Bulletproof glass

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Bulletproof glass of a jeweler's window after a burglary attempt. Bulletproof glass window after a burglary attempt.jpg
Bulletproof glass of a jeweler's window after a burglary attempt.
The Mona Lisa behind bulletproof glass at the Louvre Museum MonaLisaShield.jpg
The Mona Lisa behind bulletproof glass at the Louvre Museum

Bulletproof glass, ballistic glass, transparent armor, or bullet-resistant glass is a strong and optically transparent material that is particularly resistant to penetration by projectiles, although, like any other material, it is not completely impenetrable. It is usually made from a combination of two or more types of glass, one hard and one soft. [1] The softer layer makes the glass more elastic, so that it can flex instead of shatter. The index of refraction for all of the glasses used in the bulletproof layers must be almost the same to keep the glass transparent and allow a clear, undistorted view through the glass. Bulletproof glass varies in thickness from 34 to 3+12 inches (19 to 89 mm). [2] [3]

Contents

Bulletproof glass is used in windows of buildings that require such security, such as jewelry stores and embassies, and of military and private vehicles.

Construction

A rough visualisation of bulletproof glass, composed of layers of plastic sheeting (grey) and layers of glass (blue) Bulletproof glass visualisation.png
A rough visualisation of bulletproof glass, composed of layers of plastic sheeting (grey) and layers of glass (blue)

Bullet-resistant glass is constructed using layers of laminated glass. The more layers there are, the more protection the glass offers. When a weight reduction is needed, polycarbonate (a thermoplastic) is laminated onto the safe side to stop spall. The aim is to make a material with the appearance and clarity of standard glass but with effective protection from small arms. Polycarbonate designs usually consist of products such as Armormax, Makroclear, Cyrolon: a soft coating that heals after being scratched (such as elastomeric carbon-based polymers) or a hard coating that prevents scratching (such as silicon-based polymers). [4]

The plastic in laminate designs also provides resistance to impact from physical assault from blunt and sharp objects. The plastic provides little in the way of bullet-resistance. The glass, which is much harder than plastic, flattens the bullet, and the plastic deforms, with the aim of absorbing the rest of the energy and preventing penetration. The ability of the polycarbonate layer to stop projectiles with varying energy is directly proportional to its thickness, [5] and bulletproof glass of this design may be up to 3.5 inches thick. [3]

Laminated glass layers are built from glass sheets bonded together with polyvinyl butyral, polyurethane, Sentryglas, or ethylene-vinyl acetate. When treated with chemical processes, the glass becomes much stronger. This design has been in regular use on combat vehicles since World War II. It is typically thick and is usually extremely heavy. [6]

Sample thickness and weight for bullet-resistant glass materials [7] [8] [9]
Threat StoppedGlass LaminatePolycarbonateAcrylicGlass-Clad Polycarbonate Aluminum oxynitride
Protection Level(example)ThicknessWeightThicknessWeightThicknessWeightThicknessWeightThicknessWeight
in.mmlb/sq. ft.kg/m2in.mmlb/sq. ft.kg/m2in.mmlb/sq. ft.kg/m2in.mmlb/sq. ft.kg/m2in.mmlb/sq. ft.kg/m2
UL 752 Level 1 9 mm 3 shots1.18530.0915.2574.460.7519.054.622.461.2531.757.737.60.81820.788.9943.9
UL 752 Level 2 .357 Magnum 3 shots1.435.5617.9487.61.0326.166.431.251.37534.928.541.501.07527.311.6857.02
UL 752 Level 3 (approximately NIJ IIIA [10] ) .44 Magnum 3 shots (5 shots for NIJ IIIa)1.5940.3820.94102.241.2531.757.737.61.28832.7114.2369.47
UL 752 Level 4 .30-06 1 shot1.33835.2514.4369.47
UL 752 Level 5 7.62 mm 1 shot
UL 752 Level 6 .357 Magnum underloaded 5 shots
UL 752 Level 7 5.56x45 5 shots
UL 752 Level 8 (approximately NIJ III) 7.62 mm NATO 5 shots2.37460.326.01126.9918.25
UL 752 Level 9 .30-06 M2 AP 1 shot
UL 752 Level 10 .50 BMG 1 shot1.640.630.76150.1

9mm 124gr @ 1175-1293fps (1400-1530fps for Level 6), 357M 158gr @ 1250-1375fps, 44M 240gr @ 1350-1485fps, 30-06 180gr @ 2540-2794fps, 5.56NATO 55gr @ 3080-3388fps, 7.62NATO 150gr @ 2750-3025fps. For all ratings in the above chart; all copper-jacketed lead FMJ, except 44 mg is lead semi-wadcutter gas-check, and 30-06 is LEAD core soft point.

Test standards

Ballistic test of a bullet-resistant glass panel IDET2007 bulletproof glass armor.jpg
Ballistic test of a bullet-resistant glass panel

Bullet-resistant materials are tested using a gun to fire a projectile from a set distance into the material, in a specific pattern. Levels of protection are based on the ability of the target to stop a specific type of projectile traveling at a specific speed. Experiments suggest that polycarbonate fails at lower velocities with regular shaped projectiles compared to irregular ones (like fragments), meaning that testing with regular shaped projectiles gives a conservative estimate of its resistance. [11] When projectiles do not penetrate, the depth of the dent left by the impact can be measured and related to the projectile’s velocity and thickness of the material. [5] Some researchers have developed mathematical models based on results of this kind of testing to help them design bulletproof glass to resist specific anticipated threats. [12]

Environmental effects

The properties of bullet-resistant glass can be affected by temperature and by exposure to solvents or UV radiation, usually from sunlight. If the polycarbonate layer is below a glass layer, it has some protection from UV radiation due to the glass and bonding layer. Over time the polycarbonate becomes more brittle because it is an amorphous polymer (which is necessary for it to be transparent) that moves toward thermodynamic equilibrium. [4]

An impact on polycarbonate by a projectile at temperatures below −7 °C sometimes creates spall, pieces of polycarbonate that are broken off and become projectiles themselves. Experiments have demonstrated that the size of the spall is related to the thickness of the laminate rather than the size of the projectile. The spall starts in surface flaws caused by bending of the inner, polycarbonate layer and the cracks move “backwards” through to the impact surface. It has been suggested that a second inner layer of polycarbonate may effectively resist penetration by the spall. [4]

2000s advances

In 2005, it was reported that U.S. military researchers were developing a class of transparent armor incorporating aluminum oxynitride (ALON) as the outside "strike plate" layer. Traditional glass/polymer was demonstrated by ALON's manufacturer to require 2.3 times more thickness than ALON's, to guard against a .50 BMG projectile. [13] ALON is much lighter and performs much better than traditional glass/polymer laminates. Aluminum oxynitride "glass" can defeat threats like the .50 caliber armor-piercing rounds using material that is not prohibitively heavy. [14] [15]

Spinel ceramics

Certain types of ceramics can also be used for transparent armor due to their properties of increased density and hardness when compared to traditional glass. These types of synthetic ceramic transparent armors can allow for thinner armor with equivalent stopping power to traditional laminated glass. [16]

See also

Related Research Articles

<span class="mw-page-title-main">Composite armour</span> Type of vehicle armour

Composite armour is a type of vehicle armour consisting of layers of different materials such as metals, plastics, ceramics or air. Most composite armours are lighter than their all-metal equivalent, but instead occupy a larger volume for the same resistance to penetration. It is possible to design composite armour stronger, lighter and less voluminous than traditional armour, but the cost is often prohibitively high, restricting its use to especially vulnerable parts of a vehicle. Its primary purpose is to help defeat high-explosive anti-tank (HEAT) projectiles.

<span class="mw-page-title-main">Bulletproof vest</span> Form of body armour that protects the torso from some projectiles

A bulletproof vest, also known as a ballistic vest or bullet-resistant vest, is a type of body armour designed to absorb impact and prevent the penetration of firearm projectiles and explosion fragments to the torso. The vest can be either soft—as worn by police officers, security personnel, prison guards, and occasionally private citizens to protect against stabbing attacks or light projectiles—or hard, incorporating metallic or para-aramid components. Soldiers and police tactical units typically wear hard armour, either alone or combined with soft armour, to protect against rifle ammunition or fragmentation. Additional protection includes trauma plates for blunt force and ceramic inserts for high-caliber rounds. Bulletproof vests have evolved over centuries, from early designs like those made for knights and military leaders to modern-day versions. Early ballistic protection used materials like cotton and silk, while contemporary vests employ advanced fibers and ceramic plates. Ongoing research focuses on improving materials and effectiveness against emerging threats.

<span class="mw-page-title-main">Terminal ballistics</span> Projectiles behavior after reaching their targets

Terminal ballistics is a sub-field of ballistics concerned with the behavior and effects of a projectile when it hits and transfers its energy to a target.

<span class="mw-page-title-main">Chobham armour</span> British-designed composite tank armour

Chobham armour is the informal name of a composite armour developed in the 1960s at the Military Vehicles and Engineering Establishment, a British tank research centre on Chobham Lane in Chertsey. The name has since become the common generic term for composite ceramic vehicle armour. Other names informally given to Chobham armour include Burlington and Dorchester. Special armour is a broader informal term referring to any armour arrangement comprising sandwich reactive plates, including Chobham armour.

<span class="mw-page-title-main">Armour-piercing discarding sabot</span> Anti-tank projectile

Armor-piercing discarding sabot (APDS) is a type of spin-stabilized kinetic energy projectile for anti-armor warfare. Each projectile consists of a sub-caliber round fitted with a sabot. The combination of a lighter sub-caliber projectile with a full-caliber propellant charge allows for an increase in muzzle velocity compared to full-caliber rounds, giving the round increased armor-penetration performance. To further enhance their armor-penetration capabilities, APDS rounds typically feature a hardened core made from tungsten or another hard, dense material.

<span class="mw-page-title-main">Flak jacket</span> Jacket or vest that protects against shell fragments

A flak jacket or flak vest is a form of body armor. A flak jacket is designed to provide protection from case fragments ("frag") from high explosive weaponry, such as anti-aircraft artillery, grenade fragments, very small pellets used in shotguns such as the "Birdshot", and other lower-velocity projectiles. It is not designed to protect against bullets fired from most small arms such as rifles or handguns. However flak jackets are able to sustain certain gunshots, depending on the angle at which the shot was fired, the caliber of the bullet, the speed of the projectile and the range from which the shot was fired.

<span class="mw-page-title-main">Vehicle armour</span> High-strength plating used to fortify important vehicles against bullets, shells etc.

Military vehicles are commonly armoured to withstand the impact of shrapnel, bullets, shells, rockets, and missiles, protecting the personnel inside from enemy fire. Such vehicles include armoured fighting vehicles like tanks, aircraft, and ships.

<span class="mw-page-title-main">Body armor</span> Protective clothing; armor worn on the body

Body armor, personal armor, armored suit (armoured) or coat of armor, among others, is armor for a person's body: protective clothing or close-fitting hands-free shields designed to absorb or deflect physical attacks. Historically used to protect military personnel, today it is also used by various types of police, private security guards, or bodyguards, and occasionally ordinary citizens. Today there are two main types: regular non-plated body armor for moderate to substantial protection, and hard-plate reinforced body armor for maximum protection, such as used by combatants.

<span class="mw-page-title-main">Bulletproofing</span> Provision for resisting fired bullets

Bulletproofing is the process of making an object capable of stopping a bullet or similar high velocity projectiles. The term bullet resistance is often preferred because few, if any, practical materials provide complete protection against all types of bullets, or multiple hits in the same location, or simply sufficient kinetic (movement) energy to overcome it.

<span class="mw-page-title-main">Gold Flex</span>

Gold Flex is a non-woven fabric manufactured by Honeywell from Kevlar, and is often used in ballistic vests and body armor. Gold Flex is lighter than woven Kevlar, Twaron and other Ballistic material. Gold Flex is a laminated material consisting of cross-laid, non-woven fibers in a resin matrix. The fibers are laid straight and not in a woven fabric configuration. When an object strikes this material, a "web" of its clusters absorb the impact and minimizes penetration.

<span class="mw-page-title-main">Ballistic plate</span> Protective armoured plate

A ballistic plate, also known as an armour plate, is a protective armoured plate inserted into a carrier or bulletproof vest, that can be used stand-alone, or in conjunction with other armour. "Hard armour" usually denotes armour that uses ballistic plates.

<span class="mw-page-title-main">Aluminium oxynitride</span> Transparent ceramic material

Aluminium oxynitride is a transparent ceramic composed of aluminium, oxygen and nitrogen. Aluminium oxynitride is optically transparent (≥ 80%) in the near-ultraviolet, visible, and mid-wave-infrared regions of the electromagnetic spectrum. It is four times as hard as fused silica glass, 85% as hard as sapphire, and nearly 115% as hard as magnesium aluminate spinel. It can be fabricated into transparent windows, plates, domes, rods, tubes, and other forms using conventional ceramic powder processing techniques.

<span class="mw-page-title-main">Laminated glass</span> Type of safety glass with a thin polymer interlayer that holds together when shattered

Laminated glass is a type of safety glass consisting of two or more layers of glass with one or more thin polymer interlayers between them which prevent the glass from breaking into large sharp pieces. Breaking produces a characteristic "spider web" cracking pattern when the impact is not enough to completely pierce the glass.

<span class="mw-page-title-main">Ballistic shield</span> Police and military anti-projectile shields

A ballistic shield, also called a tactical shield or bulletproof shield, is a protection device deployed by police, paramilitaries, and armed forces that are designed to stop or deflect bullets and other projectiles fired at their carrier. Ballistic shields also protect from less serious threats such as thrown items. Ballistic shields are similar to riot shields, but offer greater protection and are typically used by special units or in situations where riot shields would not offer adequate protection.

<span class="mw-page-title-main">Improved Outer Tactical Vest</span> US Army body armor

The Improved Outer Tactical Vest (IOTV) is an enhanced version of, and a replacement for, the older Outer Tactical Vest (OTV) component of the Interceptor multi-threat body armor system, as fielded by the United States Army beginning in the mid-2000s. The IOTV is compatible with the Deltoid and Axillary Protector System (DAPS) components, ESAPI, Enhanced Side Ballistic Inserts (ESBI), as well as the OTV's groin protector. A flame-resistant standalone shirt, the Army Combat Shirt (ACS), was designed in the late 2000s specifically for use with the IOTV.

Ceramic armor is armor used by armored vehicles and in personal armor to resist projectile penetration through its high hardness and compressive strength. In its most basic form, it consists of two primary components: A ceramic layer on the outer surface, called the "strike face," backed up by a ductile fiber reinforced plastic composite or metal layer. The role of the ceramic is to (1) fracture the projectile or deform the projectile nose upon impact, (2) erode and slow down the projectile remnant as it penetrates the shattered ceramic layer, and (3) distribute the impact load over a larger area, which can be absorbed by ductile polymer or metallic backings. Ceramics are often used where light weight is important, as they weigh less than metal alloys for a given degree of resistance. The most common materials are alumina, boron carbide, and, to a lesser extent, silicon carbide.

<span class="mw-page-title-main">Twinwall plastic</span>

Twin-wall plastic, specifically twin-wall polycarbonate, is an extruded multi-wall polymer product created for applications where its strength, thermally insulative properties, and moderate cost are ideal. Polycarbonate, which is most commonly formed through the reaction of Bisphenol A and Carbonyl Chloride, is an extremely versatile material. It is significantly lighter than glass, while managing to be stronger, more flexible, and more impact resistant. Twin-wall polycarbonate is used most commonly for green houses, where it can support itself in a structurally sound configuration, limit the amount of UV light due to its nominal translucence, and can withstand the rigors of daily abuse in an outdoor environment. The stagnant air in the cellular space between sheets provides insulation, and additional cell layers can be extruded to enhance insulative properties at the cost of light transmission.

Ballistic eyewear is a form of glasses or goggles that protect from small projectiles and fragments. For the U.S. military, choices are listed on the Authorized Protective Eyewear List (APEL). Ballistic eyewear including examples that meet APEL requirements are commercially available for anyone who wishes to buy it. The history of protective eyewear goes back to 1880 and extends through to World War I and the present. There are three standards that are currently used to test the effectiveness of ballistic eyewear. These include a U.S. civilian standard, a U.S. military standard (MIL-PRF-31013), and a European standard.

The polyurethane urea elastomer (PUU), or poly elastomer, is a flexible polymeric material that is composed of linkages made out of polyurethane and polyurea compounds. Due to its hyperelastic properties, it is capable of bouncing back high-speed ballistic projectiles as if the material had “hardened” upon impact. PUUs were developed by researchers from the U.S. Army Research Laboratory (ARL) and the Army’s Institute for Soldier Nanotechnology at the Massachusetts Institute of Technology (MIT) to potentially replace polyethylene materials in body armor and other protective gear, such as combat helmets, face shields, and ballistic vests.

References

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  7. Company specifications from Total Security Solutions and/or Pacific Bulletproof. Retrieved May 9, 2011
  8. Nationwide Structures Inc. "Ballistic Charts". Nationwidestructures.com. Retrieved 2014-08-04.
  9. "Surmet's ALON® Transparent Armor 50 Caliber Test". YouTube. 2011-03-14. Retrieved 2014-08-04.
  10. UL 752 Level 3 Bullet Resistant Fiberglass click on the lower chart
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  12. Cros PE, Rota L, Contento CE, Schirer R, Fond C. Experimental and numerical analysis of the impact behavior of polycarbonate and polyurethane liner Phys IV, France 10:Pr9-671 – Pr9-676, 2000.
  13. Surmet's ALON® Transparent Armor 50 Caliber Test
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  15. "Sapphire gem based transparent armor protects soldiers from snipers". Fox News. October 18, 2018. Retrieved February 16, 2021.
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