Cantilever enhanced photoacoustic spectroscopy

Last updated

Cantilever enhanced photoacoustic spectroscopy enables the detection of small amount of trace gases which is vital in many applications. Photoacoustic spectroscopy is one of the most sensitive optical detection schemes. It is based on detecting a gas specific acoustic wave generated that originates from the absorption of light in the medium. The sensitivity of the traditional membrane microphones is limited by electrical noise and the nonlinearity of the displacement of the mechanical sensor at high optical power levels. Conventional membrane microphones can be replaced with optically measured micromechanical cantilevers to enhance sensitivity.

Contents

Characteristics

The novel MEMS cantilever approach detects pressure changes in a photoacoustic cell. [1] High sensitivity is achieved by using a cantilever pressure sensor that is over hundred times more sensitive compared to a membrane, which is conventionally used in photoacoustic spectroscopy. A laser-based readout interferometer is able to accurately measure displacement from well under a picometer up to millimeters. [2]

Technology

An extremely thin cantilever portion moves like a flexible door due to the pressure variations in the surrounding gas. The displacement of the cantilever is measured with an accurate interferometric readout system. This way the "breathing effect" can be avoided. The so-called breathing effect occurs in capacitive measurement principle where the other electrode damps the movement of the sensor and restricts the dynamic range.

Cantilever sensor

The cantilever sensor is made out of single crystal SOI-silicon with a specially developed dry-etching process that leads to a highly stable and robust component; this is why the sensor is practically totally immune to temperature and humidity variations. In addition, the sensor does not suffer from wearing. The sensor and readout can be isolated in terms of temperature allowing heated gas cell which enables applications that require gas analysis at elevated temperatures such as chemical emissions monitoring and process control. [2]

Applications

Cantilever enhanced photoacoustics measuring technology can be used e.g. in detection and analysis of gases, liquids, and solid materials in applications of research, industry, environmental, safety, and security. [3]

Related Research Articles

Pressure measurement Analysis of force applied by a fluid on a surface

Pressure measurement is the analysis of an applied force by a fluid on a surface. Pressure is typically measured in units of force per unit of surface area. Many techniques have been developed for the measurement of pressure and vacuum. Instruments used to measure and display pressure in an integral unit are called pressure meters or pressure gauges or vacuum gauges. A manometer is a good example, as it uses the surface area and weight of a column of liquid to both measure and indicate pressure. Likewise the widely used Bourdon gauge is a mechanical device, which both measures and indicates and is probably the best known type of gauge.

Magnetometer Device that measures magnetism

A magnetometer is a device that measures magnetic field or magnetic dipole moment. Some magnetometers measure the direction, strength, or relative change of a magnetic field at a particular location. A compass is one such device, one that measures the direction of an ambient magnetic field, in this case, the Earth's magnetic field. Other magnetometers measure the magnetic dipole moment of a magnetic material such as a ferromagnet, for example by recording the effect of this magnetic dipole on the induced current in a coil.

Sensor converter that measures a physical quantity and converts it into a signal

In the broadest definition, a sensor is a device, module, machine, or subsystem whose purpose is to detect events or changes in its environment and send the information to other electronics, frequently a computer processor. A sensor is always used with other electronics.

Tunable diode laser absorption spectroscopy is a technique for measuring the concentration of certain species such as methane, water vapor and many more, in a gaseous mixture using tunable diode lasers and laser absorption spectrometry. The advantage of TDLAS over other techniques for concentration measurement is its ability to achieve very low detection limits. Apart from concentration, it is also possible to determine the temperature, pressure, velocity and mass flux of the gas under observation. TDLAS is by far the most common laser based absorption technique for quantitative assessments of species in gas phase.

Nanosensors are nanoscale devices that measure physical quantities and convert these to signals that can be detected and analyzed. There are several ways proposed today to make nanosensors; these include top-down lithography, bottom-up assembly, and molecular self-assembly. There are different types of nanosensors in the market and in development for various applications, most notably in defense, environmental, and healthcare industries. These sensors share the same basic workflow: a selective binding of an analyte, signal generation from the interaction of the nanosensor with the bio-element, and processing of the signal into useful metrics.

Photoacoustic spectroscopy is the measurement of the effect of absorbed electromagnetic energy on matter by means of acoustic detection. The discovery of the photoacoustic effect dates to 1880 when Alexander Graham Bell showed that thin discs emitted sound when exposed to a beam of sunlight that was rapidly interrupted with a rotating slotted disk. The absorbed energy from the light causes local heating, generating a thermal expansion which creates a pressure wave or sound. Later Bell showed that materials exposed to the non-visible portions of the solar spectrum can also produce sounds.

A carbon dioxide sensor or CO2 sensor is an instrument for the measurement of carbon dioxide gas. The most common principles for CO2 sensors are infrared gas sensors (NDIR) and chemical gas sensors. Measuring carbon dioxide is important in monitoring indoor air quality, the function of the lungs in the form of a capnograph device, and many industrial processes.

Nondispersive infrared sensor

A nondispersive infrared sensor is a simple spectroscopic sensor often used as a gas detector. It is non-dispersive in the fact that no dispersive element is used to separate out the broadband light into a narrow spectrum suitable for gas sensing. The majority of NDIR sensors use a broadband lamp source and an optical filter to select a narrow band spectral region that overlaps with the absorption region of the gas of interest. In this context narrow may be 50-300nm bandwidth. Modern NDIR sensors may use Microelectromechanical systems (MEMs) or mid IR LED sources, with or without an optical filter.

A hydrogen sensor is a gas detector that detects the presence of hydrogen. They contain micro-fabricated point-contact hydrogen sensors and are used to locate hydrogen leaks. They are considered low-cost, compact, durable, and easy to maintain as compared to conventional gas detecting instruments.

Moisture analysis covers a variety of methods for measuring moisture content in both high level and trace amounts in solids, liquids, or gases. Moisture in percentage amounts is monitored as a specification in commercial food production. There are many applications where trace moisture measurements are necessary for manufacturing and process quality assurance. Trace moisture in solids must be controlled for plastics, pharmaceuticals and heat treatment processes. Gas or liquid measurement applications include dry air, hydrocarbon processing, pure semiconductor gases, bulk pure gases, dielectric gases such as those in transformers and power plants, and natural gas pipeline transport.

Photothermal spectroscopy is a group of high sensitivity spectroscopy techniques used to measure optical absorption and thermal characteristics of a sample. The basis of photothermal spectroscopy is the change in thermal state of the sample resulting from the absorption of radiation. Light absorbed and not lost by emission results in heating. The heat raises temperature thereby influencing the thermodynamic properties of the sample or of a suitable material adjacent to it. Measurement of the temperature, pressure, or density changes that occur due to optical absorption are ultimately the basis for the photothermal spectroscopic measurements.

Laser absorption spectrometry (LAS) refers to techniques that use lasers to assess the concentration or amount of a species in gas phase by absorption spectrometry (AS).

Noise-immune cavity-enhanced optical-heterodyne molecular spectroscopy (NICE-OHMS) is an ultra-sensitive laser-based absorption technique that utilizes laser light to assess the concentration or the amount of a species in gas phase by absorption spectrometry (AS).

A fiber-optic sensor is a sensor that uses optical fiber either as the sensing element, or as a means of relaying signals from a remote sensor to the electronics that process the signals. Fibers have many uses in remote sensing. Depending on the application, fiber may be used because of its small size, or because no electrical power is needed at the remote location, or because many sensors can be multiplexed along the length of a fiber by using light wavelength shift for each sensor, or by sensing the time delay as light passes along the fiber through each sensor. Time delay can be determined using a device such as an optical time-domain reflectometer and wavelength shift can be calculated using an instrument implementing optical frequency domain reflectometry.

Pipeline leak detection is used to determine if and in some cases where a leak has occurred in systems which contain liquids and gases. Methods of detection include hydrostatic testing, infrared, and laser technology after pipeline erection and leak detection during service.

MEMS magnetic field sensor

A MEMSmagnetic field sensor is a small-scale microelectromechanical systems (MEMS) device for detecting and measuring magnetic fields (Magnetometer). Many of these operate by detecting effects of the Lorentz force: a change in voltage or resonant frequency may be measured electronically, or a mechanical displacement may be measured optically. Compensation for temperature effects is necessary. Its use as a miniaturized compass may be one such simple example application.

The photoacoustic effect or optoacoustic effect is the formation of sound waves following light absorption in a material sample. In order to obtain this effect the light intensity must vary, either periodically or as a single flash. The photoacoustic effect is quantified by measuring the formed sound with appropriate detectors, such as microphones or piezoelectric sensors. The time variation of the electric output from these detectors is the photoacoustic signal. These measurements are useful to determine certain properties of the studied sample. For example, in photoacoustic spectroscopy, the photoacoustic signal is used to obtain the actual absorption of light in either opaque or transparent objects. It is useful for substances in extremely low concentrations, because very strong pulses of light from a laser can be used to increase sensitivity and very narrow wavelengths can be used for specificity. Furthermore, photoacoustic measurements serve as a valuable research tool in the study of the heat evolved in photochemical reactions, particularly in the study of photosynthesis.

Incoherent broad band cavity enhanced absorption spectroscopy (IBBCEAS), sometimes called broadband cavity enhanced extinction spectroscopy (IBBCEES), measures the transmission of light intensity through a stable optical cavity consisting of high reflectance mirrors. The technique is realized using incoherent sources of radiation e.g. Xenon arc lamps, LEDs or supercontinuum (SC) lasers, hence the name.

Gas blending is the process of mixing gases for a specific purpose where the composition of the resulting mixture is specified and controlled. A wide range of applications include scientific and industrial processes, food production and storage and breathing gases.

Gasera

Gasera Ltd. is a Finnish high-tech company focused on the analysis of gases, liquids and solid materials. The main focus of Gasera is measuring harmful air pollutants in order to protect humans and the environment. Other applications include e.g. greenhouse gas monitoring, automotive and ship emissions monitoring, dissolved gas analysis in transformer oil, CWA and TIC detection, material identification and food production and safety.

References

  1. Kauppinen, Jyrki; Wilcken, Klaus; Kauppinen, Ismo; Koskinen, Vesa (2004). "High sensitivity in gas analysis with photoacoustic detection". Microchemical Journal. 76 (1–2): 151–159. doi:10.1016/j.microc.2003.11.007.
  2. 1 2 "Optical microphone for photoacoustic gas detection". Gasera. Retrieved 2016-06-22.
  3. "Photoacoustic spectroscopy - Gasera". Gasera. Retrieved 2016-06-22.