Hedenbergite

Last updated
Hedenbergite
Hedenbergite-Quartz-Hematite-54421.jpg
General
Category Pyroxenes
Formula
(repeating unit)
Ca Fe Si 2 O 6
IMA symbol Hd [1]
Strunz classification 9.DA.15
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group C2/c
Identification
Formula mass 248.09 g/mol
Colorbrownish green, black
Crystal habit massive, prismatic crystals
Cleavage Good on {110}
Fracture Irregular
Tenacity Brittle
Mohs scale hardness5.5–6.5
Luster Vitreous, dull
Streak white, gray
Diaphaneity Transparent-Opaque
Density 3.56 g/cm3
Optical propertiesBiaxial (+)
Refractive index nα = 1.699 – 1.739 nβ = 1.705 – 1.745 nγ = 1.728 – 1.757
Birefringence δ = 0.029
Pleochroism Weak
Dispersion r > v strong
References [2] [3]

Hedenbergite, Ca Fe Si 2 O 6, is the iron rich end member of the pyroxene group having a monoclinic crystal system. The mineral is extremely rarely found as a pure substance, and usually has to be synthesized in a lab. It was named in 1819 after M.A. Ludwig Hedenberg, who was the first to define hedenbergite as a mineral. Contact metamorphic rocks high in iron are the primary geologic setting for hedenbergite. This mineral is unique because it can be found in chondrites and skarns (calc–silicate metamorphic rocks). Since it is a member of the pyroxene family, there is a great deal of interest in its importance to general geologic processes.

Contents

Properties

Spray of variegated green and lustrous Hedenbergite crystals to 9 cm (3.5 in) with rounded garnets Hedenbergite-Garnet-Group-36942.jpg
Spray of variegated green and lustrous Hedenbergite crystals to 9 cm (3.5 in) with rounded garnets

Hedenbergite has a number of specific properties. Its hardness is usually between five and six with two cleavage plains and conchoidal fracture. Color varies between black, greenish black, and dark brown with a resinous luster. Hedenbergite is a part of a pyroxene solid solution chain consisting of diopside and augite, and is the iron rich end member. One of the best indicators that you have located hedenbergite is the radiating prisms with a monoclinic crystal system. Hedenbergite is found primarily in metamorphic rocks.

Composition and structure

Pyroxene quadrilateral Pyrox names.svg
Pyroxene quadrilateral

The pyroxene quadrilateral easily records the compositions of different pyroxenes contained in igneous rocks, such as diopside, hedenbergite, enstatite, ferrosilite. [4] Hedenbergite is almost never found isolated. From the chemical formulas above, we can tell that the main differences in the compositions will be in terms of calcium, magnesium, and iron. D. H. Lindsley and J. L. Munoz (1969) did such an experiment in order to figure out exactly which combinations of temperature and pressure will cause particular minerals to combine. According to their experiment, at 1000 degrees with a pressure less than two kilobars the stable composition is a mixture of hedenbergite, olivine, and quartz. When the pressure moves to twenty kilobars, the composition moves towards the clinopyroxenes, which contains trace amounts of hedenbergite if any. For temperatures of 750 degrees Celsius, the compositions move from hedenbergite with olivine and quartz to ferrosilite with a greater amount of hedenbergite. If you combine the results of both of these sets of data, you can see that the stability of hedenbergite is more dependent on temperature as opposed to pressure.

Hedenbergite with andradite garnet from the Cyclades Andradite-Hedenbergite-20546.jpg
Hedenbergite with andradite garnet from the Cyclades

Effects of chemical composition on elasticity

Pyroxenes are essential to the geologic processes that occur in the mantle and transition zones. [5] One crystal was oriented with the C axis, and another perpendicular to the C axis. The elastic strength of a polyhedron is determined by the cation occupying the central site. [5] As the bond length of the cations and anions decreases the bond strength increases making the mineral more compact and dense. Substitution between ions like Ca2+ and Mg 2+ would not have a great effect on the resistance to compression while substitution of Si4+ would make it much harder to compress. Si4+ would be inherently stronger than Ca2+ due to the larger charge and electronegativity.

Occurrence in chondrites

Chondrites are meteorites that have experienced very little alteration by melting or differentiation since the formation of the Solar System 4.56 billion years ago. One of the most studied chondrites in existence is the Allende meteorite. Hedenbergite was found to be the most abundant secondary calcium-rich silicate phase within Allende chondules and is closely associated with other minerals such as sodalite and nepheline. [6] Kimura and Ikeda (1995) also suggest that hedenbergite formation may have been the result of the consumption of CaO and SiO2 as plagioclases decomposed into sodalite and nepheline as well as alkali-calcium exchange before the condrules' incorporation into the parent body.

Occurrence in skarns

Hedenbergite can be found in skarns. A skarn is a metamorphic rock that is formed by the chemical alterations of the original minerals by hydrothermal causes. They are formed by large chemical reactions between adjacent lithologies. The Nickel Plate gold skarn deposit of the Hedley District in southern British Columbia is characterized by hedenbergitic pyroxene. [7] [8]

See also

Related Research Articles

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Gabbro is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is chemically equivalent to rapid-cooling, fine-grained basalt. Much of the Earth's oceanic crust is made of gabbro, formed at mid-ocean ridges. Gabbro is also found as plutons associated with continental volcanism. Due to its variant nature, the term gabbro may be applied loosely to a wide range of intrusive rocks, many of which are merely "gabbroic". By rough analogy, gabbro is to basalt as granite is to rhyolite.

<span class="mw-page-title-main">Amphibole</span> Group of inosilicate minerals

Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4
tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.

<span class="mw-page-title-main">Pyroxene</span> Group of inosilicate minerals with single chains of silica tetrahedra

The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula XY(Si,Al)2O6, where X represents calcium (Ca), sodium (Na), iron or magnesium (Mg) and more rarely zinc, manganese or lithium, and Y represents ions of smaller size, such as chromium (Cr), aluminium (Al), magnesium (Mg), cobalt (Co), manganese (Mn), scandium (Sc), titanium (Ti), vanadium (V) or even iron. Although aluminium substitutes extensively for silicon in silicates such as feldspars and amphiboles, the substitution occurs only to a limited extent in most pyroxenes. They share a common structure consisting of single chains of silica tetrahedra. Pyroxenes that crystallize in the monoclinic system are known as clinopyroxenes and those that crystallize in the orthorhombic system are known as orthopyroxenes.

<span class="mw-page-title-main">Augite</span> Common rock-forming pyroxene mineral

Augite, also known as Augurite, is a common rock-forming pyroxene mineral with formula (Ca,Na)(Mg,Fe,Al,Ti)(Si,Al)2O6. The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees.

<span class="mw-page-title-main">Wüstite</span> Iron(II) oxide mineral formed under reducing conditions

Wüstite is a mineral form of mostly iron(II) oxide found with meteorites and native iron. It has a grey colour with a greenish tint in reflected light. Wüstite crystallizes in the isometric-hexoctahedral crystal system in opaque to translucent metallic grains. It has a Mohs hardness of 5 to 5.5 and a specific gravity of 5.88. Wüstite is a typical example of a non-stoichiometric compound.

<span class="mw-page-title-main">Nepheline syenite</span> Holocrystalline plutonic rock

Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.

<span class="mw-page-title-main">Skarn</span> Hard, coarse-grained, hydrothermally altered metamorphic rocks

Skarns or tactites are coarse-grained metamorphic rocks that form by replacement of carbonate-bearing rocks during regional or contact metamorphism and metasomatism. Skarns may form by metamorphic recrystallization of impure carbonate protoliths, bimetasomatic reaction of different lithologies, and infiltration metasomatism by magmatic-hydrothermal fluids. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals. These minerals form as a result of alteration which occurs when hydrothermal fluids interact with a protolith of either igneous or sedimentary origin. In many cases, skarns are associated with the intrusion of a granitic pluton found in and around faults or shear zones that commonly intrude into a carbonate layer composed of either dolomite or limestone. Skarns can form by regional or contact metamorphism and therefore form in relatively high temperature environments. The hydrothermal fluids associated with the metasomatic processes can originate from a variety of sources; magmatic, metamorphic, meteoric, marine, or even a mix of these. The resulting skarn may consist of a variety of different minerals which are highly dependent on both the original composition of the hydrothermal fluid and the original composition of the protolith.

<span class="mw-page-title-main">Chondrite</span> Class of stony meteorites made of round grains

A chondrite is a stony (non-metallic) meteorite that has not been modified, by either melting or differentiation of the parent body. They are formed when various types of dust and small grains in the early Solar System accreted to form primitive asteroids. Some such bodies that are captured in the planet's gravity well become the most common type of meteorite by arriving on a trajectory toward the planet's surface. Estimates for their contribution to the total meteorite population vary between 85.7% and 86.2%.

<span class="mw-page-title-main">Diopside</span> Pyroxene mineral

Diopside is a monoclinic pyroxene mineral with composition MgCaSi
2
O
6
. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.

<span class="mw-page-title-main">Metasomatism</span> Chemical alteration of a rock by hydrothermal and other fluids

Metasomatism is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical composition, excluding volatile components. It is the replacement of one rock by another of different mineralogical and chemical composition. The minerals which compose the rocks are dissolved and new mineral formations are deposited in their place. Dissolution and deposition occur simultaneously and the rock remains solid.

<span class="mw-page-title-main">Enstatite</span> Pyroxene: magnesium-iron silicate with MgSiO3 and FeSiO3 end-members

Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, (Mg,Fe)SiO
3
, has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20).

<span class="mw-page-title-main">Serpentinization</span> Formation of serpentinite by hydration and metamorphic transformation of olivine

Serpentinization is a hydration and metamorphic transformation of ferromagnesian minerals, such as olivine and pyroxene, in mafic and ultramafic rock to produce serpentinite. Minerals formed by serpentinization include the serpentine group minerals, brucite, talc, Ni-Fe alloys, and magnetite. The mineral alteration is particularly important at the sea floor at tectonic plate boundaries.

<span class="mw-page-title-main">Melilite</span> Sorosilicate mineral

Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is (Ca,Na)2(Al,Mg,Fe2+)[(Al,Si)SiO7]. Discovered in 1793 near Rome, it has a yellowish, greenish-brown color. The name derives from the Greek words meli (μέλι) "honey" and lithos (λίθους) "stone".The name refers to a group of minerals (melilite group) with chemically similar composition, nearly always minerals in åkermanite-gehlenite series.

Talc carbonates are a suite of rock and mineral compositions found in metamorphosed ultramafic rocks.

<span class="mw-page-title-main">Leucitite</span>

Leucitite or leucite rock is an igneous rock containing leucite. It is scarce, many countries such as England being entirely without them. However, they are of wide distribution, occurring in every quarter of the globe. Taken collectively, they exhibit a considerable variety of types and are of great interest petrographically. For the presence of this mineral it is necessary that the silica percentage of the rock should be low, since leucite is incompatible with free quartz and reacts with it to form potassium feldspar. Because it weathers rapidly, leucite is most common in lavas of recent and Tertiary age, which have a fair amount of potassium, or at any rate have potassium equal to or greater than sodium; if sodium is abundant nepheline occurs rather than leucite.

<span class="mw-page-title-main">Metamorphic facies</span> Set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures

A metamorphic facies is a set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures. The assemblage is typical of what is formed in conditions corresponding to an area on the two dimensional graph of temperature vs. pressure. Rocks which contain certain minerals can therefore be linked to certain tectonic settings, times and places in the geological history of the area. The boundaries between facies are wide because they are gradational and approximate. The area on the graph corresponding to rock formation at the lowest values of temperature and pressure is the range of formation of sedimentary rocks, as opposed to metamorphic rocks, in a process called diagenesis.

<span class="mw-page-title-main">Allende meteorite</span> CV3 carbonaceous chondrite meteorite

The Allende meteorite is the largest carbonaceous chondrite ever found on Earth. The fireball was witnessed at 01:05 on February 8, 1969, falling over the Mexican state of Chihuahua. After it broke up in the atmosphere, an extensive search for pieces was conducted and over 2 tonnes were recovered. The availability of large quantities of samples of the scientifically important chondrite class has enabled numerous investigations by many scientists; it is often described as "the best-studied meteorite in history." The Allende meteorite has abundant, large calcium–aluminum-rich inclusions (CAI), which are among the oldest objects formed in the Solar System.

<span class="mw-page-title-main">Lodranite</span> Type of meteorites

Lodranites are a small group of primitive achondrite meteorites that consists of meteoric iron and silicate minerals. Olivine and pyroxene make up most of the silicate minerals. Like all primitive achondrites lodranites share similarities with chondrites and achondrites.

Mineral alteration refers to the various natural processes that alter a mineral's chemical composition or crystallography.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Hedenbergite".
  3. "Hedenbergite Mineral Data".
  4. Lindsley D. H. and Munoz J. L. (1969) Solidus Relations Along The Join Hedenbergite – Ferrosilite. American Journal of Science. Vol. 267-A, pp. 295–324
  5. 1 2 Kandelin J. and Weidner D. J. (1988) Elastic Properties of Hedenbergite. Journal of Geophysical Research: Solid Earth and Planets Vol. 93, pp.1063–1072
  6. Kimura, M., Ikeda, Y. Anhydrous Alterations of the Allende Meteorite in the Solar Nebula II: Alkali-Ca Exchange Reactions and Formation of Nepheline, Sodalite and Ca-rich Phases in Chondrules. Proc. NIPR Symp. Antarct. Meteorites, 8, 123–138, 1995.
  7. G.E. Ray and G.L. Dawson, The Geology and Mineral Deposits of the Hedley Gold Skarn District, Southern B.C., British Columbia Ministry of Energy and Mines, Bulletin 87, 1994
  8. Ettlinger A. D., Meinert L. D., and Ray G. E. (1992) Gold Skarn Mineralization and Fluid Evolution in the Nickel Plate Deposit, British Columbia. Economic Geology. Vol. 87, pp. 1541–1565

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