Ammonia fuming is a wood finishing process that darkens wood and brings out the grain pattern. It consists of exposing the wood to fumes from a strong aqueous solution of ammonium hydroxide which reacts with the tannins in the wood. The process works best on white oak because of the high tannin content of this wood. Fumed oak is also called fumigated oak or smoked oak. Other species may also be fumed, but usually will not darken as much as white oak. In America, the introduction of the process is usually associated with the furniture maker Gustav Stickley at the beginning of the 20th century, but fuming was known in Europe before this.
The wood to be fumed is placed in a sealed chamber with all the surfaces to be fumed exposed to freely circulating air. A large shallow container of ammonium hydroxide solution is placed on the floor of the chamber and the chamber is sealed. If the chamber is large or the fuming is to be done for a long time, more than one container may be provided, or the ammonia may be replenished during the process. The fuming time depends on the amount of darkening required, the size of the chamber, and the strength of the ammonia used. It is usual to oil the wood after fuming to fully bring out the effect. [1]
Fuming has an advantage over staining because it does not obscure the grain, it merely darkens it. Unlike staining, there is no possibility of blotches or runs. Fuming is also colourfast. Fuming has the disadvantage that it is not a precise process. Different batches of wood will react to fuming differently. For this reason, wood to be fumed for a project is often harvested from the same tree. Even so, boards from the same tree, and different regions of the same board, can still have a noticeably different colour. Where a consistent colour is important, staining or aniline dyeing may be better options. [2]
Fuming has some safety issues. The solution of ammonium hydroxide used is much stronger (26% to 30%) than in household ammonia and is corrosive. The fuming must be done in an enclosed sealed chamber. Ammonia splashes can burn skin and the fumes can cause burns to eyes and lungs. [3] Operators need to wear gas masks, gloves and eye protection. [4]
The darkening of the colour relies on the ammonia reacting with tannins in the wood. The process is usually applied to white oak, as this wood has a high tannin content. Red oak may turn greenish rather than deep brown. Other species may not darken as noticeably as white oak, depending on the tannin content. The effect of fuming can be enhanced in non-tannic woods by applying a coat of tannic acid to the surface before fuming. [5]
Fuming was an accidental discovery in England [6] after it was noticed that oak boards stored in a stable had darkened. This was caused by the ammonia fumes from the horse urine reacting with the wood. [7] At the end of the 19th and beginning of the 20th centuries fuming became popular with furniture makers in the Arts and Crafts movement. The technique was introduced to the US by Gustav Stickley in 1901 [8] and a manufacturing technique was perfected in the mission style furniture line of the Stickley family business. [9] Stickley also described a method of fuming the wooden architecture of an entire room by placing bowls of ammonia in the room and sealing it. This method was not very practical and quite dangerous for the person placing the ammonia without personal protective equipment available to modern workers. [10] Stickley was quickly followed by other American Arts and Crafts furniture makers such as Charles Limbert and the Roycroft community. [11]
Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the formula NH3. A stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pungent smell. Biologically, it is a common nitrogenous waste, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to fertilisers. Around 70% of ammonia produced industrially is used to make fertilisers in various forms and composition, such as urea and diammonium phosphate. Ammonia in pure form is also applied directly into the soil.
Nitric acid is the inorganic compound with the formula HNO3. It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into oxides of nitrogen. Most commercially available nitric acid has a concentration of 68% in water. When the solution contains more than 86% HNO3, it is referred to as fuming nitric acid. Depending on the amount of nitrogen dioxide present, fuming nitric acid is further characterized as red fuming nitric acid at concentrations above 86%, or white fuming nitric acid at concentrations above 95%.
Shellac is a resin secreted by the female lac bug on trees in the forests of India and Thailand. Chemically, it is mainly composed of aleuritic acid, jalaric acid, shellolic acid, and other natural waxes. It is processed and sold as dry flakes and dissolved in alcohol to make liquid shellac, which is used as a brush-on colorant, food glaze and wood finish. Shellac functions as a tough natural primer, sanding sealant, tannin-blocker, odour-blocker, stain, and high-gloss varnish. Shellac was once used in electrical applications as it possesses good insulation qualities and seals out moisture. Phonograph and 78 rpm gramophone records were made of shellac until they were replaced by vinyl long-playing records from 1948 onwards.
In chemistry, there are three definitions in common use of the word "base": Arrhenius bases, Brønsted bases, and Lewis bases. All definitions agree that bases are substances that react with acids, as originally proposed by G.-F. Rouelle in the mid-18th century.
Ammonium chloride is an inorganic chemical compound with the chemical formula NH4Cl, also written as [NH4]Cl. It is an ammonium salt of hydrogen chloride. It consists of ammonium cations [NH4]+ and chloride anions Cl−. It is a white crystalline salt that is highly soluble in water. Solutions of ammonium chloride are mildly acidic. In its naturally occurring mineralogic form, it is known as sal ammoniac. The mineral is commonly formed on burning coal dumps from condensation of coal-derived gases. It is also found around some types of volcanic vents. It is mainly used as fertilizer and a flavouring agent in some types of liquorice. It is a product of the reaction of hydrochloric acid and ammonia.
Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH3(aq). Although the name ammonium hydroxide suggests an alkali with the composition [NH+
4][OH−
], it is actually impossible to isolate samples of NH4OH. The ions NH+
4 and OH− do not account for a significant fraction of the total amount of ammonia except in extremely dilute solutions.
Iron gall ink is a purple-black or brown-black ink made from iron salts and tannic acids from vegetable sources. It was the standard ink formulation used in Europe for the 1400-year period between the 5th and 19th centuries, remained in widespread use well into the 20th century, and is still sold today.
Tannic acid is a specific form of tannin, a type of polyphenol. Its weak acidity (pKa around 6) is due to the numerous phenol groups in the structure. The chemical formula for commercial tannic acid is often given as C76H52O46, which corresponds with decagalloyl glucose, but in fact it is a mixture of polygalloyl glucoses or polygalloyl quinic acid esters with the number of galloyl moieties per molecule ranging from 2 up to 12 depending on the plant source used to extract the tannic acid. Commercial tannic acid is usually extracted from any of the following plant parts: Tara pods (Caesalpinia spinosa), gallnuts from Rhus semialata or Quercus infectoria or Sicilian sumac leaves (Rhus coriaria).
Classical qualitative inorganic analysis is a method of analytical chemistry which seeks to find the elemental composition of inorganic compounds. It is mainly focused on detecting ions in an aqueous solution, therefore materials in other forms may need to be brought to this state before using standard methods. The solution is then treated with various reagents to test for reactions characteristic of certain ions, which may cause color change, precipitation and other visible changes.
Whiteprint describes a document reproduction produced by using the diazo chemical process. It is also known as the blue-line process since the result is blue lines on a white background. It is a contact printing process that accurately reproduces the original in size, but cannot reproduce continuous tones or colors. The light sensitivity of the chemicals used was known in the 1890s and several related printing processes were patented at that time. Whiteprinting replaced the blueprint process for reproducing architectural and engineering drawings because the process was simpler and involved fewer toxic chemicals. A blue-line print is not permanent and will fade if exposed to light for weeks or months, but a drawing print that lasts only a few months is sufficient for many purposes.
Gustav Stickley was an American furniture manufacturer, design leader, publisher, and a leading voice in the American Arts and Crafts movement. Stickley's design philosophy was a major influence on American Craftsman architecture.
Silica fume, also known as microsilica, is an amorphous (non-crystalline) polymorph of silicon dioxide, silica. It is an ultrafine powder collected as a by-product of the silicon and ferrosilicon alloy production and consists of spherical particles with an average particle diameter of 150 nm. The main field of application is as pozzolanic material for high performance concrete.
Wood finishing refers to the process of refining or protecting a wooden surface, especially in the production of furniture where typically it represents between 5 and 30% of manufacturing costs.
Ammonia production takes place worldwide, mostly in large-scale manufacturing plants that produce 183 million metric tonnes of ammonia (2021) annually. Leading producers are China (31.9%), Russia (8.7%), India (7.5%), and the United States (7.1%). 80% or more of ammonia is used as fertilizer. Ammonia is also used for the production of plastics, fibres, explosives, nitric acid, and intermediates for dyes and pharmaceuticals. The industry contributes 1% to 2% of global CO
2. Between 18-20 Mt of the gas is transported globally each year.
Quarter sawing or quartersawing is a woodworking process that produces quarter-sawn or quarter-cut boards in the rip cutting of logs into lumber. The resulting lumber can also be called radially-sawn or simply quartered. There is widespread confusion between the terms rift sawn and quarter sawn with the terms defined both with opposite meanings and as synonyms.
The phenolic content in wine refers to the phenolic compounds—natural phenol and polyphenols—in wine, which include a large group of several hundred chemical compounds that affect the taste, color and mouthfeel of wine. These compounds include phenolic acids, stilbenoids, flavonols, dihydroflavonols, anthocyanins, flavanol monomers (catechins) and flavanol polymers (proanthocyanidins). This large group of natural phenols can be broadly separated into two categories, flavonoids and non-flavonoids. Flavonoids include the anthocyanins and tannins which contribute to the color and mouthfeel of the wine. The non-flavonoids include the stilbenoids such as resveratrol and phenolic acids such as benzoic, caffeic and cinnamic acids.
Fumed Oak is a short play in two scenes by Noël Coward, one of ten that make up Tonight at 8.30, a cycle written to be performed across three evenings. Coward billed the work as an "unpleasant comedy in two scenes". The play concerns a downtrodden, middle-aged salesman who, having saved up enough money to cut all ties, walks out on his wife, mother-in-law and "horrible adenoidal daughter", having first told all three what he thinks of them.
Ammonium carbamate is a chemical compound with the formula [NH4][H2NCO2] consisting of ammonium cation NH+4 and carbamate anion NH2COO−. It is a white solid that is extremely soluble in water, less so in alcohol. Ammonium carbamate can be formed by the reaction of ammonia NH3 with carbon dioxide CO2, and will slowly decompose to those gases at ordinary temperatures and pressures. It is an intermediate in the industrial synthesis of urea (NH2)2CO, an important fertilizer.
A cabinet is a case or cupboard with shelves and/or drawers for storing or displaying items. Some cabinets are stand alone while others are built in to a wall or are attached to it like a medicine cabinet. Cabinets are typically made of wood, coated steel, or synthetic materials. Commercial grade cabinets usually have a melamine-particleboard substrate and are covered in a high pressure decorative laminate, commonly referred to as Wilsonart or Formica.