"Silk" in seal script (top), Traditional (middle), and Simplified (bottom) Chinese
Silk is a natural protein fiber, some forms of which can be woven into textiles. The protein fiber of silk is composed mainly of fibroin and is produced by certain insect larvae to form cocoons.The best-known silk is obtained from the cocoons of the larvae of the mulberry silkworm Bombyx mori reared in captivity (sericulture). The shimmering appearance of silk is due to the triangular prism-like structure of the silk fibre, which allows silk cloth to refract incoming light at different angles, thus producing different colors.
Proteins are large biomolecules, or macromolecules, consisting of one or more long chains of amino acid residues. Proteins perform a vast array of functions within organisms, including catalysing metabolic reactions, DNA replication, responding to stimuli, providing structure to cells and organisms, and transporting molecules from one location to another. Proteins differ from one another primarily in their sequence of amino acids, which is dictated by the nucleotide sequence of their genes, and which usually results in protein folding into a specific three-dimensional structure that determines its activity.
Fiber or fibre is a natural or synthetic substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate fibers, for example carbon fiber and ultra-high-molecular-weight polyethylene.
Weaving is a method of textile production in which two distinct sets of yarns or threads are interlaced at right angles to form a fabric or cloth. Other methods are knitting, crocheting, felting, and braiding or plaiting. The longitudinal threads are called the warp and the lateral threads are the weft or filling. The method in which these threads are inter-woven affects the characteristics of the cloth. Cloth is usually woven on a loom, a device that holds the warp threads in place while filling threads are woven through them. A fabric band which meets this definition of cloth can also be made using other methods, including tablet weaving, back strap loom, or other techniques without looms.
Silk is produced by several insects; but, generally, only the silk of moth caterpillars has been used for textile manufacturing. There has been some research into other types of silk, which differ at the molecular level.Silk is mainly produced by the larvae of insects undergoing complete metamorphosis, but some insects such as webspinners and raspy crickets produce silk throughout their lives. Silk production also occurs in Hymenoptera (bees, wasps, and ants), silverfish, mayflies, thrips, leafhoppers, beetles, lacewings, fleas, flies, and midges. Other types of arthropod produce silk, most notably various arachnids such as spiders.
A larva is a distinct juvenile form many animals undergo before metamorphosis into adults. Animals with indirect development such as insects, amphibians, or cnidarians typically have a larval phase of their life cycle.
Holometabolism, also called complete metamorphosis, is a form of insect development which includes four life stages: egg, larva, pupa, and imago or adult. Holometabolism is a synapomorphic trait of all insects in the superorder Endopterygota. Immature stages of holometabolous insects are very different from the mature stage. In some species the holometabolous life cycle prevents larvae from competing with adults because they inhabit different ecological niches. The morphology and behavior of each stage are adapted for different activities. For example, larval traits maximize feeding, growth, and development, while adult traits enable dispersal, mating, and egg laying. Some species of holometabolous insects protect and feed their offspring. Other insect developmental strategies include ametabolism and hemimetabolism.
Gryllacrididae are a family of non-jumping insects in the suborder Ensifera occurring worldwide, known commonly as leaf-rolling crickets or raspy crickets. The family historically has been broadly defined to include what are presently several other families, such as Stenopelmatidae and Rhaphidophoridae, now considered separate. As presently defined, the family contains two subfamilies, with the vast majority in the subfamily Gryllacridinae. The remaining subfamily, Lezininae, contains only a single genus with 12 described species. They are commonly wingless and nocturnal. In the daytime, most species rest in shelters made from folded leaves sewn with silk. Some species use silk to burrow in sand, earth or wood. Raspy crickets evolved the ability to produce silk independently from other insects, but their silk has many convergent features to silkworm silk, being made of long, repetitive proteins with an extended beta-sheet structure.
The word silk comes from Old English :sioloc, from Ancient Greek : σηρικός, translit. sērikós, "silken", ultimately from an Asian source — compare Mandarin sī "silk", Manchurian sirghe, Mongolian sirkek.
Standard Chinese, also known as Modern Standard Mandarin, Standard Mandarin, Modern Standard Mandarin Chinese (MSMC), or simply Mandarin, is a standard variety of Chinese that is the sole official language of China, the de facto official language of Taiwan and also one of the four official languages of Singapore. Its pronunciation is based on the Beijing dialect, its vocabulary on the Mandarin dialects, and its grammar is based on written vernacular Chinese.
Manchu is a critically endangered Tungusic language spoken in Manchuria; it was the native language of the Manchus and one of the official languages of the Qing dynasty (1636–1911) of China and in Inner Asia. Most Manchus now speak Mandarin Chinese. According to data from UNESCO, there are 10 native speakers of Manchu out of a total of nearly 10 million ethnic Manchus. Now, several thousand can speak Manchu as a second language through governmental primary education or free classes for adults in classrooms or online.
The Mongolian language is the official language of Mongolia and both the most widely-spoken and best-known member of the Mongolic language family. The number of speakers across all its dialects may be 5.2 million, including the vast majority of the residents of Mongolia and many of the Mongolian residents of the Inner Mongolia Autonomous Region. In Mongolia, the Khalkha dialect, written in Cyrillic, is predominant, while in Inner Mongolia, the language is dialectally more diverse and is written in the traditional Mongolian script. In the discussion of grammar to follow, the variety of Mongolian treated is Standard Khalkha Mongolian, but much of what is to be said is also valid for vernacular (spoken) Khalkha and for other Mongolian dialects, especially Chakhar.
Several kinds of wild silk, which are produced by caterpillars other than the mulberry silkworm, have been known and used in China, South Asia, and Europe since ancient times. However, the scale of production was always far smaller than for cultivated silks. There are several reasons for this: first, they differ from the domesticated varieties in colour and texture and are therefore less uniform; second, cocoons gathered in the wild have usually had the pupa emerge from them before being discovered so the silk thread that makes up the cocoon has been torn into shorter lengths; and third, many wild cocoons are covered in a mineral layer that prevents attempts to reel from them long strands of silk.Thus, the only way to obtain silk suitable for spinning into textiles in areas where commercial silks are not cultivated was by tedious and labor-intensive carding.
Wild silks have been known and used in many countries from early times, although the scale of production is far smaller than that from cultivated silkworms.
Caterpillars are the larval stage of members of the order Lepidoptera.
China, officially the People's Republic of China (PRC), is a country in East Asia and the world's most populous country, with a population of around 1.404 billion. Covering approximately 9,600,000 square kilometers (3,700,000 sq mi), it is the third- or fourth-largest country by total area. Governed by the Communist Party of China, the state exercises jurisdiction over 22 provinces, five autonomous regions, four direct-controlled municipalities, and the special administrative regions of Hong Kong and Macau.
Commercial silks originate from reared silkworm pupae, which are bred to produce a white-colored silk thread with no mineral on the surface. The pupae are killed by either dipping them in boiling water before the adult moths emerge or by piercing them with a needle. These factors all contribute to the ability of the whole cocoon to be unravelled as one continuous thread, permitting a much stronger cloth to be woven from the silk. Wild silks also tend to be more difficult to dye than silk from the cultivated silkworm.A technique known as demineralizing allows the mineral layer around the cocoon of wild silk moths to be removed, leaving only variability in color as a barrier to creating a commercial silk industry based on wild silks in the parts of the world where wild silk moths thrive, such as in Africa and South America.
Demineralizing has the potential to be used in the silk sector enabling wet reeling of Wild Silk moth cocoons by removing the mineral layer present in these cocoons. This technique is not like degumming where the gum of the fibroin fibres is removed what would lead to a tangled cocoon. With "demineralizing" the gum and structure of the cocoon is kept intact enabling the cocoons to be wet reeled. This could allow a new silk industry in areas which have not the conditions or infrastructure for raising the domesticated silk worm Bombyx mori, possibly generating a revolutionary new income stream and alleviating poverty
Silk was first developed in ancient China.
The earliest example of silk has been found in tombs at the neolithic site Jiahu in Henan, and dates back 8,500 years.Silk fabric from 3630 BC was used as wrapping for the body of a child from a Yangshao culture site in Qingtaicun at Xingyang, Henan.
The Neolithic, the final division of the Stone Age, began about 12,000 years ago when the first development of farming appeared in the Epipalaeolithic Near East, and later in other parts of the world. The division lasted until the transitional period of the Chalcolithic from about 6,500 years ago, marked by the development of metallurgy, leading up to the Bronze Age and Iron Age. In Northern Europe, the Neolithic lasted until about 1700 BC, while in China it extended until 1200 BC. Other parts of the world remained broadly in the Neolithic stage of development, although this term may not be used, until European contact.
Jiahu was the site of a Neolithic settlement based in the central plain of ancient China, near the Yellow River. It is located between the floodplains of the Ni River to the north, and the Sha River to the south, 22 km (14 mi) north of the modern city of Wuyang, Henan Province. Most archaeologists consider the site to be one of the earliest examples of the Peiligang culture. Settled around 7000 BC, the site was later flooded and abandoned around 5700 BC. The settlement was surrounded by a moat and covered a relatively large area of 55,000 square meters. At one time, it was "a complex, highly organized Chinese Neolithic society," home to at least 250 people and perhaps as many as 800.
Henan is a province of the People's Republic of China, located in the central part of the country. Henan is often referred to as Zhongyuan or Zhongzhou (中州) which literally means "central plain land" or "midland", although the name is also applied to the entirety of China proper. Henan is the birthplace of Chinese civilization with over 3,000 years of recorded history, and remained China's cultural, economical, and political center until approximately 1,000 years ago.
Legend gives credit for developing silk to a Chinese empress, Leizu (Hsi-Ling-Shih, Lei-Tzu). Silks were originally reserved for the Emperors of China for their own use and gifts to others, but spread gradually through Chinese culture and trade both geographically and socially, and then to many regions of Asia. Because of its texture and lustre, silk rapidly became a popular luxury fabric in the many areas accessible to Chinese merchants. Silk was in great demand, and became a staple of pre-industrial international trade. In July 2007, archaeologists discovered intricately woven and dyed silk textiles in a tomb in Jiangxi province, dated to the Eastern Zhou Dynasty roughly 2,500 years ago.Although historians have suspected a long history of a formative textile industry in ancient China, this find of silk textiles employing "complicated techniques" of weaving and dyeing provides direct evidence for silks dating before the Mawangdui-discovery and other silks dating to the Han Dynasty (202 BC-220 AD).
Silk is described in a chapter on mulberry planting by Si Shengzhi of the Western Han (206 BC – 9 AD). There is a surviving calendar for silk production in an Eastern Han (25–220 AD) document. The two other known works on silk from the Han period are lost.The first evidence of the long distance silk trade is the finding of silk in the hair of an Egyptian mummy of the 21st dynasty, c.1070 BC. The silk trade reached as far as the Indian subcontinent, the Middle East, Europe, and North Africa. This trade was so extensive that the major set of trade routes between Europe and Asia came to be known as the Silk Road.
The Emperors of China strove to keep knowledge of sericulture secret to maintain the Chinese monopoly. Nonetheless sericulture reached Korea with technological aid from China around 200 BC,the ancient Kingdom of Khotan by AD 50, and India by AD 140.
In the ancient era, silk from China was the most lucrative and sought-after luxury item traded across the Eurasian continent,and many civilizations, such as the ancient Persians, benefited economically from trade.
Silk has a long history in India. It is known as Resham in eastern and north India, and Pattu in southern parts of India. Recent archaeological discoveries in Harappa and Chanhu-daro suggest that sericulture, employing wild silk threads from native silkworm species, existed in South Asia during the time of the Indus Valley Civilization (now in Pakistan) dating between 2450 BC and 2000 BC, while "hard and fast evidence" for silk production in China dates back to around 2570 BC.Shelagh Vainker, a silk expert at the Ashmolean Museum in Oxford, who sees evidence for silk production in China "significantly earlier" than 2500–2000 BC, suggests, "people of the Indus civilization either harvested silkworm cocoons or traded with people who did, and that they knew a considerable amount about silk."
India is the second largest producer of silk in the world after China. About 97% of the raw mulberry silk comes from six Indian states, namely, Andhra Pradesh, Karnataka, Jammu and Kashmir, Tamil Nadu, Bihar and West Bengal.North Bangalore, the upcoming site of a $20 million "Silk City" Ramanagara and Mysore, contribute to a majority of silk production in Karnataka.
In Tamil Nadu, mulberry cultivation is concentrated in the Coimbatore, Erode, Bhagalpuri, Tiruppur, Salem and Dharmapuri districts. Hyderabad, Andhra Pradesh, and Gobichettipalayam, Tamil Nadu, were the first locations to have automated silk reeling units in India.
India is also the largest consumer of silk in the world. The tradition of wearing silk sarees for marriages and other auspicious ceremonies is a custom in Assam and southern parts of India. Silk is considered to be a symbol of royalty, and, historically, silk was used primarily by the upper classes. Silk garments and sarees produced in Kanchipuram, Pochampally, Dharmavaram, Mysore, Arani in the south, Banaras in the north, Bhagalpur and Murshidabad in the east are well recognized. In the northeastern state of Assam, three different types of silk are produced, collectively called Assam silk: Muga, Eri and Pat silk. Muga, the golden silk, and Eri are produced by silkworms that are native only to Assam.
Silk is produced year-round in Thailand by two types of silkworms, the cultured Bombycidae and wild Saturniidae. Most production is after the rice harvest in the southern and northeastern parts of the country. Women traditionally weave silk on hand looms and pass the skill on to their daughters, as weaving is considered to be a sign of maturity and eligibility for marriage. Thai silk textiles often use complicated patterns in various colours and styles. Most regions of Thailand have their own typical silks. A single thread filament is too thin to use on its own so women combine many threads to produce a thicker, usable fiber. They do this by hand-reeling the threads onto a wooden spindle to produce a uniform strand of raw silk. The process takes around 40 hours to produce a half kilogram of silk. Many local operations use a reeling machine for this task, but some silk threads are still hand-reeled. The difference is that hand-reeled threads produce three grades of silk: two fine grades that are ideal for lightweight fabrics, and a thick grade for heavier material.
The silk fabric is soaked in extremely cold water and bleached before dyeing to remove the natural yellow coloring of Thai silk yarn. To do this, skeins of silk thread are immersed in large tubs of hydrogen peroxide. Once washed and dried, the silk is woven on a traditional hand-operated loom.
The Rajshahi Division of northern Bangladesh is the hub of the country's silk industry. There are three types of silk produced in the region: mulberry, endi and tassar. Bengali silk was a major item of international trade for centuries. It was known as Ganges silk in medieval Europe. Bengal was the leading exporter of silk between the 16th and 19th centuries.
In the Odyssey , 19.233, when Odysseus, while pretending to be someone else, is questioned by Penelope about her husband's clothing, he says that he wore a shirt "gleaming like the skin of a dried onion" (varies with translations, literal translation here)which could refer to the lustrous quality of silk fabric. Aristotle wrote of Coa vestis , a wild silk textile from Kos. Sea silk from certain large sea shells was also valued. The Roman Empire knew of and traded in silk, and Chinese silk was the most highly priced luxury good imported by them. During the reign of emperor Tiberius, sumptuary laws were passed that forbade men from wearing silk garments, but these proved ineffectual. The Historia Augusta mentions that the 3rd Century AD emperor Elagabalus was the first Roman to wear garments of pure silk, whereas it had been customary to wear fabrics of silk/cotton or silk/linen blends. Despite the popularity of silk, the secret of silk-making only reached Europe around AD 550, via the Byzantine Empire. Legend has it that monks working for the emperor Justinian I smuggled silkworm eggs to Constantinople in hollow canes from China. All top-quality looms and weavers were located inside the Great Palace complex in Constantinople, and the cloth produced was used in imperial robes or in diplomacy, as gifts to foreign dignitaries. The remainder was sold at very high prices.
In the Torah, a scarlet cloth item called in Hebrew "sheni tola'at" שני תולעת – literally "crimson of the worm" – is described as being used in purification ceremonies, such as those following a leprosy outbreak (Leviticus 14), alongside cedar wood and hyssop (za'atar). Eminent scholar and leading medieval translator of Jewish sources and books of the Bible into Arabic, Rabbi Saadia Gaon, translates this phrase explicitly as "crimson silk" – חריר קרמז حرير قرمز.
In Islamic teachings, Muslim men are forbidden to wear silk. Many religious jurists believe the reasoning behind the prohibition lies in avoiding clothing for men that can be considered feminine or extravagant.There are disputes regarding the amount of silk a fabric can consist of (e.g., whether a small decorative silk piece on a cotton caftan is permissible or not) for it to be lawful for men to wear, but the dominant opinion of most Muslim scholars is that the wearing of silk by men is forbidden. Modern attire has raised a number of issues, including, for instance, the permissibility of wearing silk neckties, which are masculine articles of clothing.
Despite injunctions against silk for men, silk has retained its popularity in the Islamic world because of its permissibility for women, and due to the presence of non-Muslim communities. The Muslim Moors brought silk with them to Spain during their conquest of the Iberian Peninsula.
Italy was the most important producer of silk during the Medieval age. The first center to introduce silk production to Italy was the city of Catanzaro during the 11th century in the region of Calabria. The silk of Catanzaro supplied almost all of Europe and was sold in a large market fair in the port of Reggio Calabria, to Spanish, Venetian, Genovese and Dutch merchants. Catanzaro became the lace capital of the world with a large silkworm breeding facility that produced all the laces and linens used in the Vatican. The city was world-famous for its fine fabrication of silks, velvets, damasks and brocades.
Another notable center was the Italian city-state of Lucca which largely financed itself through silk-production and silk-trading, beginning in the 12th century. Other Italian cities involved in silk production were Genoa, Venice and Florence.
The Silk Exchange in Valencia from the 15th century—where previously in 1348 also perxal (percale) was traded as some kind of silk—illustrates the power and wealth of one of the great Mediterranean mercantile cities.
Silk was produced in and exported from the province of Granada, Spain, especially the Alpujarras region, until the Moriscos, whose industry it was, were expelled from Granada in 1571.
Since the 15th century, silk production in France has been centered around the city of Lyon where many mechanic tools for mass production were first introduced in the 17th century.
James I attempted to establish silk production in England, purchasing and planting 100,000 mulberry trees, some on land adjacent to Hampton Court Palace, but they were of a species unsuited to the silk worms, and the attempt failed. In 1732 John Guardivaglio set up a silk throwing enterprise at Logwood mill in Stockport; in 1744, Burton Mill was erected in Macclesfield; and in 1753 Old Mill was built in Congleton.These three towns remained the centre of the English silk throwing industry until silk throwing was replaced by silk waste spinning. British enterprise also established silk filature in Cyprus in 1928. In England in the mid-20th century, raw silk was produced at Lullingstone Castle in Kent. Silkworms were raised and reeled under the direction of Zoe Lady Hart Dyke, later moving to Ayot St Lawrence in Hertfordshire in 1956.
Wild silk taken from the nests of native caterpillars was used by the Aztecs to make containers and as paper.Silkworms were introduced to Oaxaca from Spain in the 1530s and the region profited from silk production until the early 17th century, when the king of Spain banned export to protect Spain's silk industry. Silk production for local consumption has continued until the present day, sometimes spinning wild silk.
King James I introduced silk-growing to the British colonies in America around 1619, ostensibly to discourage tobacco planting. The Shakers in Kentucky adopted the practice.
The history of industrial silk in the United States is largely tied to several smaller urban centers in the Northeast region. Beginning in the 1830s, Manchester, Connecticut emerged as the early center of the silk industry in America, when the Cheney Brothers became the first in the United States to properly raise silkworms on an industrial scale; today the Cheney Brothers Historic District showcases their former mills.With the mulberry tree craze of that decade, other smaller producers began raising silkworms. This economy particularly gained traction in the vicinity of Northampton, Massachusetts and its neighboring Williamsburg, where a number of small firms and cooperatives emerged. Among the most prominent of these was the cooperative utopian Northampton Association for Education and Industry, of which Sojourner Truth was a member. Following the destructive Mill River Flood of 1874, one manufacturer, William Skinner, relocated his mill from Williamsburg to the then-new city of Holyoke. Over the next 50 years he and his sons would maintain relations between the American silk industry and its counterparts in Japan, and expanded their business to the point that by 1911, the Skinner Mill complex contained the largest silk mill under one roof in the world, and the brand Skinner Fabrics had become the largest manufacturer of silk satins internationally. Other efforts later in the 19th century would also bring the new silk industry to Paterson, New Jersey, with several firms hiring European-born textile workers and granting it the nickname "Silk City" as another major center of production in the United States.
World War II interrupted the silk trade from Asia, and silk prices increased dramatically.U.S. industry began to look for substitutes, which led to the use of synthetics such as nylon. Synthetic silks have also been made from lyocell, a type of cellulose fiber, and are often difficult to distinguish from real silk (see spider silk for more on synthetic silks).
In Terengganu, which is now part of Malaysia, a second generation of silkworm was being imported as early as 1764 for the country's silk textile industry, especially songket.However, since the 1980s, Malaysia is no longer engaged in sericulture but does plant mulberry trees.
In Vietnamese legend, silk appeared in the first millennia AD and is still being woven today.
The process of silk production is known as sericulture. [ clarification needed ]. Extracting raw silk starts by cultivating the silkworms on mulberry leaves. Once the worms start pupating in their cocoons, these are dissolved in boiling water in order for individual long fibres to be extracted and fed into the spinning reel.The entire production process of silk can be divided into several steps which are typically handled by different entities
To produce 1 kg of silk, 104 kg of mulberry leaves must be eaten by 3000 silkworms. It takes about 5000 silkworms to make a pure silk kimono. :104 The major silk producers are China (54%) and India (14%). Other statistics:
|Top Ten Cocoons (Reelable) Producers — 2005|
|Country||Production (Int $1000)||Footnote||Production (1000 kg)||Footnote|
|No symbol = official figure, F = FAO estimate,*= Unofficial figure, C = Calculated figure;|
Production in Int $1000 have been calculated based on 1999–2001 international prices
The environmental impact of silk production is potentially large when compared with other natural fibers. A life cycle assessment of Indian silk production shows that the production process has a large carbon and water footprint, mainly due to the fact that it is an animal-derived fiber and more inputs such as fertilizer and water are needed per unit of fiber produced.
Silk fibers from the Bombyx mori silkworm have a triangular cross section with rounded corners, 5–10 μm wide. The fibroin-heavy chain is composed mostly of beta-sheets, due to a 59-mer amino acid repeat sequence with some variations.The flat surfaces of the fibrils reflect light at many angles, giving silk a natural sheen. The cross-section from other silkworms can vary in shape and diameter: crescent-like for Anaphe and elongated wedge for tussah. Silkworm fibers are naturally extruded from two silkworm glands as a pair of primary filaments (brin), which are stuck together, with sericin proteins that act like glue, to form a bave. Bave diameters for tussah silk can reach 65 μm. See cited reference for cross-sectional SEM photographs.
Silk has a smooth, soft texture that is not slippery, unlike many synthetic fibers.
Silk is one of the strongest natural fibers, but it loses up to 20% of its strength when wet. It has a good moisture regain of 11%. Its elasticity is moderate to poor: if elongated even a small amount, it remains stretched. It can be weakened if exposed to too much sunlight. It may also be attacked by insects, especially if left dirty.
One example of the durable nature of silk over other fabrics is demonstrated by the recovery in 1840 of silk garments from a wreck of 1782: 'The most durable article found has been silk; for besides pieces of cloaks and lace, a pair of black satin breeches, and a large satin waistcoat with flaps, were got up, of which the silk was perfect, but the lining entirely gone ... from the thread giving way ... No articles of dress of woollen cloth have yet been found.'
Silk is a poor conductor of electricity and thus susceptible to static cling. Silk has a high emissivity for infrared light, making it feel cool to the touch.
Unwashed silk chiffon may shrink up to 8% due to a relaxation of the fiber macrostructure, so silk should either be washed prior to garment construction, or dry cleaned. Dry cleaning may still shrink the chiffon up to 4%. Occasionally, this shrinkage can be reversed by a gentle steaming with a press cloth. There is almost no gradual shrinkage nor shrinkage due to molecular-level deformation.
Natural and synthetic silk is known to manifest piezoelectric properties in proteins, probably due to its molecular structure.
Silkworm silk was used as the standard for the denier, a measurement of linear density in fibers. Silkworm silk therefore has a linear density of approximately 1 den, or 1.1 dtex.
|Comparison of silk fibers||Linear density (dtex)||Diameter (μm)||Coeff. variation|
|Moth: Bombyx mori||1.17||12.9||24.8%|
|Spider: Argiope aurentia||0.14||3.57||14.8%|
Silk emitted by the silkworm consists of two main proteins, sericin and fibroin, fibroin being the structural center of the silk, and serecin being the sticky material surrounding it. Fibroin is made up of the amino acids Gly-Ser-Gly-Ala-Gly-Ala and forms beta pleated sheets. Hydrogen bonds form between chains, and side chains form above and below the plane of the hydrogen bond network.
The high proportion (50%) of glycine allows tight packing. This is because glycine's R group is only a hydrogen and so is not as sterically constrained. The addition of alanine and serine makes the fibres strong and resistant to breaking. This tensile strength is due to the many interceded hydrogen bonds, and when stretched the force is applied to these numerous bonds and they do not break.
Silk is resistant to most mineral acids, except for sulfuric acid, which dissolves it. It is yellowed by perspiration. Chlorine bleach will also destroy silk fabrics.
RSF is produced by chemically dissolving silkworm cocoons, leaving their molecular structure intact. The silk fibers dissolve into tiny thread-like structures known as microfibrils. The resulting solution is extruded through a small opening, causing the microfibrils to reassemble into a single fiber. The resulting material is reportedly twice as stiff as silk.
Silk's absorbency makes it comfortable to wear in warm weather and while active. Its low conductivity keeps warm air close to the skin during cold weather. It is often used for clothing such as shirts, ties, blouses, formal dresses, high fashion clothes, lining, lingerie, pajamas, robes, dress suits, sun dresses and Eastern folk costumes. For practical use, silk is excellent as clothing that protects from many biting insects that would ordinarily pierce clothing, such as mosquitoes and horseflies.
Fabrics that are often made from silk include charmeuse, habutai, chiffon, taffeta, crepe de chine, dupioni, noil, tussah, and shantung, among others.
Silk's attractive lustre and drape makes it suitable for many furnishing applications. It is used for upholstery, wall coverings, window treatments (if blended with another fiber), rugs, bedding and wall hangings.[ citation needed ]
Silk had many industrial and commercial uses, such as in parachutes, bicycle tires, comforter filling and artillery gunpowder bags.
A special manufacturing process removes the outer sericin coating of the silk, which makes it suitable as non-absorbable surgical sutures. This process has also recently led to the introduction of specialist silk underclothing, which has been used for skin conditions including eczema.New uses and manufacturing techniques have been found for silk for making everything from disposable cups to drug delivery systems and holograms.
Silk has been considered as a luxurious textile since 3630 BC. However, it started to serve also as a biomedical material for suture in surgeries decades ago. In the past 30 years, it has been widely studied and used as a biomaterial, which refers to materials used for medical applications in organisms, due to its excellent properties, including remarkable mechanical properties, comparative biocompatibility, tunable degradation rates in vitro and in vivo, the ease to load cellular growth factors (for example, BMP-2), and the ability to be processed into several other formats such as films, gels, particles, and scaffolds.Silks from Bombyx mori, a kind of cultivated silkworm, are the most widely investigated silks.
Silks derived from Bombyx mori are generally made of two parts: the silk fibroin fiber which contains a light chain of 25kDa and a heavy chain of 350kDa (or 390kDa) linked by a single disulfide bond and a glue-like protein, sericin, comprising 25 to 30 percentage by weight. Silk fibroin contains hydrophobic beta sheet blocks, interrupted by small hydrophilic groups. And the beta-sheets contribute much to the high mechanical strength of silk fibers, which achieves 740 MPa, tens of times that of poly(lactic acid) and hundreds of times that of collagen. This impressive mechanical strength has made silk fibroin very competitive for applications in biomaterials. Indeed, silk fibers have found their way into tendon tissue engineering, where mechanical properties matter greatly. In addition, mechanical properties of silks from various kinds of silkworms vary widely, which provides more choices for their use in tissue engineering.
Most products fabricated from regenerated silk are weak and brittle, with only ≈1–2% of the mechanical strength of native silk fibers due to the absence of appropriate secondary and hierarchical structure,
|Source Organisms||Tensile strength |
|Tensile modulus |
|Philosamia cynthia ricini||1.9–3.5||29–31||28.0–24.0|
|Coscinocera hercules||5 ± 1||87 ± 17||12 ± 5|
|Hyalophora euryalus||2.7 ± 0.9||59 ± 18||11 ± 6|
|Rothschildia hesperis||3.3 ± 0.8||71 ± 16||10 ± 4|
|Eupackardia calleta||2.8 ± 0.7||58 ± 18||12 ± 6|
|Rothschildia lebeau||3.1 ± 0.8||54 ± 14||16 ± 7|
|Antheraea oculea||3.1 ± 0.8||57 ± 15||15 ± 7|
|Hyalophora gloveri||2.8 ± 0.4||48 ± 13||19 ± 7|
|Copaxa multifenestrata||0.9 ± 0.2||39 ± 6||4 ± 3|
Biocompatibility, i.e., to what level the silk will cause an immune response, is a critical issue for biomaterials. The issue arose during its increasing clinical use. Wax or silicone is usually used as a coating to avoid fraying and potential immune responseswhen silk fibers serve as suture materials. Although the lack of detailed characterization of silk fibers, such as the extent of the removal of sericin, the surface chemical properties of coating material, and the process used, make it difficult to determine the real immune response of silk fibers in literature, it is generally believed that sericin is the major cause of immune response. Thus, the removal of sericin is an essential step to assure biocompatibility in biomaterial applications of silk. However, further research fails to prove clearly the contribution of sericin to inflammatory responses based on isolated sericin and sericin based biomaterials. In addition, silk fibroin exhibits an inflammatory response similar to that of tissue culture plastic in vitro when assessed with human mesenchymal stem cell s (hMSCs) or lower than collagen and PLA when implant rat MSCs with silk fibroin films in vivo. Thus, appropriate degumming and sterilization will assure the biocompatibility of silk fibroin, which is further validated by in vivo experiments on rats and pigs. There are still concerns about the long-term safety of silk-based biomaterials in the human body in contrast to these promising results. Even though silk sutures serve well, they exist and interact within a limited period depending on the recovery of wounds (several weeks), much shorter than that in tissue engineering. Another concern arises from biodegradation because the biocompatibility of silk fibroin does not necessarily assure the biocompatibility of the decomposed products. In fact, different levels of immune responses and diseases have been triggered by the degraded products of silk fibroin.
Biodegradability (also known as biodegradation)--the ability to be disintegrated by biological approaches, including bacteria, fungi, and cells—is another significant property of biomaterials today. Biodegradable materials can minimize the pain of patients from surgeries, especially in tissue engineering, there is no need of surgery in order to remove the scaffold implanted. Wang et al.showed the in vivo degradation of silk via aqueous 3-D scaffolds implanted into Lewis rats. Enzyme s are the means used to achieve degradation of silk in vitro. Protease XIV from Streptomyces griseus and α-chymotrypsin from bovine pancreases are the two popular enzymes for silk degradation. In addition, gamma-radiation, as well as cell metabolism, can also regulate the degradation of silk.
Compared with synthetic biomaterials such as polyglycolides and polylactides, silk is obviously advantageous in some aspects in biodegradation. The acidic degraded products of polyglycolides and polylactides will decrease the pH of the ambient environment and thus adversely influence the metabolism of cells, which is not an issue for silk. In addition, silk materials can retain strength over a desired period from weeks to months as needed by mediating the content of beta sheets.
Genetic modification of domesticated silkworms has been used to alter the composition of the silk.As well as possibly facilitating the production of more useful types of silk, this may allow other industrially or therapeutically useful proteins to be made by silkworms.
Silk moths lay eggs on specially prepared paper. The eggs hatch and the caterpillars (silkworms) are fed fresh mulberry leaves. After about 35 days and 4 moltings, the caterpillars are 10,000 times heavier than when hatched and are ready to begin spinning a cocoon. A straw frame is placed over the tray of caterpillars, and each caterpillar begins spinning a cocoon by moving its head in a pattern. Two glands produce liquid silk and force it through openings in the head called spinnerets. Liquid silk is coated in sericin, a water-soluble protective gum, and solidifies on contact with the air. Within 2–3 days, the caterpillar spins about 1 mile of filament and is completely encased in a cocoon. The silk farmers then heat the cocoons to kill them, leaving some to metamorphose into moths to breed the next generation of caterpillars. Harvested cocoons are then soaked in boiling water to soften the sericin holding the silk fibers together in a cocoon shape. The fibers are then unwound to produce a continuous thread. Since a single thread is too fine and fragile for commercial use, anywhere from three to ten strands are spun together to form a single thread of silk.
As the process of harvesting the silk from the cocoon kills the larvae by boiling them, sericulture has been criticized by animal welfare and rights activists.Mohandas Gandhi was critical of silk production based on the Ahimsa philosophy which led to promotion of cotton and Ahimsa silk, a type of wild silk made from the cocoons of wild and semi-wild silk moths.
Since silk cultivation kills silkworms, possibly painfully,People for the Ethical Treatment of Animals (PETA) urges people not to buy silk items.
A textile is a flexible material consisting of a network of natural or artificial fibers. Yarn is produced by spinning raw fibres of wool, flax, cotton, hemp, or other materials to produce long strands. Textiles are formed by weaving, knitting, crocheting, knotting, felting, or braiding.
The silkworm is the larva or caterpillar of the domestic silkmoth, Bombyx mori. It is an economically important insect, being a primary producer of silk. A silkworm's preferred food is white mulberry leaves, though they may eat other mulberry species and even osage orange. Domestic silkmoths are closely dependent on humans for reproduction, as a result of millennia of selective breeding. Wild silkmoths are different from their domestic cousins as they have not been selectively bred; they are not as commercially viable in the production of silk.
Sericulture, or silk farming, is the cultivation of silkworms to produce silk. Although there are several commercial species of silkworms, Bombyx mori is the most widely used and intensively studied silkworm. Silk was believed to have first been produced in China as early as the Neolithic period. Sericulture has become an important cottage industry in countries such as Brazil, China, France, India, Italy, Japan, Korea, and Russia. Today, China and India are the two main producers, with more than 60% of the world's annual production.
A silk comforter (絲綿被) is a bed covering, most often used as a duvet, and also commonly referred to as a silk duvet, silk quilt, or silk blanket. Originally used and made in China, since the late 20th century, silk comforters have become more common in Western market areas. Their increasing popularity stems from a combination of factors, including their thermal properties, their light weight, and their natural hypoallergenic properties. The opening of the Chinese market to the world since the 1990s has also played a significant role in the spread of silk comforters, as China is both the world's biggest silk producer and silk comforter manufacturer.
Leizu, also known as Xi Lingshi, was a legendary Chinese empress and wife of the Yellow Emperor. According to tradition, she discovered sericulture, and invented the silk loom, in the 27th century BC.
The Stazione Bacologica Sperimentale is an institution specialising in sericulture (silk-farming) in Padua, Italy. It was founded in 1871 by a decree of Vittorio Emanuele II. The actual founder was Enrico Verson. It is a section of the Institute for Experimental Agrarian Zoology of Florence. The current director is Dr. Luciano Cappellozza and the Institute building is owned by the Provincial Administration of Padua, which is planning a museum with live collections of insects. This will include exhibitions on sericulture, apiculture and a general display of Lepidoptera. The sericultural part will show the silk collections of the Section as well as old tools and machines used for the rearing of the silkworm and the reeling of the cocoon.
Rajshahi silk is the name given to the silk products produced in Rajshahi, Bangladesh. It is famous because it is a high quality fabric used for clothing, especially for saris.
Silk in the Indian subcontinent is a luxury good. In India, about 97% of the raw mulberry silk is produced in the five Indian states of Karnataka, Andhra Pradesh, Tamil Nadu, West Bengal and Jammu and Kashmir. Mysore and North Bangalore, the upcoming site of a US$20 million "Silk City", contribute to a majority of silk production. Another emerging silk producer is Tamil Nadu where mulberry cultivation is concentrated in Salem, Erode and Dharmapuri districts. Hyderabad, Andhra Pradesh and Gobichettipalayam, Tamil Nadu were the first locations to have automated silk reeling units.
Fibroin is an insoluble protein present in silk created by spiders, the larvae of Bombyx mori, other moth genera such as Antheraea, Cricula, Samia and Gonometa, and numerous other insects. Silk in its raw state consists of two main proteins, sericin and fibroin, with a glue-like layer of sericin coating two singular filaments of fibroin called brins.
Assam silk denotes the three major types of indigenous wild silks produced in Assam—golden muga, white pat and warm eri silk. The Assam silk industry, now centered in Sualkuchi, is a labor-intensive industry.
The production of silk originates in China in the Neolithic. Silk remained confined to China until the Silk Road opened at some point during the later half of the 1st millennium BC. China maintained its virtual monopoly over silk production for another thousand years. Not confined to clothing, silk was also used for a number of other applications, including writing, and the color of silk worn was an important guide of social class during the Tang dynasty.
Thai silk is produced from the cocoons of Thai silkworms. Thailand's silkworm farmers cultivate both types of the domesticated silkworms that produce commercial silk: Samia ricini, commonly known as the eri silkworm, which produces matte eri silk, and the Bombyx mori, producer of the better known, glossy mulberry silk. The latter is by far the larger silk producer of the two.
China is the world's largest silk producer. The vast majority of Chinese silk originates from the mulberry silkworms. During the larval stage of its life-cycle, the insects feeds on the leaves of mulberry trees. Non-mulberry silkworms cocoon production in China primarily focuses on wild silk from the Chinese Tussah moth. This moth typically feeds on trees and its larvae spin coarser, flatter, yellower filament than the mulberry silk moths.
Silk waste includes all kinds of raw silk which may be unwindable, and therefore unsuited to the throwing process. Before the introduction of machinery applicable to the spinning of silk waste, the refuse from cocoon reeling, and also from silk winding, which is now used in producing spun silk fabrics, was nearly all destroyed as being useless, with the exception of that which could be hand-combed and spun by means of the distaff and spinning wheel, a method which is still practised by some of the peasantry in India and other countries in Asia.
Eri silk comes from the caterpillar of Samia cynthia ricini, found in northeast India and some parts of China, Japan. It was imported to Thailand in 1974. The name "eri" is derived from the Assamese word "era", which means "castor", as the silkworm feeds on castor plants. One of the common names, the "Ailanthus silk moth", refers to the host plant. Eri silk is also known as endi or errandi in India. The woolly white silk is often referred to as the fabric of peace when it is processed without killing the silkworm. This process results in a silk called Ahimsa silk. Moths leave the cocoon and then the cocoons are harvested to be spun. The eri silkworm is the only completely domesticated silkworm other than Bombyx mori.
Tussar silk is produced from larvae of several species of silkworms belonging to the moth genus Antheraea, including A. assamensis, A. mylitta, A. paphia, A. pernyi, A. roylei and A. yamamai. These silkworms live in the wild forests in trees belonging to Terminalia species and Shorea robusta as well as other food plants like jamun and oak found in South Asia, eating the leaves of the trees they live on. Tussar silk is valued for its rich texture and natural deep gold colour, and varieties are produced in many countries, including China, India, Japan, and Sri Lanka.
Artisans Angkor is a Cambodian social business creating job opportunities for young people in rural areas, while reviving traditional Khmer craftsmanship.
Silk amino acid (SAAs) also known as Sericin is a natural water-soluble glycoprotein extracted from raw silk. It is used as an additive in skin and hair care products due to its high levels of serine which has excellent moisture preservation characteristics. As a water-based additive it is used to provide a protective barrier and silky feel to lotions, soaps, personal lubricants, hair and skincare products. Silk amino acids are produced by hydrolyzing silk proteins into smaller peptide chains, typically 18 to 19 amino acids in length. Silk amino acids have a lower molecular weight than silk protein powders and are moisturizing to skin and hair.
Gonometa postica, known commonly as the African wild silk moth, burn worm, and brandwurm, is a large species of African moth belonging to the family Lasiocampidae. The genus Gonometa boasts some very large moths and larvae; Gonometa sjostedti from Africa has a larva 16 centimeters long, for example. Most of the Lasiocampidae are highly sexually dimorphic. In G. postica the forewing of the male measures 21–25 mm and of the female 35–42 mm.
[silkworms] have the capacity to feel and the right to live free from pain and suffering.[ better source needed ]
Silk Production Causes Painful Death for Insects
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