Bulletproof glass

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Bulletproof glass of a jeweler's window after a burglary attempt. Bulletproof glass window after a burglary attempt.jpg
Bulletproof glass of a jeweler's window after a burglary attempt.
The Mona Lisa behind bulletproof glass at the Louvre Museum MonaLisaShield.jpg
The Mona Lisa behind bulletproof glass at the Louvre Museum

Bulletproof glass, ballistic glass, transparent armor, or bullet-resistant glass is a strong and optically transparent material that is particularly resistant to penetration by projectiles. Like any other material, it is not completely impenetrable. It is usually made from a combination of two or more types of glass, one hard and one soft. [1] The softer layer makes the glass more elastic, so that it can flex instead of shatter. The index of refraction for all of the glasses used in the bulletproof layers must be almost the same to keep the glass transparent and allow a clear, undistorted view through the glass. Bulletproof glass varies in thickness from 34 to 3+12 inches (19 to 89 mm). [2] [3]

Contents

Bulletproof glass is used in windows of buildings that require such security, such as jewelry stores and embassies, and of military and private vehicles.

Construction

A rough visualisation of bulletproof glass, composed of layers of plastic sheeting (grey) and layers of glass (blue) Bulletproof glass visualisation.png
A rough visualisation of bulletproof glass, composed of layers of plastic sheeting (grey) and layers of glass (blue)

Bullet-resistant glass is constructed using layers of laminated glass. The more layers there are, the more protection the glass offers. When a weight reduction is needed, polycarbonate (a thermoplastic) is laminated onto the safe side to stop spall. The aim is to make a material with the appearance and clarity of standard glass but with effective protection from small arms. Polycarbonate designs usually consist of products such as Armormax, Makroclear, Cyrolon: a soft coating that heals after being scratched (such as elastomeric carbon-based polymers) or a hard coating that prevents scratching (such as silicon-based polymers). [4]

The plastic in laminate designs also provides resistance to impact from physical assault from blunt and sharp objects. The plastic provides little in the way of bullet-resistance. The glass, which is much harder than plastic, flattens the bullet, and the plastic deforms, with the aim of absorbing the rest of the energy and preventing penetration. The ability of the polycarbonate layer to stop projectiles with varying energy is directly proportional to its thickness, [5] and bulletproof glass of this design may be up to 3.5 inches thick. [3]

Laminated glass layers are built from glass sheets bonded together with polyvinyl butyral, polyurethane, Sentryglas, or ethylene-vinyl acetate. When treated with chemical processes, the glass becomes much stronger. This design has been in regular use on combat vehicles since World War II. It is typically thick and is usually extremely heavy. [6]

Sample thickness and weight for bullet-resistant glass materials [7] [8] [9]
Threat StoppedGlass LaminatePolycarbonateAcrylicGlass-Clad Polycarbonate Aluminum oxynitride
Protection Level(example)ThicknessWeightThicknessWeightThicknessWeightThicknessWeightThicknessWeight
in.mmlb/sq. ft.kg/m2in.mmlb/sq. ft.kg/m2in.mmlb/sq. ft.kg/m2in.mmlb/sq. ft.kg/m2in.mmlb/sq. ft.kg/m2
UL 752 Level 1 9 mm 3 shots1.18530.0915.2574.460.7519.054.622.461.2531.757.737.60.81820.788.9943.9
UL 752 Level 2 .357 Magnum 3 shots1.435.5617.9487.61.0326.166.431.251.37534.928.541.501.07527.311.6857.02
UL 752 Level 3 (approximately NIJ IIIA [10] ) .44 Magnum 3 shots (5 shots for NIJ IIIa)1.5940.3820.94102.241.2531.757.737.61.28832.7114.2369.47
UL 752 Level 4 .30-06 1 shot1.33835.2514.4369.47
UL 752 Level 5 7.62 mm 1 shot
UL 752 Level 6 .357 Magnum underloaded 5 shots
UL 752 Level 7 5.56x45 5 shots
UL 752 Level 8 (approximately NIJ III) 7.62 mm NATO 5 shots2.37460.326.01126.9918.25
UL 752 Level 9 .30-06 M2 AP 1 shot
UL 752 Level 10 .50 BMG 1 shot1.640.630.76150.1

9mm 124gr @ 1175-1293fps (1400-1530fps for Level 6), 357M 158gr @ 1250-1375fps, 44M 240gr @ 1350-1485fps, 30-06 180gr @ 2540-2794fps, 5.56NATO 55gr @ 3080-3388fps, 7.62NATO 150gr @ 2750-3025fps. For all ratings in the above chart; all copper-jacketed lead FMJ, except 44 mg is lead semi-wadcutter gas-check, and 30-06 is LEAD core soft point.

Test standards

Ballistic test of a bullet-resistant glass panel IDET2007 bulletproof glass armor.jpg
Ballistic test of a bullet-resistant glass panel

Bullet-resistant materials are tested using a gun to fire a projectile from a set distance into the material, in a specific pattern. Levels of protection are based on the ability of the target to stop a specific type of projectile traveling at a specific speed. Experiments suggest that polycarbonate fails at lower velocities with regular shaped projectiles compared to irregular ones (like fragments), meaning that testing with regular shaped projectiles gives a conservative estimate of its resistance. [11] When projectiles do not penetrate, the depth of the dent left by the impact can be measured and related to the projectile’s velocity and thickness of the material. [5] Some researchers have developed mathematical models based on results of this kind of testing to help them design bulletproof glass to resist specific anticipated threats. [12]

Environmental effects

The properties of bullet-resistant glass can be affected by temperature and by exposure to solvents or UV radiation, usually from sunlight. If the polycarbonate layer is below a glass layer, it has some protection from UV radiation due to the glass and bonding layer. Over time the polycarbonate becomes more brittle because it is an amorphous polymer (which is necessary for it to be transparent) that moves toward thermodynamic equilibrium. [4]

An impact on polycarbonate by a projectile at temperatures below −7 °C sometimes creates spall, pieces of polycarbonate that are broken off and become projectiles themselves. Experiments have demonstrated that the size of the spall is related to the thickness of the laminate rather than the size of the projectile. The spall starts in surface flaws caused by bending of the inner, polycarbonate layer and the cracks move “backwards” through to the impact surface. It has been suggested that a second inner layer of polycarbonate may effectively resist penetration by the spall. [4]

2000s advances

In 2005, it was reported that U.S. military researchers were developing a class of transparent armor incorporating aluminum oxynitride (ALON) as the outside "strike plate" layer. Traditional glass/polymer was demonstrated by ALON's manufacturer to require 2.3 times more thickness than ALON's, to guard against a .50 BMG projectile. [13] ALON is much lighter and performs much better than traditional glass/polymer laminates. Aluminum oxynitride "glass" can defeat threats like the .50 caliber armor-piercing rounds using material that is not prohibitively heavy. [14] [15]

Spinel ceramics

Certain types of ceramics can also be used for transparent armor due to their properties of increased density and hardness when compared to traditional glass. These types of synthetic ceramic transparent armors can allow for thinner armor with equivalent stopping power to traditional laminated glass. [16]

Air chamber glass

The newest type of curved transparent vehicle armor has an air chamber between the glass and the polycarbonate. Level IIIA (high speed 9 mm) armor consists of 8 mm of laminated glass (strike face), a 1 mm air gap, and 7 mm of polycarbonate. This solution stops the bullets in a totally different way. The glass, being hard, deforms the incoming bullet. The deformed bullet completely penetrates the glass and then it is stopped by the flexible polycarbonate. The weight reduction over traditional glass-clad polycarbonate is 35%, weighing 0.25 kilogram per square meter for level NIJ 06 IIIA (NIJ 07 HG2). It is also thinner (16.2 mm) vs conventional Glass Clad Polycarbonate (21 mm).

See also

Related Research Articles

<span class="mw-page-title-main">Reactive armour</span> Type of vehicle armour

Reactive armour is a type of vehicle armour used in protecting vehicles, especially modern tanks, against shaped charges and hardened kinetic energy penetrators. The most common type is explosive reactive armour (ERA), but variants include self-limiting explosive reactive armour (SLERA), non-energetic reactive armour (NERA), non-explosive reactive armour (NxRA), and electric armour. NERA and NxRA modules can withstand multiple hits, unlike ERA and SLERA.

<span class="mw-page-title-main">Bulletproof vest</span> Form of body armour that protects the torso from some projectiles

A bulletproof vest, also known as a ballistic vest or a bullet-resistant vest, is an item of body armour that helps absorb the impact and reduce or stop penetration to the torso by firearm-fired projectiles and fragmentation from explosions. The vest may come in a soft form, as worn by many police officers, prison officers, security guards, and some private citizens, used to protect against stabbing attacks or light projectiles, or hard form, using metallic or para-aramid components. Soldiers and police tactical units wear hard armour, either in conjunction with soft armour or alone, to protect against rifle ammunition or fragmentation.

<span class="mw-page-title-main">Chobham armour</span> British-designed composite tank armour

Chobham armour is the informal name of a composite armour developed in the 1960s at the British tank research centre on Chobham Common, Surrey. The name has since become the common generic term for composite ceramic vehicle armour. Other names informally given to Chobham armour include Burlington and Dorchester. Special armour is a broader informal term referring to any armour arrangement comprising sandwich reactive plates, including Chobham armour.

<span class="mw-page-title-main">Polycarbonate</span> Family of polymers

Polycarbonates (PC) are a group of thermoplastic polymers containing carbonate groups in their chemical structures. Polycarbonates used in engineering are strong, tough materials, and some grades are optically transparent. They are easily worked, molded, and thermoformed. Because of these properties, polycarbonates find many applications. Polycarbonates do not have a unique resin identification code (RIC) and are identified as "Other", 7 on the RIC list. Products made from polycarbonate can contain the precursor monomer bisphenol A (BPA).

<span class="mw-page-title-main">Flak jacket</span> Jacket or vest that protects against shell fragments

A flak jacket or flak vest is a form of body armor. A flak jacket is designed to provide protection from case fragments ("frag") from high explosive weaponry, such as anti-aircraft artillery, grenade fragments, some types of pellets used in shotguns, and other lower-velocity projectiles. It is not designed to protect against bullets fired from most small arms such as rifles or handguns. However flak jackets are able to sustain certain gunshots, depending on the angle at which the shot was fired, the caliber of the bullet, the speed of the projectile and the range from which the shot was fired.

<span class="mw-page-title-main">Vehicle armour</span> High-strength plating used to fortify important vehicles against bullets, shells etc.

Military vehicles are commonly armoured to withstand the impact of shrapnel, bullets, shells, rockets, and missiles, protecting the personnel inside from enemy fire. Such vehicles include armoured fighting vehicles like tanks, aircraft, and ships.

<span class="mw-page-title-main">Body armor</span> Protective clothing; armor worn on the body

Body armor, personal armor, armored suit (armoured) or coat of armor, among others, is protective clothing designed to absorb or deflect physical attacks. Historically used to protect military personnel, today it is also used by various types of police, private security guards, or bodyguards, and occasionally ordinary citizens. Today there are two main types: regular non-plated body armor for moderate to substantial protection, and hard-plate reinforced body armor for maximum protection, such as used by combatants.

<span class="mw-page-title-main">Bulletproofing</span> Provision for resisting fired bullets

Bulletproofing is the process of making an object capable of stopping a bullet or similar high velocity projectiles. The term bullet resistance is often preferred because few, if any, practical materials provide complete protection against all types of bullets, or multiple hits in the same location, or simply sufficient kinetic (movement) energy to overcome it.

<span class="mw-page-title-main">Ballistic plate</span> Protective armoured plate

A ballistic plate, also known as an armour plate, is a protective armoured plate inserted into a carrier or bulletproof vest, that can be used stand-alone, or in conjunction with other armour. "Hard armour" usually denotes armour that uses ballistic plates.

<span class="mw-page-title-main">Aluminium oxynitride</span> Transparent ceramic material

Aluminium oxynitride is a transparent ceramic composed of aluminium, oxygen and nitrogen. Aluminium oxynitride is optically transparent (≥ 80%) in the near-ultraviolet, visible, and mid-wave-infrared regions of the electromagnetic spectrum. It is four times as hard as fused silica glass, 85% as hard as sapphire, and nearly 115% as hard as magnesium aluminate spinel. It can be fabricated into transparent windows, plates, domes, rods, tubes, and other forms using conventional ceramic powder processing techniques.

<span class="mw-page-title-main">Spaced armour</span> Armour with plates spaced a distanced apart

Armour with two or more plates spaced a distance apart falls under the category of spaced armour. Spaced armour can be sloped or unsloped. When sloped, it reduces the penetrating power of bullets and solid shot, as after penetrating each plate projectiles tend to tumble, deflect, deform, or disintegrate; spaced armour that is not sloped is generally designed to provide protection from explosive projectiles, which detonate before reaching the primary armour. Spaced armour is used on military vehicles such as tanks and combat bulldozers. In a less common application, it is used in some spacecraft that use Whipple shields.

<span class="mw-page-title-main">Laminated glass</span> Type of safety glass with a thin polymer interlayer that holds together when shattered

Laminated glass is a type of safety glass consisting of two or more layers of glass with one or more thin polymer interlayers between them which prevent the glass from breaking into large sharp pieces. Breaking produces a characteristic "spider web" cracking pattern when the impact is not enough to completely pierce the glass.

<span class="mw-page-title-main">Ballistic shield</span> Police and military anti-projectile shields

A ballistic shield, also called a tactical shield or bulletproof shield, is a protection device deployed by police, paramilitaries, and armed forces that are designed to stop or deflect bullets and other projectiles fired at their carrier. Ballistic shields also protect from less serious threats such as thrown items. Ballistic shields are similar to riot shields, but offer greater protection and are typically used by special units or in situations where riot shields would not offer adequate protection.

Ceramic armor is armor used by armored vehicles and in personal armor to resist projectile penetration through its high hardness and compressive strength. In its most basic form, it consists of two primary components: A ceramic layer on the outer surface, called the "strike face," backed up by a ductile fiber reinforced plastic composite or metal layer. The role of the ceramic is to (1) fracture the projectile or deform the projectile nose upon impact, (2) erode and slow down the projectile remnant as it penetrates the shattered ceramic layer, and (3) distribute the impact load over a larger area, which can be absorbed by ductile polymer or metallic backings. Ceramics are often used where light weight is important, as they weigh less than metal alloys for a given degree of resistance. The most common materials are alumina, boron carbide, and, to a lesser extent, silicon carbide.

Liquid armour is a material under research by defense institutions and universities around the world including the United States Army Research Laboratory (ARL). Some of the earliest research in this area was performed at Massachusetts Institute of Technology and University of Delaware in 2003. Liquid armor was initially presented as a way to increase the survivability of soldiers in high risk roles while retaining their mobility, as reported by NPR in an interview with MIT professors and a U.S. admiral.

<span class="mw-page-title-main">Twinwall plastic</span>

Twin-wall plastic, specifically twin-wall polycarbonate, is an extruded multi-wall polymer product created for applications where its strength, thermally insulative properties, and moderate cost are ideal. Polycarbonate, which is most commonly formed through the reaction of Bisphenol A and Carbonyl Chloride, is an extremely versatile material. It is significantly lighter than glass, while managing to be stronger, more flexible, and more impact resistant. Twin-wall polycarbonate is used most commonly for green houses, where it can support itself in a structurally sound configuration, limit the amount of UV light due to its nominal translucence, and can withstand the rigors of daily abuse in an outdoor environment. The stagnant air in the cellular space between sheets provides insulation, and additional cell layers can be extruded to enhance insulative properties at the cost of light transmission.

Ballistic eyewear is a form of glasses or goggles that protect from small projectiles and fragments. For the U.S. military, choices are listed on the Authorized Protective Eyewear List (APEL). Ballistic eyewear including examples that meet APEL requirements are commercially available for anyone who wishes to buy it. The history of protective eyewear goes back to 1880 and extends through to World War I and the present. There are three standards that are currently used to test the effectiveness of ballistic eyewear. These include a U.S. civilian standard, a U.S. military standard (MIL-PRF-31013), and a European standard.

Armor has been used in the military for a long period of time during the course of history, but is becoming more frequently seen in the public sector as time passes. There are many different forms and ways that armor is being commercially used throughout the world today. The most popular and well-known uses are body and vehicle armor. There are other commercial uses including aircraft armor and armored glass.

The polyurethane urea elastomer (PUU), or poly(urethane urea) elastomer, is a flexible polymeric material that is composed of linkages made out of polyurethane and polyurea compounds. Due to its hyperelastic properties, it is capable of bouncing back high-speed ballistic projectiles as if the material had “hardened” upon impact. PUUs were developed by researchers from the U.S. Army Research Laboratory (ARL) and the Army’s Institute for Soldier Nanotechnology at the Massachusetts Institute of Technology (MIT) to potentially replace polyethylene materials in body armor and other protective gear, such as combat helmets, face shields, and ballistic vests.

References

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  8. Nationwide Structures Inc. "Ballistic Charts". Nationwidestructures.com. Retrieved 2014-08-04.
  9. "Surmet's ALON® Transparent Armor 50 Caliber Test". YouTube. 2011-03-14. Retrieved 2014-08-04.
  10. UL 752 Level 3 Bullet Resistant Fiberglass click on the lower chart
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