Cumulate rock

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Close-up view of a cumulate rock from Montana (scale: about
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45 millimetres (1+3/4 in) across) Sulfidic norite (platinum-palladium ore) Stillwater Mine MT.jpg
Close-up view of a cumulate rock from Montana (scale: about 45 millimetres (1+34 in) across)

Cumulate rocks are igneous rocks formed by the accumulation of crystals from a magma either by settling or floating. Cumulate rocks are named according to their texture; cumulate texture is diagnostic of the conditions of formation of this group of igneous rocks. Cumulates can be deposited on top of other older cumulates of different composition and colour, typically giving the cumulate rock a layered or banded appearance.

Contents

Formation

Schematic diagrams showing the principles behind fractional crystallisation in a magma. While cooling, the magma evolves in composition because different minerals crystallize from the melt. 1: olivine crystallizes; 2: olivine and pyroxene crystallize; 3: pyroxene and plagioclase crystallize; 4: plagioclase crystallizes. At the bottom of the magma reservoir, a cumulate rock forms. Fractional crystallization.svg
Schematic diagrams showing the principles behind fractional crystallisation in a magma. While cooling, the magma evolves in composition because different minerals crystallize from the melt. 1: olivine crystallizes; 2: olivine and pyroxene crystallize; 3: pyroxene and plagioclase crystallize; 4: plagioclase crystallizes. At the bottom of the magma reservoir, a cumulate rock forms.

Cumulate rocks are the typical product of precipitation of solid crystals from a fractionating magma chamber. These accumulations typically occur on the floor of the magma chamber, although they are possible on the roofs if anorthite plagioclase is able to float free of a denser mafic melt. [1]

Cumulates are typically found in ultramafic intrusions, in the base of large ultramafic lava tubes in komatiite and magnesium rich basalt flows and also in some granitic intrusions.

Terminology

Cumulates are named according to their dominant mineralogy and the percentage of crystals to their groundmass (Hall, 1996).

Cumulate rocks are typically named according to the cumulate minerals in order of abundance, and then cumulate type (adcumulate, mesocumulate, orthocumulate), and then accessory or minor phases. For example:

Cumulate terminology is appropriate for use when describing cumulate rocks. In intrusions which have a uniform composition and minimal textural and mineralogical layering or visible crystal accumulations it is inappropriate to describe them according to this convention.

Geochemistry

Layers of cumulate rock (gabbro) in Oman Layered Gabbro in Oman.jpg
Layers of cumulate rock (gabbro) in Oman

Cumulate rocks, because they are fractionates of a parental magma, should not be used to infer the composition of a magma from which they are formed. The chemistry of the cumulate itself can inform on the residual melt composition, but several factors need to be considered.

Chemistry

The chemistry of a cumulate can inform upon the temperature, pressure and chemistry of the melt from which it was formed, but the number of minerals which co-precipitate need to be known, as does the chemistry or mineral species of the precipitated minerals. [2] This is best illustrated by an example;

As an example, a magma of basalt composition that is precipitating cumulates of anorthite plagioclase plus enstatite pyroxene is changing composition by the removal of the elements which make up the precipitated minerals. In this example, the precipitation of anorthite (a calcium aluminium feldspar) removes calcium from the melt, which becomes more depleted in calcium. Enstatite being precipitated from the melt will remove magnesium, so the melt becomes depleted in these elements. This tends to enrich the concentration of other elements - typically sodium, potassium, titanium and iron.

The rock that is made of the accumulated minerals will not have the same composition as the magma. In the above example, the cumulate of anorthite + enstatite is rich in calcium and magnesium, and the melt is depleted in calcium and magnesium. The cumulate rock is a plagioclase-pyroxene cumulate (a gabbro) and the melt is now more felsic and aluminous in composition (trending towards andesite compositions).

In the above example, the plagioclase and pyroxene need not be pure end-member compositions (anorthite-enstatite), and thus the effect of depletion of elements can be complex. The minerals can be precipitated in any ratio within the cumulate; such cumulates can be 90% plagioclase:10% enstatite, through to 10% plagiclase:90% enstatite and remain a gabbro. This also alters the chemistry of the cumulate, and the depletions of the residual melt.

It can be seen that the effect on the composition of the residual melt left behind by the formation of the cumulate is dependent on the composition of the minerals which precipitate, the number of minerals which co-precipitate at the same time, and the ratio of the minerals which co-precipitate. In nature, cumulates usually form from 2 mineral species, although ranges from 1 to 4 mineral species are known. Cumulate rocks which are formed from one mineral alone are often named after the mineral, for example a 99% magnetite cumulate is known as a magnetitite.

A specific example is the Skaergaard intrusion in Greenland. At Skaergaard a 2500 m thick layered intrusion shows distinct chemical and mineralogic layering: [3]

The Skaergaard is interpreted to have crystallised from a single confined magma chamber. [3]

Residual melt chemistry

One way to infer the composition of the magma that created the cumulate rocks is to measure groundmass chemistry, but that chemistry is problematic or impossible to sample. Otherwise, complex calculations of averaging cumulate layers must be utilised, which is a complex process. Alternatively, the magma composition can be estimated by assuming certain conditions of magma chemistry and testing them on phase diagrams using measured mineral chemistry. These methods work fairly well for cumulates formed in volcanic conditions (i.e.; komatiites). Investigating magma conditions of large layered ultramafic intrusions is more fraught with problems.

These methods have their drawbacks, primarily that they must all make certain assumptions which rarely hold true in nature. The foremost problem is that in large ultramafic intrusions, assimilation of wall rocks tends to alter the chemistry of the melt as time progresses, so measuring groundmass compositions may fall short. Mass balance calculations will show deviations from expected ranges, which may infer assimilation has occurred, but then further chemistry must be embarked upon to quantify these findings.

Secondly, large ultramafic intrusions are rarely sealed systems and may be subject to regular injections of fresh, primitive magma, or to loss of volume due to further upward migration of the magma (possibly to feed volcanic vents or dyke swarms). In such cases, calculating magma chemistries may resolve nothing more than the presence of these two processes having affected the intrusion.

Though crystallized at high temperature, cumulate can remelt when later intruded by a sill or dyke of magma. [4]

Economic importance

The economic importance of cumulate rocks is best represented by three classes of mineral deposits found in ultramafic to mafic layered intrusions.

Silicate mineral cumulates

Silicate minerals are rarely sufficiently valuable to warrant extraction as ore. However, some anorthosite intrusions contain such pure anorthite concentrations that they are mined for feldspar, for use in refractories, glassmaking, semiconductors and other sundry uses (toothpaste, cosmetics, etc.).

Oxide mineral cumulates

Dark layers of chromite-rich cumulate rock alternating with light layers of plagioclase-rich rock in the Bushveld Igneous Complex, South Africa Chromitite Bushveld South Africa.jpg
Dark layers of chromite-rich cumulate rock alternating with light layers of plagioclase-rich rock in the Bushveld Igneous Complex, South Africa

Oxide mineral cumulates form in layered intrusions when fractional crystallisation has progressed enough to allow the crystallisation of oxide minerals which are invariably a form of spinel. This can happen due to fractional enrichment of the melt in iron, titanium or chromium.

These conditions are created by the high-temperature fractionation of highly magnesian olivine or pyroxene, which causes a relative iron-enrichment in the residual melt. When the iron content of the melt is sufficiently high, magnetite or ilmenite crystallise and, due to their high density, form cumulate rocks. Chromite is generally formed during pyroxene fractionation at low pressures, where chromium is rejected from the pyroxene crystals.

These oxide layers form laterally continuous deposits of rocks containing in excess of 50% oxide minerals. When oxide minerals exceed 90% of the bulk of the interval the rock may be classified according to the oxide mineral, for example magnetitite, ilmenitite or chromitite. Strictly speaking, these would be magnetite orthocumulate, ilmenite orthocumulate and chromite orthocumulates.

Sulfide mineral segregations

Sulfide mineral cumulates in layered intrusions are an important source of nickel, copper, platinum group elements and cobalt. Deposits of a mixed massive or mixed sulfide-silicate 'matrix' of pentlandite, chalcopyrite, pyrrhotite and/or pyrite are formed, occasionally with cobaltite and platinum-tellurium sulfides. These deposits are formed by melt immiscibility between sulfide and silicate melts in a sulfur-saturated magma.

They are not strictly a cumulate rock, as the sulfide is not precipitated as a solid mineral, but rather as immiscible sulfide liquid. However, they are formed by the same processes and accumulate due to their high specific gravity, and can form laterally extensive sulfide 'reefs'. The sulfide minerals generally form an interstitial matrix to a silicate cumulate.

Sulfide mineral segregations can only be formed when a magma attains sulfur saturation. In mafic and ultramafic rocks they form economic nickel, copper and platinum group (PGE) deposits because these elements are chalcophile and are strongly partitioned into the sulfide melt. In rare cases, felsic rocks become sulfur saturated and form sulfide segregations. In this case, the typical result is a disseminated form of sulfide mineral, usually a mixture of pyrrhotite, pyrite and chalcopyrite, forming copper mineralisation. It is very rare but not unknown to see cumulate sulfide rocks in granitic intrusions.

See also

Related Research Articles

<span class="mw-page-title-main">Gabbro</span> Coarse-grained mafic intrusive rock

Gabbro is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is chemically equivalent to rapid-cooling, fine-grained basalt. Much of the Earth's oceanic crust is made of gabbro, formed at mid-ocean ridges. Gabbro is also found as plutons associated with continental volcanism. Due to its variant nature, the term gabbro may be applied loosely to a wide range of intrusive rocks, many of which are merely "gabbroic". By rough analogy, gabbro is to basalt as granite is to rhyolite.

<span class="mw-page-title-main">Dunite</span> Ultramafic and ultrabasic rock from Earths mantle which is made of the mineral olivine

Dunite, also known as olivinite, is an intrusive igneous rock of ultramafic composition and with phaneritic (coarse-grained) texture. The mineral assemblage is greater than 90% olivine, with minor amounts of other minerals such as pyroxene, chromite, magnetite, and pyrope. Dunite is the olivine-rich endmember of the peridotite group of mantle-derived rocks.

<span class="mw-page-title-main">Anorthosite</span> Mafic intrusive igneous rock composed predominantly of plagioclase

Anorthosite is a phaneritic, intrusive igneous rock characterized by its composition: mostly plagioclase feldspar (90–100%), with a minimal mafic component (0–10%). Pyroxene, ilmenite, magnetite, and olivine are the mafic minerals most commonly present.

<span class="mw-page-title-main">Peridotite</span> Coarse-grained ultramafic igneous rock type

Peridotite ( PERR-ih-doh-tyte, pə-RID-ə-) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.

<span class="mw-page-title-main">Pyroxenite</span> Igneous rock

Pyroxenite is an ultramafic igneous rock consisting essentially of minerals of the pyroxene group, such as augite, diopside, hypersthene, bronzite or enstatite. Pyroxenites are classified into clinopyroxenites, orthopyroxenites, and the websterites which contain both types of pyroxenes. Closely allied to this group are the hornblendites, consisting essentially of hornblende and other amphiboles.

<span class="mw-page-title-main">Ultramafic rock</span> Type of igneous and meta-igneous rock

Ultramafic rocks are igneous and meta-igneous rocks with a very low silica content, generally >18% MgO, high FeO, low potassium, and are composed of usually greater than 90% mafic minerals. The Earth's mantle is composed of ultramafic rocks. Ultrabasic is a more inclusive term that includes igneous rocks with low silica content that may not be extremely enriched in Fe and Mg, such as carbonatites and ultrapotassic igneous rocks.

<span class="mw-page-title-main">Lamprophyre</span> Ultrapotassic igneous rocks

Lamprophyres are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium.

<span class="mw-page-title-main">Komatiite</span> Ultramafic mantle-derived volcanic rock

Komatiite is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% magnesium oxide (MgO). It is classified as a 'picritic rock'. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite was named for its type locality along the Komati River in South Africa, and frequently displays spinifex texture composed of large dendritic plates of olivine and pyroxene.

<span class="mw-page-title-main">Picrite basalt</span> Variety of high-magnesium basalt that is very rich in the mineral olivine

Picrite basalt or picrobasalt is a variety of high-magnesium olivine basalt that is very rich in the mineral olivine. It is dark with yellow-green olivine phenocrysts (20-50%) and black to dark brown pyroxene, mostly augite.

<span class="mw-page-title-main">Eucrite</span> Achondritic stony meteorite

Eucrites are achondritic stony meteorites, many of which originate from the surface of the asteroid 4 Vesta and are part of the HED meteorite clan. They are the most common achondrite group with over 100 meteorites found.

<span class="mw-page-title-main">Layered intrusion</span>

A layered intrusion is a large sill-like body of igneous rock which exhibits vertical layering or differences in composition and texture. These intrusions can be many kilometres in area covering from around 100 km2 (39 sq mi) to over 50,000 km2 (19,000 sq mi) and several hundred metres to over one kilometre (3,300 ft) in thickness. While most layered intrusions are Archean to Proterozoic in age, they may be any age such as the Cenozoic Skaergaard intrusion of east Greenland or the Rum layered intrusion in Scotland. Although most are ultramafic to mafic in composition, the Ilimaussaq intrusive complex of Greenland is an alkalic intrusion.

In geology, igneous differentiation, or magmatic differentiation, is an umbrella term for the various processes by which magmas undergo bulk chemical change during the partial melting process, cooling, emplacement, or eruption. The sequence of magmas produced by igneous differentiation is known as a magma series.

The tholeiitic magma series is one of two main magma series in subalkaline igneous rocks, the other being the calc-alkaline series. A magma series is a chemically distinct range of magma compositions that describes the evolution of a mafic magma into a more evolved, silica rich end member. Rock types of the tholeiitic magma series include tholeiitic basalt, ferro-basalt, tholeiitic basaltic andesite, tholeiitic andesite, dacite and rhyolite. The variety of basalt in the series was originally called tholeiite but the International Union of Geological Sciences recommends that tholeiitic basalt be used in preference to that term.

Normative mineralogy is a calculation of the composition of a rock sample that estimates the idealised mineralogy of a rock based on a quantitative chemical analysis according to the principles of geochemistry.

<span class="mw-page-title-main">Fractional crystallization (geology)</span> Process of rock formation

Fractional crystallization, or crystal fractionation, is one of the most important geochemical and physical processes operating within crust and mantle of a rocky planetary body, such as the Earth. It is important in the formation of igneous rocks because it is one of the main processes of magmatic differentiation. Fractional crystallization is also important in the formation of sedimentary evaporite rocks or simply fractional crystallization is the removal of early formed crystals from an Original homogeneous magma so that the crystals are prevented from further reaction with the residual melt.

<span class="mw-page-title-main">Harzburgite</span> Ultramafic mantle rock


Harzburgite, an ultramafic, igneous rock, is a variety of peridotite consisting mostly of the two minerals olivine and low-calcium (Ca) pyroxene (enstatite); it is named for occurrences in the Harz Mountains of Germany. It commonly contains a few percent chromium-rich spinel as an accessory mineral. Garnet-bearing harzburgite is much less common, found most commonly as xenoliths in kimberlite.

<span class="mw-page-title-main">Merensky Reef</span> Layer of igneous rock in the Bushveld igneous complex, South Africa

The Merensky Reef is a layer of igneous rock in the Bushveld Igneous Complex (BIC) in the North West, Limpopo, Gauteng and Mpumalanga provinces of South Africa which together with an underlying layer, the Upper Group 2 Reef (UG2), contains most of the world's known reserves of platinum group metals (PGMs) or platinum group elements (PGEs)—platinum, palladium, rhodium, ruthenium, iridium and osmium. The Reef is 46 cm thick and bounded by thin chromite seams or stringers. The composition consists predominantly of cumulate rocks, including leuconorite, anorthosite, chromitite, and melanorite.

<span class="mw-page-title-main">Chromitite</span> Rock composed mostly of the mineral chromite

Chromitite is an igneous cumulate rock composed mostly of the mineral chromite. It is found in layered intrusions such as the Bushveld Igneous Complex in South Africa, the Stillwater igneous complex in Montana and the Ring of Fire discovery in Ontario.

<span class="mw-page-title-main">Igneous rock</span> Rock formed through the cooling and solidification of magma or lava

Igneous rock, or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava.

<span class="mw-page-title-main">Southern Oklahoma Aulacogen</span> Failed rift in the western and southern US of the triple junction that became the Iapetus Ocean

The Southern Oklahoma Aulacogen is a failed rift, or failed rift arm (aulacogen), of the triple junction that became the Iapetus Ocean spreading ridges. It is a significant geological feature in the Western and Southern United States. It formed sometime in the early to mid Cambrian Period and spans the Wichita Mountains, Taovayan Valley, Anadarko Basin, and Hardeman Basin in Southwestern Oklahoma. The Southern Oklahoma Aulacogen is primarily composed of basaltic dikes, gabbros, and units of granitic rock.

References

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  2. Chadwick, J. P.; Troll, V. R.; Waight, T. E.; van der Zwan, F. M.; Schwarzkopf, L. M. (2013-02-01). "Petrology and geochemistry of igneous inclusions in recent Merapi deposits: a window into the sub-volcanic plumbing system" . Contributions to Mineralogy and Petrology. 165 (2): 259–282. Bibcode:2013CoMP..165..259C. doi:10.1007/s00410-012-0808-7. ISSN   1432-0967. S2CID   128817557.
  3. 1 2 Hall, Anthony, Igneous Petrology, 1987, Longman, p. 228-231, ISBN   0-582-30174-2
  4. J. Leuthold, J. C. Lissenberg, B. O’Driscoll, O. Karakas; T. Falloon, D.N. Klimentyeva, P. Ulmer (2018); Partial melting of the lower oceanic crust at spreading ridges. Frontiers in Earth Sciences: Petrology: 6(15): 20p; https://dx.doi.org/10.3389/feart.2018.00015

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