In organic chemistry, an amide, also known as an organic amide or a carboxamide, is a compound with the general formula R−C(=O)−NR′R″, where R, R', and R″ represent any group, typically organyl groups or hydrogen atoms. The amide group is called a peptide bond when it is part of the main chain of a protein, and an isopeptide bond when it occurs in a side chain, such as in the amino acids asparagine and glutamine. It can be viewed as a derivative of a carboxylic acid with the hydroxyl group replaced by an amine group ; or, equivalently, an acyl (alkanoyl) group joined to an amine group.
Ascorbic acid is an organic compound with formula C
6H
8O
6, originally called hexuronic acid. It is a white solid, but impure samples can appear yellowish. It dissolves freely in water to give mildly acidic solutions. It is a mild reducing agent.
Tetrahydrofuran (THF), or oxolane, is an organic compound with the formula (CH2)4O. The compound is classified as heterocyclic compound, specifically a cyclic ether. It is a colorless, water-miscible organic liquid with low viscosity. It is mainly used as a precursor to polymers. Being polar and having a wide liquid range, THF is a versatile solvent.
Lithium aluminium hydride, commonly abbreviated to LAH, is an inorganic compound with the chemical formula Li[AlH4] or LiAlH4. It is a white solid, discovered by Finholt, Bond and Schlesinger in 1947. This compound is used as a reducing agent in organic synthesis, especially for the reduction of esters, carboxylic acids, and amides. The solid is dangerously reactive toward water, releasing gaseous hydrogen (H2). Some related derivatives have been discussed for hydrogen storage.
Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH3CO)2O. Commonly abbreviated Ac2O, it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis. It is a colorless liquid that smells strongly of acetic acid, which is formed by its reaction with moisture in the air.
Chemistry education is the study of teaching and learning chemistry. It is one subset of STEM education or discipline-based education research (DBER). Topics in chemistry education include understanding how students learn chemistry and determining the most efficient methods to teach chemistry. There is a constant need to improve chemistry curricula and learning outcomes based on findings of chemistry education research (CER). Chemistry education can be improved by changing teaching methods and providing appropriate training to chemistry instructors, within many modes, including classroom lectures, demonstrations, and laboratory activities.
Frank Henry Westheimer was an American chemist. He taught at the University of Chicago from 1936 to 1954, and at Harvard University from 1953 to 1983, becoming the Morris Loeb Professor of Chemistry in 1960, and Professor Emeritus in 1983. The Westheimer medal was established in his honor in 2002.
The alpha effect refers to the increased nucleophilicity of an atom due to the presence of an adjacent (alpha) atom with lone pair electrons. This first atom does not necessarily exhibit increased basicity compared with a similar atom without an adjacent electron-donating atom, resulting in a deviation from the classical Brønsted-type reactivity-basicity relationship. In other words, the alpha effect refers to nucleophiles presenting higher nucleophilicity than the predicted value obtained from the Brønsted basicity. The representative examples would be high nucleophilicities of hydroperoxide (HO2−) and hydrazine (N2H4). The effect is now well established with numerous examples and became an important concept in mechanistic chemistry and biochemistry. However, the origin of the effect is still controversial without a clear winner.
Robert George Bergman is an American chemist. He is Professor of the Graduate School and Gerald E. K. Branch Distinguished Professor Emeritus at the University of California, Berkeley.
In organic chemistry, vinylogy is the transmission of electronic effects through a conjugated organic bonding system. The concept was introduced in 1926 by Ludwig Claisen to explain the acidic properties of formylacetone and related ketoaldehydes. Formylacetone, technically CH3(C=O)CH2CH=O, only exists in the ionized form CH3(C−O−)=CH−CH=O or CH3(C=O)−CH=CH−O−. Its adjectival form, vinylogous, is used to describe functional groups in which the standard moieties of the group are separated by a carbon–carbon double bond.
George Simms Hammond was an American scientist and theoretical chemist who developed "Hammond's postulate", and fathered organic photochemistry,–the general theory of the geometric structure of the transition state in an organic chemical reaction. Hammond's research is also known for its influence on the philosophy of science. His research garnered him the Norris Award in 1968, the Priestley Medal in 1976, the National Medal of Science in 1994, and the Othmer Gold Medal in 2003. He served as the executive chairman of the Allied Chemical Corporation from 1979 to 1989.
Brian Frederick Gilbert Johnson is a British scientist and emeritus professor of chemistry at the University of Cambridge. He was also Master of Fitzwilliam College, Cambridge from 1999 to 2005.
This is a list of 194 sources that list elements classified as metalloids. The sources are listed in chronological order. Lists of metalloids differ since there is no rigorous widely accepted definition of metalloid. Individual lists share common ground, with variations occurring at the margins. The elements most often regarded as metalloids are boron, silicon, germanium, arsenic, antimony and tellurium. Other sources may subtract from this list, add a varying number of other elements, or both.
In chemistry, the amino radical, ·NH2, also known as the aminyl radical or azanyl radical, is the neutral form of the amide ion. Aminyl radicals are highly reactive and consequently short-lived, like most radicals; however, they form an important part of nitrogen chemistry. In sufficiently high concentration, amino radicals dimerise to form hydrazine. While NH2 as a functional group is common in nature, forming a part of many compounds, the radical cannot be isolated in its free form.
Melanie Sarah Sanford is an American chemist, currently the Moses Gomberg Distinguished University Professor of Chemistry and Arthur F. Thurnau Professor of Chemistry at the University of Michigan. She is a Fellow for the American Association for the Advancement of Science, and was elected a member of the National Academy of Sciences and the American Academy of Arts and Sciences in 2016. She has served as an executive editor of the Journal of the American Chemical Society since 2021, having been an associate editor of the since 2014.
Borane, also known as borine, is an unstable and highly reactive molecule with the chemical formula BH
3. The preparation of borane carbonyl, BH3(CO), played an important role in exploring the chemistry of boranes, as it indicated the likely existence of the borane molecule. However, the molecular species BH3 is a very strong Lewis acid. Consequently, it is highly reactive and can only be observed directly as a continuously produced, transitory, product in a flow system or from the reaction of laser ablated atomic boron with hydrogen. It normally dimerizes to diborane in the absence of other chemicals.
The Robert Foster Cherry Award is a prize given biennially by Baylor University for "great teaching". The Cherry Award honors professors at the College or University level, in the English-speaking world, with established track records of teaching excellence and the ability to inspire students. Robert Foster Cherry, a graduate of Baylor University, made an estate bequest to establish the award. In a typical award cycle, three Finalists are selected based on nomination packages. The Finalists then compete for the award by giving a series of lectures at Baylor University. Each Finalist receives $15,000 and the ultimate award Recipient receives an additional $250,000 prize. Although the Nobel Foundation doesn't award a Nobel prize for teaching, the Cherry Award is often dubbed as the highest teaching award in the world or the "Nobel Prize" for teaching.
Richmond Sarpong is a Ghanaian-American chemist who is a professor at the University of California, Berkeley. Sarpong works on natural product total synthesis to better understand biological systems and allow for the development of novel therapeutics. He was awarded a Guggenheim Fellowship in 2017, and was elected a fellow of the American Academy of Arts and Sciences in 2020. He serves on the editorial boards of Organic Syntheses, Accounts of Chemical Research and Synlett.
Imre Gyula Csizmadia was a Canadian Hungarian chemist, university professor, external member of the Hungarian Academy of Sciences.
