compton Gamma Ray Observatory. With his focus on radioactive supernova gas Clayton discovered a new chemical pathway causing carbon dust to condense there by a process that is activated by the radioactivity.
Ernst Kunibert Zinner was an Austrian astrophysicist, known for his pioneering work in the analysis of stardust in the laboratory. He long had a position in the United States at the Laboratory for Space Physics at Washington University in St. Louis, Missouri, where he had earned his doctorate. He came to the United States in the 1960s for graduate work. In addition, Zinner regularly taught at European universities, and other American institutions.
References
- ↑ "Uranium Isotopes". GlobalSecurity.org . Retrieved 14 March 2012.
- ↑ Clayton, Robert N. (1978). "Isotopic anomalies in the early solar system". Annual Review of Nuclear and Particle Science . 28: 501–522. Bibcode:1978ARNPS..28..501C. doi:10.1146/annurev.ns.28.120178.002441.
- ↑ Zinner, Ernst (2003). "An isotopic view of the early solar system". Science. 300 (5617): 265–267. doi:10.1126/science.1080300. PMID 12690180. S2CID 118638578.
- 1 2 Anders, Edward; Zinner, Ernst (1993). "Interstellar Grains in Primitive Meteorites: Diamond, Silicon Carbide, and Graphite". Meteoritics. 28 (4): 490–514. Bibcode:1993Metic..28..490A. doi:10.1111/j.1945-5100.1993.tb00274.x.
- ↑ Zinner, Ernst (1998). "Stellar nucleosynthesis and the isotopic composition of presolar grains from primitive meteorites". Annual Review of Earth and Planetary Sciences . 26: 147–188. Bibcode:1998AREPS..26..147Z. doi:10.1146/annurev.earth.26.1.147.
- ↑ Lide, D. R., ed. (2002). CRC Handbook of Chemistry and Physics (83rd ed.). Boca Raton, FL: CRC Press. ISBN 0-8493-0483-0.