William Barry Jensen (born March 25, 1948, in Marshfield, Wisconsin- died November 2, 2024 Cincinnati, Ohio) [1] was an American chemist and chemical historian. [2]
Jensen, son of a sign painter and librarian, went to school in Wausau, Wisconsin. He became interested in chemistry at an early age and, after reading Discovery of the Elements by Mary Elvira Weeks, he also became interested in the history of chemistry. In 2013, Jensen wrote Memoirs of an Amateur Chemist: Growing up a Science Nerd in the 1960s, an autobiography detailing his earliest memories, such as receiving his first chemistry kit, collecting pieces of glassware, and winning science fairs. These memoirs were published electronically by the Oesper Collections in 2024 and can be found here: https://hdl.handle.net/2374.UC/768605
Jensen studied chemistry at the University of Wisconsin – Madison, taking a bachelor's degree in 1970, a master's degree in 1972 and a doctorate in inorganic chemistry in 1982. He was then appointed as assistant professor of inorganic chemistry at the Rochester Institute of Technology from 1983 to 1986, before becoming Oesper Professor of the History of Chemistry and Chemistry Education at the University of Cincinnati. [2] There he was also curator of the Oesper Collection on the History of Chemistry, the largest such collection in the United States after that at the Smithsonian Museum.
He had an Ask the Historian column in the Journal of Chemical Education. From 1988 to 1995, he was the founding editor of the Bulletin for the History of Chemistry. He was awarded the 2005 Edelstein Award for Outstanding contributions to the History of Chemistry by the History division of the American Chemical Society. As a chemical historian, he was primarily concerned with the history of physical and inorganic chemistry at the end of the 19th and beginning of the 20th centuries, as well as the history of chemical apparatus. He endeavours to bring the history of chemistry closer to more chemistry students, detached from the history of science. [2]
Jensen was an article contributor to Encyclopedia Britannica. [3] He was also a caricaturist for MeasureNet Technology Ltd. [4] . In 2010, Jensen published a book of his caricatures of famous scientists which the Oesper Collections published digitally in 2024. Chymists: That strange class of mortals: Caricatures of famous chemists with a few physicists and biologists added, can be found here: https://hdl.handle.net/2374.UC/768601
In 1982, an influential article by Jensen appeared in the Journal of Chemical Education, suggesting that group 3 in the periodic table should contain lutetium and lawrencium instead of lanthanum and actinium. [5] This question has been much debated in the literature. Jensen was a member of a 2015–2021 IUPAC project to decide on the composition of group 3, chaired by Eric Scerri; [6] so far it has produced a provisional report (written by Scerri), which was in support of Jensen's 1982 conclusion. [7]
Dr. Jensen's books published by the Oesper Collections can be found here: https://hdl.handle.net/2374.UC/768600 and include books on the origins of the chemistry community in Cincinnati, OH, titles previously mentioned, and his beloved history of chemistry textbook, Philosophers of Fire.
Actinium is a chemical element; it has symbol Ac and atomic number 89. It was first isolated by Friedrich Oskar Giesel in 1902, who gave it the name emanium; the element got its name by being wrongly identified with a substance André-Louis Debierne found in 1899 and called actinium. The actinide series, a set of 15 elements between actinium and lawrencium in the periodic table, are named for actinium. Together with polonium, radium, and radon, actinium was one of the first non-primordial radioactive elements to be isolated.
The actinide or actinoid series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. Number 103, lawrencium, is also generally included despite being part of the 6d transition series. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide.
Electronegativity, symbolized as χ, is the tendency for an atom of a given chemical element to attract shared electrons when forming a chemical bond. An atom's electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity, the more an atom or a substituent group attracts electrons. Electronegativity serves as a simple way to quantitatively estimate the bond energy, and the sign and magnitude of a bond's chemical polarity, which characterizes a bond along the continuous scale from covalent to ionic bonding. The loosely defined term electropositivity is the opposite of electronegativity: it characterizes an element's tendency to donate valence electrons.
Lanthanum is a chemical element with the symbol La and the atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. Lanthanum is traditionally counted among the rare earth elements. Like most other rare earth elements, its usual oxidation state is +3, although some compounds are known with an oxidation state of +2. Lanthanum has no biological role in humans but is used by some bacteria. It is not particularly toxic to humans but does show some antimicrobial activity.
Lutetium is a chemical element; it has symbol Lu and atomic number 71. It is a silvery white metal, which resists corrosion in dry air, but not in moist air. Lutetium is the last element in the lanthanide series, and it is traditionally counted among the rare earth elements; it can also be classified as the first element of the 6th-period transition metals.
Lawrencium is a synthetic chemical element; it has symbol Lr and atomic number 103. It is named after Ernest Lawrence, inventor of the cyclotron, a device that was used to discover many artificial radioactive elements. A radioactive metal, lawrencium is the eleventh transuranium element, the third transfermium, and the last member of the actinide series. Like all elements with atomic number over 100, lawrencium can only be produced in particle accelerators by bombarding lighter elements with charged particles. Fourteen isotopes of lawrencium are currently known; the most stable is 266Lr with half-life 11 hours, but the shorter-lived 260Lr is most commonly used in chemistry because it can be produced on a larger scale.
The periodic table, also known as the periodic table of the elements, is an ordered arrangement of the chemical elements into rows ("periods") and columns ("groups"). It is an icon of chemistry and is widely used in physics and other sciences. It is a depiction of the periodic law, which states that when the elements are arranged in order of their atomic numbers an approximate recurrence of their properties is evident. The table is divided into four roughly rectangular areas called blocks. Elements in the same group tend to show similar chemical characteristics.
In chemistry, a transition metal is a chemical element in the d-block of the periodic table, though the elements of group 12 are sometimes excluded. The lanthanide and actinide elements are called inner transition metals and are sometimes considered to be transition metals as well.
In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule in atomic or molecular orbitals. For example, the electron configuration of the neon atom is 1s2 2s2 2p6, meaning that the 1s, 2s, and 2p subshells are occupied by two, two, and six electrons, respectively.
In chemistry, a group is a column of elements in the periodic table of the chemical elements. There are 18 numbered groups in the periodic table; the 14 f-block columns, between groups 2 and 3, are not numbered. The elements in a group have similar physical or chemical characteristics of the outermost electron shells of their atoms, because most chemical properties are dominated by the orbital location of the outermost electron.
A period 6 element is one of the chemical elements in the sixth row (or period) of the periodic table of the chemical elements, including the lanthanides. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The sixth period contains 32 elements, tied for the most with period 7, beginning with caesium and ending with radon. Lead is currently the last stable element; all subsequent elements are radioactive. For bismuth, however, its only primordial isotope, 209Bi, has a half-life of more than 1019 years, over a billion times longer than the current age of the universe. As a rule, period 6 elements fill their 6s shells first, then their 4f, 5d, and 6p shells, in that order; however, there are exceptions, such as gold.
A period 7 element is one of the chemical elements in the seventh row of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behavior of the elements as their atomic number increases: a new row is begun when chemical behavior begins to repeat, meaning that elements with similar behavior fall into the same vertical columns. The seventh period contains 32 elements, tied for the most with period 6, beginning with francium and ending with oganesson, the heaviest element currently discovered. As a rule, period 7 elements fill their 7s shells first, then their 5f, 6d, and 7p shells in that order, but there are exceptions, such as uranium.
Chemistry is the physical science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions.
Group 3 is the first group of transition metals in the periodic table. This group is closely related to the rare-earth elements. It contains the four elements scandium (Sc), yttrium (Y), lutetium (Lu), and lawrencium (Lr). The group is also called the scandium group or scandium family after its lightest member.
The periodic table is an arrangement of the chemical elements, structured by their atomic number, electron configuration and recurring chemical properties. In the basic form, elements are presented in order of increasing atomic number, in the reading sequence. Then, rows and columns are created by starting new rows and inserting blank cells, so that rows (periods) and columns (groups) show elements with recurring properties. For example, all elements in group (column) 18 are noble gases that are largely—though not completely—unreactive.
Evgeny Mikhailovich Lifshitz was a leading Soviet physicist and brother of the physicist Ilya Lifshitz.
A block of the periodic table is a set of elements unified by the atomic orbitals their valence electrons or vacancies lie in. The term seems to have been first used by Charles Janet. Each block is named after its characteristic orbital: s-block, p-block, d-block, f-block and g-block.
Actinium(III) fluoride (AcF3) is an inorganic compound, a salt of actinium and fluorine.
Ralph Edward Oesper was an American chemist and historian of chemistry. He is noted for his biographies of scientists, emphasizing their personal lives in addition to their scientific contributions. Oesper translated significant works in the field of chemistry to various languages especially English. As an independent investigator, he developed improved analytical methods. These contributions included new reagents for certain types of titrations. One such new reagent, Oesper's Salt, is named after him.
The actinide contraction is the greater-than-expected decrease in atomic radii and ionic radii of the elements in the actinide series, from left to right.