Total dissolved solids (TDS) is a measure of the dissolved combined content of all inorganic and organic substances present in a liquid in molecular, ionized, or micro-granular (colloidal sol) suspended form. TDS are often measured in parts per million (ppm). TDS in water can be measured using a digital meter. [1]
Generally, the operational definition is that the solids must be small enough to survive filtration through a filter with 2-micrometer (nominal size, or smaller) pores. Total dissolved solids are normally discussed only for freshwater systems, as salinity includes some of the ions constituting the definition of TDS. The principal application of TDS is in the study of water quality for streams, rivers, and lakes. Although TDS is not generally considered a primary pollutant (e.g. it is not deemed to be associated with health effects), it is used as an indication of aesthetic characteristics of drinking water and as an aggregate indicator of the presence of a broad array of chemical contaminants.
Primary sources for TDS in receiving waters are agricultural runoff and residential (urban) runoff, clay-rich mountain waters, leaching of soil contamination, and point source water pollution discharge from industrial or sewage treatment plants. The most common chemical constituents are calcium, phosphates, nitrates, sodium, potassium, and chloride, which are found in nutrient runoff, general stormwater runoff and runoff from snowy climates where road de-icing salts are applied. The chemicals may be cations, anions, molecules or agglomerations on the order of one thousand or fewer molecules, so long as a soluble micro-granule is formed. More exotic and harmful elements of TDS are pesticides arising from surface runoff. Certain naturally occurring total dissolved solids arise from the weathering and dissolution of rocks and soils. The United States has established a secondary water quality standard of 500 mg/L to provide for palatability of drinking water.
Total dissolved solids are differentiated from total suspended solids (TSS), in that the latter cannot pass through a sieve of 2 micrometers and yet are indefinitely suspended in solution. The term settleable solids refers to material of any size that will not remain suspended or dissolved in a holding tank not subject to motion, and excludes both TDS and TSS. [2] Settleable solids may include larger particulate matter or insoluble molecules.
Total dissolved solids include both volatile and non-volatile solids. Volatile solids are ones that can easily go from a solid to a gaseous state. Non-volatile solids must be heated to a high temperature, typically 550 °C, in order to achieve this state change. Examples of non-volatile substances include salts and sugars. [3]
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The two principal methods of measuring total dissolved solids are gravimetric analysis and conductivity. [4] Gravimetric methods are the most accurate and involve evaporating the liquid solvent and measuring the mass of residues left. This method is generally the best, although it is time-consuming. If inorganic salts comprise the great majority of TDS, conductivity-based methods are appropriate.
Conductivity of water is directly related to the concentration of dissolved ionized solids. These ions allow the water to conduct electric current. This electric current can be measured using a conventional conductivity meter or TDS meter. When correlated with laboratory TDS measurements, conductivity provides an approximate value for the TDS concentration, with around 10% accuracy.
The relationship of TDS and specific conductance of groundwater can be approximated by the following equation:
where TDS is expressed in mg/L and EC is the electrical conductivity in microsiemens per centimeter at 25 °C. The conversion factor ke varies between 0.55 and 0.8. [5]
Some TDS meters use an electrical conductivity measurement to the ppm using the above formula. Regarding units, 1 ppm indicates 1 mg of dissolved solids per 1,000 g of water. [6]
Hydrologic transport models are used to mathematically analyze movement of TDS within river systems. The most common models address surface runoff, allowing variation in land use type, topography, soil type, vegetative cover, precipitation, and land management practice (e.g. the application rate of a fertilizer). Runoff models have evolved to a good degree of accuracy and permit the evaluation of alternative land management practices upon impacts to stream water quality.
Basin models are used to more comprehensively evaluate total dissolved solids within a catchment basin and dynamically along various stream reaches. The DSSAM model was developed by the U.S. Environmental Protection Agency (EPA). [7] This hydrology transport model is actually based upon the pollutant-loading metric called "Total Maximum Daily Load" (TMDL), which addresses TDS and other specific chemical pollutants. The success of this model contributed to the Agency's broadened commitment to the use of the underlying TMDL protocol in its national policy for management of many river systems in the United States. [8]
When measuring water treated with water softeners, high levels of total dissolved solids do not correlate to hard water, as water softeners do not reduce TDS; rather, they replace magnesium and calcium ions, which cause hard water, with an equal charge of sodium or potassium ions, e.g. Ca2+ ⇌ 2 Na+, leaving overall TDS unchanged [9] or even increased. Hard water can cause scale buildup in pipes, valves, and filters, reducing performance and adding to system maintenance costs. These effects can be seen in aquariums, spas, swimming pools, and reverse osmosis water treatment systems. Typically, total dissolved solids are tested frequently in these applications, and filtration membranes are checked to prevent adverse effects.
In the case of hydroponics and aquaculture, TDS is often monitored to create a water quality environment favorable for organism productivity. For freshwater, oysters, trouts, and other high-value seafood, the highest productivity and economic returns are achieved by mimicking the TDS and pH levels of each species' native environment. For hydroponic uses, total dissolved solids are considered one of the best indices of nutrient availability for the aquatic plants being grown.
Because the threshold of acceptable aesthetic criteria for human drinking water is 500 mg/L, there is no general concern for odor, taste, and color at a level much lower than is required for harm. Several studies have been conducted that indicate various species' reactions range from intolerance to outright toxicity due to elevated TDS. The numerical results must be interpreted cautiously, as accurate toxicity outcomes relate to specific chemical constituents. Nevertheless, some numerical information is a helpful guide to the nature of risks in exposing aquatic organisms or terrestrial animals to high TDS levels. Most aquatic ecosystems involving mixed fish fauna can tolerate TDS levels of 1000 mg/L. [10]
The fathead minnow (Pimephales promelas), for example, realizes an LD50 concentration of 5,600 ppm based upon a 96-hour exposure. LD50 is the concentration required to produce a lethal effect on 50 percent of the exposed population. Daphnia magna , a good example of a primary member of the food chain, is a small planktonic crustacean, about 0.5 mm (0.020 in) in length, having an LD50 of about 10,000 ppm TDS for a 96-hour exposure. [11]
Spawning fishes and juveniles appear to be more sensitive to high TDS levels. For example, it was found that concentrations of 350 mg/L TDS reduced spawning of Striped bass (Morone saxatilis) in the San Francisco Bay-Delta region, and that concentrations below 200 mg/L promoted even healthier spawning conditions. [12] In the Truckee River, EPA found that juvenile Lahontan cutthroat trout were subject to higher mortality when exposed to thermal pollution stress combined with high total dissolved solids concentrations. [7]
For terrestrial animals, poultry typically possess a safe upper limit of TDS exposure of approximately 2,900 mg/L, whereas dairy cattle are measured to have a safe upper limit of about 7,100 mg/L. Research has shown that exposure to TDS is compounded in toxicity when other stressors are present, such as abnormal pH, high turbidity, or reduced dissolved oxygen with the latter stressor acting only in the case of Animalia. [13]
In countries with often unsafe/unclean tap water supplies, technicians frequently check the TDS of drinking water to gauge how effectively their RO/Water Filtration devices are working. While TDS readings will not provide the number of microorganisms present in a sample of water, they can indicate how efficient the filter is by the presence of TDS.
[14] Water can be classified by the level of total dissolved solids (TDS) in the water:
Drinking water generally has a TDS below 500 ppm. Higher TDS Fresh Water is drinkable but taste may be objectionable.
Salinity is the saltiness or amount of salt dissolved in a body of water, called saline water. It is usually measured in g/L or g/kg.
Distilled water is water that has been boiled into vapor and condensed back into liquid in a separate container. Impurities in the original water that do not boil below or near the boiling point of water remain in the original container. Thus, distilled water is a type of purified water.
Potassium chloride is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a salt-like taste. Potassium chloride can be obtained from ancient dried lake deposits. KCl is used as a fertilizer, in medicine, in scientific applications, domestic water softeners, and in food processing, where it may be known as E number additive E508.
Water quality refers to the chemical, physical, and biological characteristics of water based on the standards of its usage. It is most frequently used by reference to a set of standards against which compliance, generally achieved through treatment of the water, can be assessed. The most common standards used to monitor and assess water quality convey the health of ecosystems, safety of human contact, extent of water pollution and condition of drinking water. Water quality has a significant impact on water supply and often determines supply options.
Hard water is water that has a high mineral content. Hard water is formed when water percolates through deposits of limestone, chalk or gypsum, which are largely made up of calcium and magnesium carbonates, bicarbonates and sulfates.
Purified water is water that has been mechanically filtered or processed to remove impurities and make it suitable for use. Distilled water was, formerly, the most common form of purified water, but, in recent years, water is more frequently purified by other processes including capacitive deionization, reverse osmosis, carbon filtering, microfiltration, ultrafiltration, ultraviolet oxidation, or electrodeionization. Combinations of a number of these processes have come into use to produce ultrapure water of such high purity that its trace contaminants are measured in parts per billion (ppb) or parts per trillion (ppt).
Total organic carbon (TOC) is an analytical parameter representing the concentration of organic carbon in a sample. TOC determinations are made in a variety of application areas. For example, TOC may be used as a non-specific indicator of water quality, or TOC of source rock may be used as one factor in evaluating a petroleum play. For marine surface sediments average TOC content is 0.5% in the deep ocean, and 2% along the eastern margins.
Saline water is water that contains a high concentration of dissolved salts. On the United States Geological Survey (USGS) salinity scale, saline water is saltier than brackish water, but less salty than brine. The salt concentration is usually expressed in parts per thousand and parts per million (ppm). The USGS salinity scale defines three levels of saline water. The salt concentration in slightly saline water is 1,000 to 3,000 ppm (0.1–0.3%); in moderately saline water is 3,000 to 10,000 ppm (0.3–1%); and in highly saline water is 10,000 to 35,000 ppm (1–3.5%). Seawater has a salinity of roughly 35,000 ppm, equivalent to 35 grams of salt per one liter of water. The saturation level is only nominally dependent on the temperature of the water. At 20 °C (68 °F) one liter of water can dissolve about 357 grams of salt, a concentration of 26.3 percent by weight. At 100 °C (212 °F), the amount of salt that can be dissolved in one liter of water increases to about 391 grams, a concentration of 28.1% w/w.
Heptachlor is an organochlorine compound that was used as an insecticide. Usually sold as a white or tan powder, heptachlor is one of the cyclodiene insecticides. In 1962, Rachel Carson's Silent Spring questioned the safety of heptachlor and other chlorinated insecticides. Due to its highly stable structure, heptachlor can persist in the environment for decades. In the United States, the Environmental Protection Agency has limited the sale of heptachlor products to the specific application of fire ant control in underground transformers. The amount that can be present in different foods is regulated.
A salinometer is a device designed to measure the salinity, or dissolved salt content, of a solution.
Electrodialysis (ED) is used to transport salt ions from one solution through ion-exchange membranes to another solution under the influence of an applied electric potential difference. This is done in a configuration called an electrodialysis cell. The cell consists of a feed (dilute) compartment and a concentrate (brine) compartment formed by an anion exchange membrane and a cation exchange membrane placed between two electrodes. In almost all practical electrodialysis processes, multiple electrodialysis cells are arranged into a configuration called an electrodialysis stack, with alternating anion and cation-exchange membranes forming the multiple electrodialysis cells. Electrodialysis processes are different from distillation techniques and other membrane based processes in that dissolved species are moved away from the feed stream, whereas other processes move away the water from the remaining substances. Because the quantity of dissolved species in the feed stream is far less than that of the fluid, electrodialysis offers the practical advantage of much higher feed recovery in many applications.
Wastewater quality indicators are laboratory test methodologies to assess suitability of wastewater for disposal, treatment or reuse. The main parameters in sewage that are measured to assess the sewage strength or quality as well as treatment options include: solids, indicators of organic matter, nitrogen, phosphorus, indicators of fecal contamination. Tests selected vary with the intended use or discharge location. Tests can measure physical, chemical, and biological characteristics of the wastewater. Physical characteristics include temperature and solids. Chemical characteristics include pH value, dissolved oxygen concentrations, biochemical oxygen demand (BOD) and chemical oxygen demand (COD), nitrogen, phosphorus, chlorine. Biological characteristics are determined with bioassays and aquatic toxicology tests.
A total maximum daily load (TMDL) is a regulatory term in the U.S. Clean Water Act, describing a plan for restoring impaired waters that identifies the maximum amount of a pollutant that a body of water can receive while still meeting water quality standards.
Alkali, or Alkaline, soils are clay soils with high pH, a poor soil structure and a low infiltration capacity. Often they have a hard calcareous layer at 0.5 to 1 metre depth. Alkali soils owe their unfavorable physico-chemical properties mainly to the dominating presence of sodium carbonate, which causes the soil to swell and difficult to clarify/settle. They derive their name from the alkali metal group of elements, to which sodium belongs, and which can induce basicity. Sometimes these soils are also referred to as alkaline sodic soils. Alkaline soils are basic, but not all basic soils are alkaline.
Reverse osmosis (RO) is a water purification process that uses a semi-permeable membrane to separate water molecules from other substances. RO applies pressure to overcome osmotic pressure that favors even distributions. RO can remove dissolved or suspended chemical species as well as biological substances, and is used in industrial processes and the production of potable water. RO retains the solute on the pressurized side of the membrane and the purified solvent passes to the other side. The relative sizes of the various molecules determines what passes through. "Selective" membranes reject large molecules, while accepting smaller molecules.
Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m).
Nutrient pollution, a form of water pollution, refers to contamination by excessive inputs of nutrients. It is a primary cause of eutrophication of surface waters, in which excess nutrients, usually nitrogen or phosphorus, stimulate algal growth. Sources of nutrient pollution include surface runoff from farm fields and pastures, discharges from septic tanks and feedlots, and emissions from combustion. Raw sewage is a large contributor to cultural eutrophication since sewage is high in nutrients. Releasing raw sewage into a large water body is referred to as sewage dumping, and still occurs all over the world. Excess reactive nitrogen compounds in the environment are associated with many large-scale environmental concerns. These include eutrophication of surface waters, harmful algal blooms, hypoxia, acid rain, nitrogen saturation in forests, and climate change.
Drinking water quality standards describes the quality parameters set for drinking water. Water may contain many harmful constituents, yet there are no universally recognized and accepted international standards for drinking water. Even where standards do exist, the permitted concentration of individual constituents may vary by as much as ten times from one set of standards to another. Many countries specify standards to be applied in their own country. In Europe, this includes the European Drinking Water Directive and in the United States, the United States Environmental Protection Agency (EPA) establishes standards as required by the Safe Drinking Water Act. China adopted its own drinking water standard GB3838-2002 enacted by Ministry of Environmental Protection in 2002. For countries without a legislative or administrative framework for such standards, the World Health Organization publishes guidelines on the standards that should be achieved.
Freshwater salinization is the process of salty runoff contaminating freshwater ecosystems, which can harm aquatic species in certain quantities and contaminate drinking water. It is often measured by the increased amount of dissolved minerals than what is considered usual for the area being observed. Naturally occurring salinization is referred to as primary salinization; this includes rainfall, rock weathering, seawater intrusion, and aerosol deposits. Human-induced salinization is termed as secondary salinization, with the use of de-icing road salts as the most common form of runoff. Approximately 37% of the drainage in the United States has been affected by salinization in the past century. The EPA has defined two thresholds for healthy salinity levels in freshwater ecosystems: 230 mg/L Cl− for average salinity levels and 860 mg/L Cl− for acute inputs.
Coastal Hydrogeology is a branch of Hydrogeology that focuses on the movement and the chemical properties of groundwater in coastal areas. Coastal Hydrogeology studies the interaction between fresh groundwater and seawater, including seawater intrusion, sea level induced groundwater level fluctuation, submarine groundwater discharge, human activities and groundwater management in coastal areas.
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(help) Environmental Protection Technology Series. Document No. EPA-660/2-73-003.