Barrerite

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Barrerite
Barrerite-27538.jpg
Barrerite from Kuiu Island, Alaska, USA.
General
Category Zeolite
Formula
(repeating unit)
(Na,K,Ca)2Al2Si7O18·6(H2O)
IMA symbol Bre [1]
Strunz classification 9.GE.15
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Amma
Identification
ColorWhite, pink
Cleavage Perfect
Mohs scale hardness3 - 4
Luster Vitreous-glassy
Streak White
Diaphaneity Transparent to translucent
Specific gravity 2.13
Optical propertiesBiaxial (-)
Refractive index nα = 1.479 nβ = 1.485 nγ = 1.489
References [2] [3] [4]

Barrerite is a tectosilicate mineral and a member of the zeolite family. It is one of the rarer zeolites. It was named for Richard Barrer, a New Zealand-born chemist. [4]

Barrerite crystal are white to pinkish, with a vitreous-glassy luster. The crystal system is orthorhombic and is flat and tabular in appearance. It has a Mohs hardness of 3 to 4 and its cleavage is perfect. Barrerite has a white streak and a density of 2.13.

It was first described in 1974 for an occurrence in Sardinia at Sant' Efisio Tower on Cape Pula in Cagliari Province. [4] It has also been reported from Rocky Pass, Kuiu Island, Alaska, and a few other localities.

Related Research Articles

<span class="mw-page-title-main">Prehnite</span>

Prehnite is an inosilicate of calcium and aluminium with the formula: Ca2Al(AlSi3O10)(OH)2. Limited Fe3+ substitutes for aluminium in the structure. Prehnite crystallizes in the orthorhombic crystal system, and most often forms as stalactitic or botryoidal aggregates, with only just the crests of small crystals showing any faces, which are almost always curved or composite. Very rarely will it form distinct, well-individualized crystals showing a square-like cross-section, including those found at the Jeffrey Mine in Asbestos, Quebec, Canada. Prehnite is brittle with an uneven fracture and a vitreous to pearly luster. Its hardness is 6-6.5, its specific gravity is 2.80-2.90 and its color varies from light green to yellow, but also colorless, blue, pink or white. In April 2000, rare orange prehnite was discovered in the Kalahari Manganese Fields, South Africa. Prehnite is mostly translucent, and rarely transparent.

<span class="mw-page-title-main">Chabazite</span> Tectosilicate mineral of the zeolite group

Chabazite is a tectosilicate mineral of the zeolite group, closely related to gmelinite, with the chemical formula (Ca,K
2
,Na
2
,Mg)Al
2
Si
4
O
12
•6H
2
O
. Recognized varieties include Chabazite-Ca, Chabazite-K, Chabazite-Na, and Chabazite-Sr, depending on the prominence of the indicated cation.

<span class="mw-page-title-main">Natrolite</span> Zeolite mineral

Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula Na2Al2Si3O10·2H2O. The type locality is Hohentwiel, Hegau, Germany.

<span class="mw-page-title-main">Heulandite</span>

Heulandite is the name of a series of tecto-silicate minerals of the zeolite group. Prior to 1997, heulandite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named:

<span class="mw-page-title-main">Mordenite</span>

Mordenite is a zeolite mineral with the chemical formula, (Ca, Na2, K2)Al2Si10O24·7H2O. and it is one of the six most abundant zeolites and is used commercially.

<span class="mw-page-title-main">Harmotome</span> Rare zeolite mineral

Harmotome is a mineral, one of the rarer zeolites; a hydrated barium silicate with formula: (Ba0.5,Ca0.5,Na,K)5Al5,Si11O32·12(H2O). It forms vitreous white well defined monoclinic crystals, often associated with calcite and other zeolites. It has a Mohs hardness of 4 to 5 and a specific gravity of 2.44 to 2.5.

<span class="mw-page-title-main">Molybdite</span>

Molybdite is the naturally occurring mineral form of molybdenum trioxide MoO3. It occurs as yellow to greenish needles and crystallizes in the orthorhombic crystal system.

<span class="mw-page-title-main">Cavansite</span>

Cavansite, whose name is derived from its chemical composition, calcium vanadium silicate, is a deep blue hydrous calcium vanadium phyllosilicate mineral, occurring as a secondary mineral in basaltic and andesitic rocks along with a variety of zeolite minerals. It's blue coloring comes from vanadium, a metal ion. Discovered in 1967 in Malheur County, Oregon, cavansite is a relatively rare mineral. It is polymorphic with the even rarer mineral, pentagonite. It is most frequently found in Pune, India and in the Deccan Traps, a large igneous province.

<span class="mw-page-title-main">Celadonite</span>

Celadonite is a mica group mineral, a phyllosilicate of potassium, iron in both oxidation states, aluminium and hydroxide with formula K(Mg,Fe2+
)(Fe3+
,Al)[Si
4
O
10
](OH)
2
.

<span class="mw-page-title-main">Thomsonite</span> Thomsonite series of the zeolite group

Thomsonite is the name of a series of tecto-silicate minerals of the zeolite group. Prior to 1997, thomsonite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named thomsonite-Ca and thomsonite-Sr. Thomsonite-Ca, by far the more common of the two, is a hydrous sodium, calcium and aluminium silicate, NaCa2Al5Si5O20·6H2O. Strontium can substitute for the calcium and the appropriate species name depends on the dominant element. The species are visually indistinguishable and the series name thomsonite is used whenever testing has not been performed. Globally, thomsonite is one of the rarer zeolites.

<span class="mw-page-title-main">Mesolite</span> Zeolite mineral

Mesolite is a tectosilicate mineral with formula Na2Ca2(Al2Si3O10)3·8H2O. It is a member of the zeolite group and is closely related to natrolite which it also resembles in appearance.

<span class="mw-page-title-main">Pollucite</span> Zeolite mineral

Pollucite is a zeolite mineral with the formula (Cs,Na)2Al2Si4O12·2H2O with iron, calcium, rubidium and potassium as common substituting elements. It is important as a significant ore of caesium and sometimes rubidium. It forms a solid solution series with analcime. It crystallizes in the isometric - hexoctahedral crystal system as colorless, white, gray, or rarely pink and blue masses. Well formed crystals are rare. It has a Mohs hardness of 6.5 and a specific gravity of 2.9. It has a brittle fracture and no cleavage.

<span class="mw-page-title-main">Brewsterite</span> Series of tectosilicate minerals

Brewsterite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, brewsterite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named brewsterite-Sr and brewsterite-Ba. Brewsterite-Sr, the more common of these, is a hydrous strontium and aluminium silicate, (Sr,Ba)2Al4Si12O32·10H2O. Small amounts of barium is usually present replacing part of the strontium. The appropriate species name depends on the dominant element. The species are visually indistinguishable, and the series name brewsterite is still used whenever testing has not been performed.

<span class="mw-page-title-main">Margarite</span>

Margarite is a calcium rich member of the mica group of the phyllosilicates with formula: CaAl2(Al2Si2)O10(OH)2. It forms white to pinkish or yellowish gray masses or thin laminae. It crystallizes in the monoclinic crystal system. It typically has a specific gravity of around 3 and a Mohs hardness of 4. It is translucent with perfect 010 cleavage and exhibits crystal twinning.

Partheite or parthéite is a calcium aluminium silicate and a member of the zeolite group of minerals, a group of silicates with large open channels throughout the crystal structure, which allow passage of liquids and gasses through the mineral. It was first discovered in 1979 in rodingitic dikes in an ophiolite zone of the Taurus Mountains in southwest Turkey. The second discovery occurred in gabbro-pegmatites in the Ural Mountains, Russia. Since its discovery and naming, the chemical formula for partheite has been revised from CaAl2Si2O8•2H2O to include not only water but hydroxyl groups as well. The framework of the mineral is interrupted due to these hydroxyl groups attaching themselves to aluminum centered oxygen tetrahedra. This type of interrupted framework is known in only one other zeolite, the mineral roggianite. As a silicate based mineral with the properties of a zeolite, partheite was first described as zeolite-like in 1984 and listed as a zeolite in 1985. Partheite and lawsonite are polymorphs. Associated minerals include prehnite, thomsonite, augite, chlorite and tremolite.

Paulingite or paulingite-K is a rare zeolite mineral that is found in vesicles in the basaltic rocks from the Columbia River near Rock Island Dam, Washington.

<span class="mw-page-title-main">Cahnite</span>

Cahnite (Cahnit in German, Cahnita in Spanish, Канит in Russian) is a brittle white or colorless mineral that has perfect cleavage and is usually transparent. It usually forms tetragonal-shaped crystals and it has a hardness of 3 mohs. Cahnite was discovered in the year 1921. It was named Cahnite to honor Lazard Cahn (1865–1940), who was a mineral collector and dealer. It is usually found in the Franklin Mine, in Franklin, New Jersey, but has also been found in Japan as well as in the Vallerano quarries in Rome, Italy. The geological environment that it occurs in is in pegmatites cutting a changed zinc orebody. The chemical formula for cahnite is Ca2B[AsO4](OH)4. It is made up of 26.91% calcium, 3.63% boron, 25.15% arsenic, 1.35% hydrogen, and 42.96% oxygen. It has a molecular weight of 297.91 grams. Cahnite is not radioactive. Cahnite is associated with these other minerals: willemite, rhodonite, pyrochroite, hedyphane, datolite, and baryte.

<span class="mw-page-title-main">Magadiite</span>

Magadiite is a hydrous sodium silicate mineral (NaSi7O13(OH)3·4(H2O)) which precipitates from alkali brines as an evaporite phase. It forms as soft (Mohs hardness of 2) white powdery monoclinic crystal masses. The mineral is unstable and decomposes during diagenesis leaving a distinctive variety of chert (Magadi-type chert).

<span class="mw-page-title-main">Stellerite</span> Zeolite mineral

Stellerite is a rare mineral discovered by and named after Georg Wilhelm Steller, a German explorer and zoologist. The mineral has a general formula of Ca[Al2Si7O18]·7H2O. Like most rare minerals, there are few commercial uses for stellerite. Mineral collectors are lucky to find it in good enough crystal form. Zeolites, including stellerite, have been studied using a dehydration process to gauge the potential use of their phases as molecular sieves, sorbents, and catalysts.

<span class="mw-page-title-main">Wairakite</span>

Wairakite is a zeolite mineral with an analcime structure but containing a calcium ion. The chemical composition is Ca8(Al16Si32O96)•16H2O. It is named for the location of its discovery in Wairakei, North Island, New Zealand, by Alfred Steiner in 1955. The first finds were in hydrothermally altered rhyolitic tuffs, ignimbrites and volcaniclastic rocks. The mineral has since been found in metamorphic rocks and in geothermal areas. It was most likely first successfully synthesized in a laboratory in 1970.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Mineralienatlas - Fossilienatlas". www.mineralienatlas.de. Retrieved 2023-06-29.
  3. "Barrerite Mineral Data". webmineral.com. Retrieved 2023-06-29.
  4. 1 2 3 "Barrerite".