Aggregation-induced emission

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Aggregation-induced emission (AIE) is a phenomenon in which certain organic luminophores (fluorescent dyes) exhibit stronger emission of light in their aggregated or solid state compared to when they are in solution. [2] [3] [4] This counterintuitive behavior contrasts with most organic compounds, which typically show reduced photoemission in the solid state due to processes like aggregation-caused quenching. AIE is primarily attributed to restricted molecular motion in the aggregated state (decreased flexibility), which suppresses nonradiative energy dissipation and enhances fluorescence efficiency. [5] The increase of fluorescence emission intensity was also observed upon restriction of molecular motion due to host-guest interactions and viscosity increase, [6] which is not a common behavior of such host-guest complexes. [7]

Contents

Aggregation-induced emission enhancement

The phenomenon in which organic luminophores show higher photoluminescence efficiency in the aggregated state than in solution is called aggregation-induced emission enhancement (AIEE). Some luminophores, e.g., diketopyrrolopyrrole-based and sulfonamide-based luminophores, only display enhanced emission upon entering the crystalline state. That is, these luminophores are said to exhibit crystallization-induced emission enhancement (CIEE). [8] [9] Luminophores such as noble metallic nanoclusters show higher photoluminescence efficiency in the aggregated state than homogenous dispersion in solution. This phenomenon is known as Aggregation-Induced Emission (AIE). [10] [11]

Aggregation-induced emission polymer

Fluorescence-emission Polymer is a kind of polymer which can absorb light of certain frequency and then give out light. [12] These polymers can be applied in biomaterial area. Due to their high biocapacity and fluorescence, they can help researchers to find and mark the location of proteins. And polymers with property of aggregation-induced emission can also help to protect the healthy tissues from the harm of the medicines. [13]

References

  1. ↑ T P, Shaima; A Mirgane, Harshad; H Upadhaya, Aditi; V Bhosale, Sheshanath; K Singh, Prabhat (2024). "A novel approach to supramolecular Aggregation-Induced emission using tetracationic tetraphenylethylene and sulfated β-Cyclodextrin". Journal of Photochemistry and Photobiology A: Chemistry. 448 115328. Bibcode:2024JPPA..44815328S. doi:10.1016/j.jphotochem.2023.115328.
  2. ↑ Hong, Yuning; Lam, Jacky W. Y.; Tang, Ben Zhong (2011). "Aggregation-induced emission". Chemical Society Reviews. 40 (11): 5361–88. doi:10.1039/c1cs15113d. PMID   21799992.
  3. ↑ Mei, Ju; Hong, Yuning; Lam, Jacky W. Y.; Qin, Anjun; Tang, Youhong; Tang, Ben Zhong (August 2014). "Aggregation-Induced Emission: The Whole Is More Brilliant than the Parts". Advanced Materials. 26 (31): 5429–5479. Bibcode:2014AdM....26.5429M. doi:10.1002/adma.201401356. PMID   24975272. S2CID   29645895.
  4. ↑ Mei, Ju; Leung, Nelson L. C.; Kwok, Ryan T. K.; Lam, Jacky W. Y.; Tang, Ben Zhong (22 October 2015). "Aggregation-Induced Emission: Together We Shine, United We Soar!". Chemical Reviews. 115 (21): 11718–11940. doi:10.1021/acs.chemrev.5b00263. PMID   26492387.
  5. ↑ Suzuki, Satoshi; Sasaki, Shunsuke; Sairi, Amir Sharidan; Iwai, Riki; Tang, Ben Zhong; Konishi, Gen-ichi (2020). "Principles of Aggregation-Induced Emission: Design of Deactivation Pathways for Advanced AIEgens and Applications". Angewandte Chemie International Edition. 59 (25): 9856–9867. Bibcode:2020ACIE...59.9856S. doi:10.1002/anie.202000940. ISSN   1521-3773. PMC   7318703 . PMID   32154630.
  6. ↑ Strada, Rebecca; Dunlop, David; Vorba, Michal; Raj, Amar; Tütüncü, Büşra Buse; Myllyperkiö, Pasi; Slanina, Tomáš; Kumpulainen, Tatu; Sebej, Peter (2025). "Restricting Intramolecular Motion Converts Non-Fluorescent Semicroconaine Dyes into Turn-On Aggregation-Induced Emission Probes". Materials Chemistry Frontiers. 9 (13): 2031–2040. doi: 10.1039/D5QM00030K . ISSN   2052-1537.
  7. ↑ Gilberg, Laura; Zhang, Ben; Zavalij, Peter Y.; Sindelar, Vladimir; Isaacs, Lyle (2015). "Acyclic cucurbit[n]uril-type molecular containers: influence of glycoluril oligomer length on their function as solubilizing agents". Organic & Biomolecular Chemistry. 13 (13): 4041–4050. doi:10.1039/C5OB00184F. ISSN   1477-0520. PMC   4366302 . PMID   25731639.
  8. ↑ Jin, Yi; Xu, Yanbin; Liu, Yinling; Wang, Lingyun; Jiang, Huanfeng; Li, Xianjie; Cao, Derong (September 2011). "Synthesis of novel diketopyrrolopyrrole-based luminophores showing crystallization-induced emission enhancement properties". Dyes and Pigments. 90 (3): 311–318. doi:10.1016/j.dyepig.2011.01.005.
  9. ↑ Virk, Tarunpreet Singh; Ilawe, Niranjan V.; Zhang, Guoxian; Yu, Craig P.; Wong, Bryan M.; Chan, Julian M. W. (20 December 2016). "Sultam-Based Hetero[5]helicene: Synthesis, Structure, and Crystallization-Induced Emission Enhancement". ACS Omega. 1 (6): 1336–1342. doi:10.1021/acsomega.6b00335. PMC   6640820 . PMID   31457199.
  10. ↑ Moghadam, Fatemeh Mortazavi; Rahaie, Mahdi (May 2019). "A signal-on nanobiosensor for VEGF165 detection based on supraparticle copper nanoclusters formed on bivalent aptamer". Biosensors and Bioelectronics. 132: 186–195. doi:10.1016/j.bios.2019.02.046. PMID   30875630. S2CID   80613434.
  11. ↑ Mortazavi Moghadam, Fatemeh; Bigdeli, Mohammadreza; Tamayol, Ali; Shin, Su Ryon (October 2021). "TISS nanobiosensor for salivary cortisol measurement by aptamer Ag nanocluster SAIE supraparticle structure". Sensors and Actuators B: Chemical. 344 130160. Bibcode:2021SeAcB.34430160M. doi:10.1016/j.snb.2021.130160.
  12. ↑ Han, Ting; Deng, Haiqin; Qiu, Zijie; Zhao, Zheng; Zhang, Haoke; Zou, Hang; Leung, Nelson L. C.; Shan, Guogang; Elsegood, Mark R. J.; Lam, Jacky W. Y.; Tang, Ben Zhong (9 April 2018). "Facile Multicomponent Polymerizations toward Unconventional Luminescent Polymers with Readily Openable Small Heterocycles". Journal of the American Chemical Society. 140 (16): 5588–5598. Bibcode:2018JAChS.140.5588H. doi:10.1021/jacs.8b01991. PMID   29630372. S2CID   207190130.
  13. ↑ Sun, Wenjing; Luo, Li; Feng, Yushuo; Cai, Yuting; Zhuang, Yixi; Xie, Rong-Jun; Chen, Xiaoyuan; Chen, Hongmin (5 September 2019). "Aggregation-Induced Emission Gold Clustoluminogens for Enhanced Low-Dose X-ray-Induced Photodynamic Therapy". Angewandte Chemie International Edition. 59 (25): 9914–9921. doi:10.1002/anie.201908712. PMID   31418982. S2CID   201020605.


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