Anorthoclase

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Anorthoclase
Anorthoclase-tn23a.jpg
Doubly terminated anorthoclase crystal from Kinki Region, Honshu, Japan. Size: 1.3 cm × 0.9 cm × 0.7 cm (0.5 in × 0.4 in × 0.3 in)
General
Category Feldspar
Formula
(repeating unit)
(Na,K)AlSi3O8
IMA symbol Ano [1]
Strunz classification 9.FA.30
Crystal system Triclinic
Crystal class Pinacoidal (1)
(same H–M symbol)
Space group C1
Unit cell a = 8.28, b = 12.97
c = 7.15 [Å]; α = 91.05°
β = 116.26°, γ = 90.15°; Z = 4
Identification
ColorColorless, also white, pale creamy yellow, red, green
Crystal habit Short prismatic crystals; tabular, rhombic, flattened along [010]
Twinning Polysynthetic twinning produces a grid pattern on [100]
Cleavage Perfect on [001], other partings
Fracture Uneven
Tenacity Brittle
Mohs scale hardness6
Luster Vitreous to pearly on cleavage planes
Streak White
Diaphaneity Transparent
Specific gravity 2.57–2.60
Optical propertiesBiaxial (−)
Refractive index nα = 1.519–1.529
nβ = 1.524–1.534
nγ = 1.527–1.536
Birefringence δ = 0.008
2V angle Measured: 34°–60°
References [2] [3] [4]

The mineral anorthoclase ((Na,K)AlSi3O8) is a crystalline solid solution in the alkali feldspar series, in which the sodium-aluminium silicate member exists in larger proportion. It typically consists of between 10 and 36 percent of KAlSi3O8 and between 64 and 90 percent of NaAlSi3O8. [5]

Contents

An anorthoclase crystal from Mount Erebus, Antarctica Anorthoclase-219058.jpg
An anorthoclase crystal from Mount Erebus, Antarctica

Structure and stability

Anorthoclase is an intermediate member of the high albitesanidine alkali feldspar solid solution series. Intermediate members of this series, high albite, anorthoclase and high sodium sanidine are stable at temperatures of 600 °C (1,100 °F) and above. Below 400–600 °C (800–1,100 °F) only very limited solution exists (less than about 5% on both the low albite and microcline ends). [6] Anorthoclase and high albite exhibit triclinic symmetry, whereas sanidine and the low temperature orthoclase have monoclinic symmetry. [6] If the high temperature intermediate composition alkali feldspars are allowed to cool slowly, exsolution occurs and a perthite structure results. [6]

Occurrence

Anorthoclase occurs in high temperature sodium rich volcanic and hypabyssal (shallow intrusive) rocks. The mineral is typically found as a constituent of the fine grained matrix or as small phenocrysts which may occur as loose crystals in a weathered rock. [2]

It was first described in 1885 for an occurrence on Pantelleria Island, Trapani Province, Sicily. The name is from the Greek αν-, ορθός and κλάσις (not cleaving at right-angles), for its oblique cleavage. [2] [3]

See also

Related Research Articles

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

<span class="mw-page-title-main">Feldspar</span> Group of rock-forming minerals

Feldspar is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the plagioclase (sodium-calcium) feldspars and the alkali (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight.

<span class="mw-page-title-main">Orthoclase</span> Tectosilicate mineral found in igneous rock

Orthoclase, or orthoclase feldspar (endmember formula KAlSi3O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar. The gem known as moonstone (see below) is largely composed of orthoclase.

<span class="mw-page-title-main">Microcline</span> Igneous rock-forming tectosilicate mineral

Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during slow cooling of orthoclase; it is more stable at lower temperatures than orthoclase. Sanidine is a polymorph of alkali feldspar stable at yet higher temperature. Microcline may be clear, white, pale-yellow, brick-red, or green; it is generally characterized by cross-hatch twinning that forms as a result of the transformation of monoclinic orthoclase into triclinic microcline.

<span class="mw-page-title-main">Plagioclase</span> Type of feldspar

Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more properly known as the plagioclase feldspar series. This was first shown by the German mineralogist Johann Friedrich Christian Hessel (1796–1872) in 1826. The series ranges from albite to anorthite endmembers (with respective compositions NaAlSi3O8 to CaAl2Si2O8), where sodium and calcium atoms can substitute for each other in the mineral's crystal lattice structure. Plagioclase in hand samples is often identified by its polysynthetic crystal twinning or "record-groove" effect.

<span class="mw-page-title-main">Amphibole</span> Group of inosilicate minerals

Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4
tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.

<span class="mw-page-title-main">Anorthite</span> Calcium-rich feldspar mineral

Anorthite is the calcium endmember of the plagioclase feldspar mineral series. The chemical formula of pure anorthite is CaAl2Si2O8. Anorthite is found in mafic igneous rocks. Anorthite is rare on the Earth but abundant on the Moon.

<span class="mw-page-title-main">Trachyte</span> Extrusive igneous rock

Trachyte is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and alkali metals. It is the volcanic equivalent of syenite.

<span class="mw-page-title-main">Augite</span> Common rock-forming pyroxene mineral

Augite is a common rock-forming pyroxene mineral with formula (Ca,Na)(Mg,Fe,Al,Ti)(Si,Al)2O6. The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees.

<span class="mw-page-title-main">Nepheline syenite</span> Holocrystalline plutonic rock

Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.

<span class="mw-page-title-main">Albite</span> Mineral, Na-feldspar, Na-silicate, tectosilicate

Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula NaAlSi
3
O
8
. It is a tectosilicate. Its color is usually pure white, hence its name from Latin, albus. It is a common constituent in felsic rocks.

<span class="mw-page-title-main">Silicate mineral</span> Rock-forming minerals with predominantly silicate anions

Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.

<span class="mw-page-title-main">Perthite</span> Intergrowth of two feldspars

Perthite is used to describe an intergrowth of two feldspars: a host grain of potassium-rich alkali feldspar (near K-feldspar, KAlSi3O8, in composition) includes exsolved lamellae or irregular intergrowths of sodic alkali feldspar (near albite, NaAlSi3O8, in composition). Typically, the host grain is orthoclase or microcline, and the lamellae are albite. If sodic feldspar is the dominant phase, the result is an antiperthite and where the feldspars are in roughly equal proportions the result is a mesoperthite.

<span class="mw-page-title-main">Oligoclase</span> Sodium-rich plagioclase feldspar mineral

Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite (NaAlSi3O8) and anorthite (CaAl2Si2O8). The albite:anorthite molar ratio of oligoclase ranges from 90:10 to 70:30.

<span class="mw-page-title-main">Sanidine</span>

Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system. Orthoclase is a monoclinic polymorph stable at lower temperatures. At yet lower temperatures, microcline, a triclinic polymorph of potassium feldspar, is stable.

A solid solution, a term popularly used for metals, is a homogeneous mixture of two different kinds of atoms in solid state and having a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solution" is used to describe the intimate mixing of components at the atomic level and distinguishes these homogeneous materials from physical mixtures of components. Two terms are mainly associated with solid solutions – solvents and solutes, depending on the relative abundance of the atomic species.

<span class="mw-page-title-main">Hauyne</span> Tectosilicate mineral with sometimes a blue colour due to a cyclic trisulfide anion

Hauyne or haüyne, also called hauynite or haüynite, is a tectosilicate sulfate mineral with endmember formula Na3Ca(Si3Al3)O12(SO4). As much as 5 wt % K2O may be present, and also H2O and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in Monte Somma, Italy, and was named in 1807 by Brunn-Neergard for the French crystallographer René Just Haüy (1743–1822). It is sometimes used as a gemstone.

In subsolvus or two feldspar granites crystallisation occurs at high water pressures resulting in the formation of two types of feldspar as opposed to hypersolvus granites in which crystallization at relatively low water pressures results in the formation of a single feldspar variety. Quoting Tuttle and Bowen in 1958 : ″A classification of salic rocks based on the nature of the alkali feldspar is proposed. The classification has two major divisions: (1) subsolidus, and (2) hypersolvus, depending on the whereabouts of the soda feldspar. In the hypersolvus rocks all the soda feldspar is or was in solid solution in the potash feldspar whereas in the subsolvus rocks the plagioclase is present as discrete grains. The two major divisions are further subdivided according to the nature of the alkali feldspar modification.″ Note that here the word "subsolidus" unfortunately looks like a misprint and probably has to be replaced by "subsolvus".

<span class="mw-page-title-main">Moonstone (gemstone)</span> Semi-precious gemstone

Moonstone is a sodium potassium aluminium silicate ((Na,K)AlSi3O8) of the feldspar group that displays a pearly and opalescent schiller. An alternative name for moonstone is hecatolite.

<span class="mw-page-title-main">Rubicline</span>

Rubicline, also referred to as Rb-microcline, is the rubidium analogue of microcline, an important tectosilicate mineral. Its chemical formula is (Rb, K)[AlSi3O8] with an ideal composition of RbAlSi3O8. Chemical analysis by electron microprobe indicated the average weight of the crystal is 56.66% SiO2, 16.95% Al2O3, and 23.77% Rb2O, along with trace amounts of caesium oxide (Cs2O) and iron(III) oxide (Fe2O3).

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 "Handbook of Mineralogy" (PDF). Archived from the original (PDF) on 2016-03-04. Retrieved 2011-12-04.
  3. 1 2 "Mindat.org".
  4. "Webmineral data".
  5. Deere; Howie; Zussman. Framework Silicates. Rock Forming Minerals. Vol. 4. Wiley. pp. 2–5, Fig. 1.
  6. 1 2 3 Klein, Cornelis; Hurlbut, Cornelius S. Jr. Handbook of Mineralogy. Wiley. pp. 446–449, Fig. 11-95. ISBN   0-471-80580-7.