Bioconversion

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Bioconversion, also known as biotransformation, is the conversion of organic materials, such as plant or animal waste, into usable products or energy sources by biological processes or agents, such as certain microorganisms. One example is the industrial production of cortisone, which one step is the bioconversion of progesterone to 11-alpha-Hydroxyprogesterone by Rhizopus nigricans. Another example is the bioconversion of glycerol to 1,3-propanediol, which is part of scientific research for many decades.

Another example of bioconversion is the conversion of organic materials, such as plant or animal waste, into usable products or energy sources by biological processes or agents, such as certain microorganisms, some detritivores or enzymes.

In the US, the Bioconversion Science and Technology group performs multidisciplinary R&D for the Department of Energy's (DOE) relevant applications of bioprocessing, especially with biomass. Bioprocessing combines the disciplines of chemical engineering, microbiology and biochemistry. The Group 's primary role is investigation of the use of microorganism, microbial consortia and microbial enzymes in bioenergy research. New cellulosic ethanol conversion processes have enabled the variety and volume of feedstock that can be bioconverted to expand rapidly. Feedstock now includes materials derived from plant or animal waste such as paper, auto-fluff, tires, fabric, construction materials, municipal solid waste (MSW), sludge, sewage, etc.

Three different processes for bioconversion

1 - Enzymatic hydrolysis - a single source of feedstock, switchgrass for example, is mixed with strong enzymes which convert a portion of cellulosic material into sugars which can then be fermented into ethanol. Genencor and Novozymes are two companies that have received United States government Department of Energy funding for research into reducing the cost of cellulase, a key enzyme in the production cellulosic ethanol by this process.

2 - Synthesis gas fermentation - a blend of feedstock, not exceeding 30% water, is gasified in a closed environment into a syngas containing mostly carbon monoxide and hydrogen. The cooled syngas is then converted into usable products through exposure to bacteria or other catalysts. BRI Energy, LLC [1] is a company whose pilot plant in Fayetteville, Arkansas is currently using synthesis gas fermentation to convert a variety of waste into ethanol. After gasification, anaerobic bacteria ( Clostridium ljungdahlii ) are used to convert the syngas (CO, CO2, and H2) into ethanol. The heat generated by gasification is also used to co-generate excess electricity.

3 - C.O.R.S. [2] and Grub Composting are sustainable technologies [3] that employ organisms that feed on organic matter to reduce and convert organic waste in to high quality feedstuff and oil rich material for the biodiesel industry. [4] Organizations pioneering this novel approach to waste management are EAWAG, [5] ESR International, [6] Prota Culture [7] and BIOCONVERSION [8] that created the e-CORS® system [9] to meet large scale organic waste management needs and environmental sustainability in both urban and livestock farming reality. This type of engineered system introduces a substantial innovation represented by the automatic modulation of the treatment, able to adapt conditions of the system to the biology of the scavenger used, improving their performances and the power of this technology.

Related Research Articles

<span class="mw-page-title-main">Biofuel</span> Type of biological fuel produced from biomass from which energy is derived

Biofuel is a fuel that is produced over a short time span from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels such as oil. Biofuel can be produced from plants or from agricultural, domestic or industrial biowaste. Biofuels are mostly used for transportation, but can also be used for heating and electricity. Biofuels are regarded as a renewable energy source. The use of biofuel has been subject to criticism regarding the "food vs fuel" debate, varied assessments of their sustainability, and possible deforestation and biodiversity loss as a result of biofuel production.

<span class="mw-page-title-main">Gasification</span> Form of energy conversion

Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (CO2). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H2 and CO of which the gas is largely composed. Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from biomass feedstock.

Cellulosic ethanol is ethanol produced from cellulose rather than from the plant's seeds or fruit. It can be produced from grasses, wood, algae, or other plants. It is generally discussed for use as a biofuel. The carbon dioxide that plants absorb as they grow offsets some of the carbon dioxide emitted when ethanol made from them is burned, so cellulosic ethanol fuel has the potential to have a lower carbon footprint than fossil fuels.

<span class="mw-page-title-main">Biorefinery</span> Refinery that converts biomass to energy and other beneficial byproducts

A biorefinery is a refinery that converts biomass to energy and other beneficial byproducts. The International Energy Agency Bioenergy Task 42 defined biorefining as "the sustainable processing of biomass into a spectrum of bio-based products and bioenergy ". As refineries, biorefineries can provide multiple chemicals by fractioning an initial raw material (biomass) into multiple intermediates that can be further converted into value-added products. Each refining phase is also referred to as a "cascading phase". The use of biomass as feedstock can provide a benefit by reducing the impacts on the environment, as lower pollutants emissions and reduction in the emissions of hazard products. In addition, biorefineries are intended to achieve the following goals:

  1. Supply the current fuels and chemical building blocks
  2. Supply new building blocks for the production of novel materials with disruptive characteristics
  3. Creation of new jobs, including rural areas
  4. Valorization of waste
  5. Achieve the ultimate goal of reducing GHG emissions
<span class="mw-page-title-main">Bioenergy</span> Renewable energy made from biomass

Bioenergy is a type of renewable energy that is derived from plants and animal waste. The biomass that is used as input materials consists of recently living organisms, mainly plants. Thus, fossil fuels are not regarded as biomass under this definition. Types of biomass commonly used for bioenergy include wood, food crops such as corn, energy crops and waste from forests, yards, or farms.

<span class="mw-page-title-main">Biomass to liquid</span>

Biomass to liquid is a multi-step process of producing synthetic hydrocarbon fuels made from biomass via a thermochemical route.

<span class="mw-page-title-main">Waste-to-energy</span> Process of generating energy from the primary treatment of waste

Waste-to-energy (WtE) or energy-from-waste (EfW) is the process of generating energy in the form of electricity and/or heat from the primary treatment of waste, or the processing of waste into a fuel source. WtE is a form of energy recovery. Most WtE processes generate electricity and/or heat directly through combustion, or produce a combustible fuel commodity, such as methane, methanol, ethanol or synthetic fuels, often derived from the product syngas.

<span class="mw-page-title-main">Bioconversion of biomass to mixed alcohol fuels</span>

The bioconversion of biomass to mixed alcohol fuels can be accomplished using the MixAlco process. Through bioconversion of biomass to a mixed alcohol fuel, more energy from the biomass will end up as liquid fuels than in converting biomass to ethanol by yeast fermentation.

<span class="mw-page-title-main">Lignocellulosic biomass</span> Plant dry matter

Lignocellulose refers to plant dry matter (biomass), so called lignocellulosic biomass. It is the most abundantly available raw material on the Earth for the production of biofuels. It is composed of two kinds of carbohydrate polymers, cellulose and hemicellulose, and an aromatic-rich polymer called lignin. Any biomass rich in cellulose, hemicelluloses, and lignin are commonly referred to as lignocellulosic biomass. Each component has a distinct chemical behavior. Being a composite of three very different components makes the processing of lignocellulose challenging. The evolved resistance to degradation or even separation is referred to as recalcitrance. Overcoming this recalcitrance to produce useful, high value products requires a combination of heat, chemicals, enzymes, and microorganisms. These carbohydrate-containing polymers contain different sugar monomers and they are covalently bound to lignin.

The United States produces mainly biodiesel and ethanol fuel, which uses corn as the main feedstock. The US is the world's largest producer of ethanol, having produced nearly 16 billion gallons in 2017 alone. The United States, together with Brazil accounted for 85 percent of all ethanol production, with total world production of 27.05 billion gallons. Biodiesel is commercially available in most oilseed-producing states. As of 2005, it was somewhat more expensive than fossil diesel, though it is still commonly produced in relatively small quantities.

<span class="mw-page-title-main">Green waste</span> Biodegradable waste

Green waste, also known as "biological waste", is any organic waste that can be composted. It is most usually composed of refuse from gardens such as grass clippings or leaves, and domestic or industrial kitchen wastes. Green waste does not include things such as dried leaves, pine straw, or hay. Such materials are rich in carbon and considered "brown wastes," while green wastes contain high concentrations of nitrogen. Green waste can be used to increase the efficiency of many composting operations and can be added to soil to sustain local nutrient cycling.

Renewable Fuels are fuels produced from renewable resources. Examples include: biofuels, Hydrogen fuel, and fully synthetic fuel produced from ambient carbon dioxide and water. This is in contrast to non-renewable fuels such as natural gas, LPG (propane), petroleum and other fossil fuels and nuclear energy. Renewable fuels can include fuels that are synthesized from renewable energy sources, such as wind and solar. Renewable fuels have gained in popularity due to their sustainability, low contributions to the carbon cycle, and in some cases lower amounts of greenhouse gases. The geo-political ramifications of these fuels are also of interest, particularly to industrialized economies which desire independence from Middle Eastern oil.

Plasma gasification is an extreme thermal process using plasma which converts organic matter into a syngas which is primarily made up of hydrogen and carbon monoxide. A plasma torch powered by an electric arc is used to ionize gas and catalyze organic matter into syngas, with slag remaining as a byproduct. It is used commercially as a form of waste treatment, and has been tested for the gasification of refuse-derived fuel, biomass, industrial waste, hazardous waste, and solid hydrocarbons, such as coal, oil sands, petcoke and oil shale.

Second-generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of non-food biomass. Biomass in this context means plant materials and animal waste used especially as a source of fuel.

Biogasoline is a type of gasoline produced from biomass such as algae. Like traditionally produced gasoline, it is made up of hydrocarbons with 6 (hexane) to 12 (dodecane) carbon atoms per molecule and can be used in internal combustion engines. However, unlike traditional gasoline/petroleum based fuels, which are mainly composed from oil, biogasolines are made from plants such as beets and sugarcane or cellulosic biomass- substances normally referred to as plant waste.

Syngas fermentation, also known as synthesis gas fermentation, is a microbial process. In this process, a mixture of hydrogen, carbon monoxide, and carbon dioxide, known as syngas, is used as carbon and energy sources, and then converted into fuel and chemicals by microorganisms.

<span class="mw-page-title-main">Ze-gen</span> Converting waste into synthesis gas since 2004

Ze-gen, Inc. was a renewable energy company developing advanced gasification technology to convert waste into synthesis gas. Founded in 2004, Ze-gen was a venture-backed company based in Boston, Massachusetts.

Bioproducts or bio-based products are materials, chemicals and energy derived from renewable biological material.

References

  1. ↑ "Clean Technology for Renewable Energy". www.brienergy.com.
  2. ↑ Diener, Stefan; Zurbrügg, Christian; Tockner, Klement (2009-06-05). "Conversion of organic material by black soldier fly larvae: establishing optimal feeding rates". Waste Management & Research. 27 (6). SAGE Publications: 603–610. Bibcode:2009WMR....27..603D. doi:10.1177/0734242x09103838. ISSN   0734-242X. PMID   19502252. S2CID   12304792.
  3. ↑ Craig Sheppard, D.; Larry Newton, G.; Thompson, Sidney A.; Savage, Stan (1994). "A value added manure management system using the black soldier fly". Bioresource Technology. 50 (3). Elsevier BV: 275–279. Bibcode:1994BiTec..50..275C. doi:10.1016/0960-8524(94)90102-3. ISSN   0960-8524.
  4. ↑ Li, Qing; Zheng, Longyu; Cai, Hao; Garza, E.; Yu, Ziniu; Zhou, Shengde (2011). "From organic waste to biodiesel: Black soldier fly, Hermetia illucens, makes it feasible". Fuel. 90 (4). Elsevier BV: 1545–1548. doi:10.1016/j.fuel.2010.11.016. ISSN   0016-2361.
  5. ↑ "Abteilung Siedlungshygiene und Wasser für Entwicklung - Eawag". www.eawag.ch.
  6. ↑ "Archived copy". Archived from the original on 2016-05-16. Retrieved 2011-11-14.{{cite web}}: CS1 maint: archived copy as title (link)
  7. ↑ "Prota™Culture & the BioPod™ - Advanced Composting Using Black Soldier Fly: The Future of Food Waste Diversion & Recycling". Archived from the original on 2012-04-02. Retrieved 2019-06-09.
  8. ↑ "Contatti". www.bioconversion.it. Archived from the original on 2019-08-06. Retrieved 2010-03-09.
  9. ↑ "Sistema per il compostaggio di rifiuti organici basato sull'azioni di insetti saprofagi" (PDF). www.bioconversion.it. 4 March 2012. Archived from the original (PDF) on 4 March 2012.
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