Atsushi Negishi

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Atsushi Negishi and Pretty Darling competing at the 2012 Summer Olympics in London. Olympic Cross-country Greenwich 2012 - Atsushi NEGISHI.jpg
Atsushi Negishi and Pretty Darling competing at the 2012 Summer Olympics in London.

Atsushi Negishi (born 20 March 1977 in Chichibu) is a Japanese equestrian. [1] At the 2012 Summer Olympics he competed in the Individual eventing. [2]

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A coupling reaction in organic chemistry refers to a variety of reactions where two fragments are joined together. Often such reactions require the aid of a metal catalyst. In one important reaction type, a main group organometallic compound of the type R-M reacts with an organic halide of the type R'-X with formation of a new carbon-carbon bond in the product R-R'. The most common type of coupling reaction is the cross coupling reaction.

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The Negishi coupling is a widely employed transition metal catalyzed cross-coupling reaction. The reaction couples organic halides or triflates with organozinc compounds, forming carbon-carbon bonds (C-C) in the process. A palladium (0) species is generally utilized as the metal catalyst, though nickel is sometimes used. A variety of nickel catalysts in either Ni0 or NiII oxidation state can be employed in Negishi cross couplings such as Ni(PPh3)4, Ni(acac)2, Ni(COD)2 etc.

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References

  1. "Atsushi Negishi". London2012.com. Archived from the original on 1 May 2013.
  2. "Atsushi Negishi". London 2012. BBC Sport. Retrieved 10 September 2012.