Sapphirine

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Sapphirine
Sapphirine-203257.jpg
Indigo-blue sapphirine crystal from Ft. Dauphin, Madagascar (size: 2.1 x 1.9 x 1.4 cm)
General
Category Silicate mineral
Formula
(repeating unit)
(Mg,Al)8(Al,Si)6O20
IMA symbol Spr [1]
Strunz classification 9.DH.45
Crystal system 2M polytype: monoclinic
1A polytype: triclinic
Crystal class 2M polytype: prismatic (2/m)
1A polytype: pinacoidal (1)
Space group 1A polytype: P1
Other polytypes: 3A, 5A, 2M, 4M
Unit cell a = 11.27  Å, b = 14.4 Å
c = 9.93 Å; β = 125.5°; Z = 4
Identification
ColourLight to dark blue or green, white, gray, pale red, yellow
Crystal habit Anhedral, granular, tabular
Twinning Uncommon on {001}
Cleavage Poor to indistinct on {100}, {001}, and {010}
Fracture Subconchoidal to uneven
Mohs scale hardness7.5
Lustre Vitreous
Streak White
Diaphaneity Transparent to translucent
Specific gravity 3.403.58
Optical propertiesBiaxial (-)
Refractive index nα = 1.701 - 1.729 nβ = 1.703 - 1.732 nγ = 1.705 - 1.734
Birefringence δ = 0.004 - 0.005
Pleochroism X = colorless, pale reddish, yellowish green, pale yellow; Y = sky-blue, lavender-blue, bluish green; Z = blue, sapphire-blue, dark blue
2V angle Measured: 47 to 114°
References [2] [3] [4]

Sapphirine is a rare mineral, a silicate of magnesium and aluminium with the chemical formula ( Mg,Al)8(Al,Si)6 O 20 (with iron as a major impurity). Named for its sapphire-like colour, sapphirine is primarily of interest to researchers and collectors: well-formed crystals are treasured and occasionally cut into gemstones. Sapphirine has also been synthesized for experimental purposes via a hydrothermal process.

Contents

Properties

Sapphirine from Madagascar Sapphirine (Madagascar).jpg
Sapphirine from Madagascar

Typical colours range from light to dark sapphire blue, bluish to brownish green, green, and bluish or greenish gray to black; less common colours include yellow, pale red, and pink to purplish pink. Sapphirine is relatively hard (7.5 on Mohs scale), usually transparent to translucent, with a vitreous lustre. Crystallising in the monoclinic system, sapphirine is typically anhedral or granular in habit, but may also be tabular or in aggregates: Twinning is uncommon. Fracture is subconchoidal to uneven, and there is one direction of perfect cleavage. The specific gravity of sapphirine is 3.543.51, and its streak is white.

Sapphirine's refractive index (as measured by monochromatic sodium light, 589.3 nm) ranges from 1.701 to 1.718 with a birefringence of 0.0060.007, biaxial negative. Refractive index values may correspond to colour: brownish green specimens will possess the highest values, purplish-pink specimens the lowest, and blue specimens will be intermediate between them. Pleochroism may be extreme, with trichroic colours ranging from: colourless, pale yellow or red; sky to lavender blue, or bluish-green; to dark blue. There is no reaction under ultraviolet light.

Formation and occurrence

While there is evidence of magmatic origin in some deposits, sapphirine is primarily a product of high grade metamorphism in environments poor in silica and rich in magnesium and aluminium. However, sapphirine occurs in a variety of rocks, including granulite and amphibolite facies, calc-silicate skarns, and quartzites; it is also known from xenoliths. Associated minerals include: calcite, chrysoberyl, cordierite, corundum, garnet, kornerupine, kyanite, phlogopite, scapolite, sillimanite, spinel, and surinamite.

Large crystals of fine clarity and colour are known from very few locales: The Central Province (Hakurutale and Munwatte) of Sri Lanka has long been known as a source of facetable greenish blue to dark blue material, and crystals up to 30 mm or more in size have been found in Fianarantsoa (Betroka District) and Toliara Province (Androy and Anosy regions), southern Madagascar. Sapphirine's type locality is Fiskenaesset (Fiskenaes), Nuuk region, western Greenland, which is where the mineral was discovered in 1819.

Other notable localities include: Western Hoggar, Algeria; the Napier complex of Enderby Land and the Vestfold Hills of Antarctica; Delegate, New South Wales and the Strangways Range of the Northern Territory, Australia; Wilson Lake, Labrador; Donghai, Jiangsu province, China; Kittilä, Lapland, Finland; Ariège, Midi-Pyrénées, France; Waldheim, Saxony, Germany; Dora Maira Massif, Province of Cuneo, Piedmont, Italy; Ulstein, Møre og Romsdal, and Meløy, Nordland, Norway; the Messina District of Limpopo Province and the Okiep Copper District of Northern Cape Province, South Africa; Falkenberg Municipality, Halland County, Sweden; Mautia Hill in the Kongwa region of Central Province, Tanzania; Isle of Harris, Outer Hebrides, Scotland; the Bani Hamid area of Semail Ophiolite, United Arab Emirates; the Dome Rock Mountains of La Paz County, Arizona, Stockdale, Riley County, Kansas; Cortlandt, New York; and Clay County, North Carolina; India The Eastern Ghats Mobile Belt.

Thin inner rim of sapphirine (Sa, light blue) associated with a garnet outer rim (Gt, light pink) in a coronite having crystallized in between green spinel (Sp) and Al-rich clinopyroxene. Sapphirine coronite.jpg
Thin inner rim of sapphirine (Sa, light blue) associated with a garnet outer rim (Gt, light pink) in a coronite having crystallized in between green spinel (Sp) and Al-rich clinopyroxene.

Sapphirine was also reported as a reaction product (together with garnet) in between Mg-Al-spinel and Ca-Tschermak-rich clinopyroxene in corundum-bearing mantle pyroxenites [5]  ·. [6]


Related Research Articles

<span class="mw-page-title-main">Corundum</span> Oxide mineral

Corundum is a crystalline form of aluminium oxide typically containing traces of iron, titanium, vanadium, and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. Corundum has two primary gem varieties: ruby and sapphire. Rubies are red due to the presence of chromium, and sapphires exhibit a range of colors depending on what transition metal is present. A rare type of sapphire, padparadscha sapphire, is pink-orange.

<span class="mw-page-title-main">Gemstone</span> Piece of mineral crystal used to make jewelry

A gemstone is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks and occasionally organic materials that are not minerals are also used for jewelry and are therefore often considered to be gemstones as well. Most gemstones are hard, but some soft minerals are used in jewelry because of their luster or other physical properties that have aesthetic value. Rarity and notoriety are other characteristics that lend value to gemstones.

<span class="mw-page-title-main">Spinel</span> Mineral or gemstone

Spinel is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl
2
O
4
in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals.

<span class="mw-page-title-main">Tourmaline</span> Cyclosilicate mineral group

Tourmaline is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a wide variety of colors.

<span class="mw-page-title-main">Chrysoberyl</span> Mineral or gemstone of beryllium aluminate

The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula BeAl2O4. The name chrysoberyl is derived from the Greek words χρυσός chrysos and βήρυλλος beryllos, meaning "a gold-white spar". Despite the similarity of their names, chrysoberyl and beryl are two completely different gemstones, although they both contain beryllium. Chrysoberyl is the third-hardest frequently encountered natural gemstone and lies at 8.5 on the Mohs scale of mineral hardness, between corundum (9) and topaz (8).

Lustre is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the Latin lux, meaning "light", and generally implies radiance, gloss, or brilliance.

<span class="mw-page-title-main">Skarn</span> Hard, coarse-grained, hydrothermally altered metamorphic rocks

Skarns or tactites are coarse-grained metamorphic rocks that form by replacement of carbonate-bearing rocks during regional or contact metamorphism and metasomatism. Skarns may form by metamorphic recrystallization of impure carbonate protoliths, bimetasomatic reaction of different lithologies, and infiltration metasomatism by magmatic-hydrothermal fluids. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals. These minerals form as a result of alteration which occurs when hydrothermal fluids interact with a protolith of either igneous or sedimentary origin. In many cases, skarns are associated with the intrusion of a granitic pluton found in and around faults or shear zones that commonly intrude into a carbonate layer composed of either dolomite or limestone. Skarns can form by regional or contact metamorphism and therefore form in relatively high temperature environments. The hydrothermal fluids associated with the metasomatic processes can originate from a variety of sources; magmatic, metamorphic, meteoric, marine, or even a mix of these. The resulting skarn may consist of a variety of different minerals which are highly dependent on both the original composition of the hydrothermal fluid and the original composition of the protolith.

<span class="mw-page-title-main">Peridotite</span> Coarse-grained ultramafic igneous rock type

Peridotite ( PERR-ih-doh-tyte, pə-RID-ə-) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.

<span class="mw-page-title-main">Asterism (gemology)</span>

An asterism is a star-shaped concentration of light reflected or refracted from a gemstone. It can appear when a suitable stone is cut en cabochon.

<span class="mw-page-title-main">Cordierite</span> Mg, Fe, Al cyclosilicate mineral

Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: (Mg,Fe)2Al3(Si5AlO18) to (Fe,Mg)2Al3(Si5AlO18). A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the (Si,Al)6O18 rings.

<span class="mw-page-title-main">Pyroxenite</span> Igneous rock

Pyroxenite is an ultramafic igneous rock consisting essentially of minerals of the pyroxene group, such as augite, diopside, hypersthene, bronzite or enstatite. Pyroxenites are classified into clinopyroxenites, orthopyroxenites, and the websterites which contain both types of pyroxenes. Closely allied to this group are the hornblendites, consisting essentially of hornblende and other amphiboles.

<span class="mw-page-title-main">Hornfels</span>

Hornfels is the group name for a set of contact metamorphic rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These properties are caused by fine grained non-aligned crystals with platy or prismatic habits, characteristic of metamorphism at high temperature but without accompanying deformation. The term is derived from the German word Hornfels, meaning "hornstone", because of its exceptional toughness and texture both reminiscent of animal horns. These rocks were referred to by miners in northern England as whetstones.

<span class="mw-page-title-main">Diamond simulant</span> Diamond-like object which is not a diamond

A diamond simulant, diamond imitation or imitation diamond is an object or material with gemological characteristics similar to those of a diamond. Simulants are distinct from synthetic diamonds, which are actual diamonds exhibiting the same material properties as natural diamonds. Enhanced diamonds are also excluded from this definition. A diamond simulant may be artificial, natural, or in some cases a combination thereof. While their material properties depart markedly from those of diamond, simulants have certain desired characteristics—such as dispersion and hardness—which lend themselves to imitation. Trained gemologists with appropriate equipment are able to distinguish natural and synthetic diamonds from all diamond simulants, primarily by visual inspection.

<span class="mw-page-title-main">Pyrope</span> Mineral of the garnet group

The mineral pyrope is a member of the garnet group. Pyrope is the only member of the garnet family to always display red colouration in natural samples, and it is from this characteristic that it gets its name: from the Greek words for fire and eye. Despite being less common than most garnets, it is a widely used gemstone with numerous alternative names, some of which are misnomers. Chrome pyrope, and Bohemian garnet are two alternative names, the usage of the latter being discouraged by the Gemological Institute of America. Misnomers include Colorado ruby, Arizona ruby, California ruby, Rocky Mountain ruby, Elie Ruby, Bohemian carbuncle, and Cape ruby.

<span class="mw-page-title-main">Hauyne</span> Tectosilicate mineral with sometimes a blue colour due to a cyclic trisulfide anion

Hauyne or haüyne, also called hauynite or haüynite, is a tectosilicate sulfate mineral with endmember formula Na3Ca(Si3Al3)O12(SO4). As much as 5 wt % K2O may be present, and also H2O and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in Monte Somma, Italy, and was named in 1807 by Brunn-Neergard for the French crystallographer René Just Haüy (1743–1822). It is sometimes used as a gemstone.

<span class="mw-page-title-main">Metamorphic facies</span> Set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures

A metamorphic facies is a set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures. The assemblage is typical of what is formed in conditions corresponding to an area on the two dimensional graph of temperature vs. pressure. Rocks which contain certain minerals can therefore be linked to certain tectonic settings, times and places in the geological history of the area. The boundaries between facies are wide because they are gradational and approximate. The area on the graph corresponding to rock formation at the lowest values of temperature and pressure is the range of formation of sedimentary rocks, as opposed to metamorphic rocks, in a process called diagenesis.

<span class="mw-page-title-main">Gemstone industry in Greenland</span>

Gemstones have been found in Greenland, including diamond, ruby, sapphire, kornerupine, tugtupite, lapis lazuli, amazonite, peridot, quartz, spinel, topaz, and tourmaline. Most of Greenland's ruby and sapphire occurrences are located near the village of Fiskenaesset/Qeqertarsuatsiaat on the southwest coast.

<span class="mw-page-title-main">Keatite</span>

Keatite is a silicate mineral with the chemical formula SiO2 (silicon dioxide) that was discovered in nature in 2013. It is a tetragonal polymorph of silica first known as a synthetic phase. It was reported as minute inclusions within clinopyroxene (diopside) crystals in an ultra high pressure garnet pyroxenite body. The host rock is part of the Kokchetav Massif in Kazakhstan.

<span class="mw-page-title-main">Luca Bindi</span>

Luca Bindi is an Italian geologist. He holds the Chair of Mineralogy and Crystallography and is the Head of the Department of Earth Sciences of the University of Florence. He is also a research associate at the Istituto di Geoscienze e Georisorse of the National Research Council (Italy) (CNR). He has received national and international scientific awards that include the President of the Republic Prize 2015 in the category of Physical, Mathematical and Natural Sciences. Since 2019 is a Member of the National Academy of Lincei.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Handbook of Mineralogy" (PDF). Archived from the original (PDF) on 2021-11-25. Retrieved 2011-10-23.
  3. Mindat.org
  4. Webmineral data
  5. Kornprobst J., Piboule M., Boudeulle M. & Roux L.- 1982. Corundum-bearing pyroxenites at Beni Bousera (Morocco): an exceptionally Al-rich clinopyroxene from « grospydites » associated with ultramafic rocks. IIId Int. Kimberlites Conf., Terra Cognita, 2, 3, 257-259
  6. Kornprobst J., Piboule M., Roden M. & Tabit A.- 1990. Corundum-bearing garnet clinopyroxenites at Beni Bousera (Morocco): original plagioclase-rich gabbros recrystallized at depth within the mantle ? J. Petrology, 31, 3, 717-745