Cavitation (elastomers)

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Cavitation is the unstable unhindered expansion of a microscopic void in a solid elastomer under the action of tensile hydrostatic stresses. This can occur whenever the hydrostatic tension exceeds 5/6 of Young's modulus. [1]

The cavitation phenomenon may manifest in any of the following situations:

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Spall Material fragments removed from a surface weakened by an impact, corrosion, or weathering

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Hydrostatic test Non-destructive test of pressure vessels

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Embrittlement

Embrittlement is a significant decrease of ductility of a material, which makes the material brittle. Embrittlement is used to describe any phenomena where the environment compromises a stressed material's mechanical performance, such as temperature or environmental composition. This is oftentimes undesirable as brittle fracture occurs quicker and can much more easily propagate than ductile fracture, leading to complete failure of the equipment. Various materials have different mechanisms of embrittlement, therefore it can manifest in a variety of ways, from slow crack growth to a reduction of tensile ductility and toughness.

Rubber toughening is a process in which rubber nanoparticles are interspersed within a polymer matrix to increase the mechanical robustness, or toughness, of the material. By "toughening" a polymer it is meant that the ability of the polymeric substance to absorb energy and plastically deform without fracture is increased. Considering the significant advantages in mechanical properties that rubber toughening offers, most major thermoplastics are available in rubber-toughened versions; for many engineering applications, material toughness is a deciding factor in final material selection.

Cavitation is the formation of vapour cavities in a liquid.

Crystallization of polymers is a process associated with partial alignment of their molecular chains. These chains fold together and form ordered regions called lamellae, which compose larger spheroidal structures named spherulites. Polymers can crystallize upon cooling from melting, mechanical stretching or solvent evaporation. Crystallization affects optical, mechanical, thermal and chemical properties of the polymer. The degree of crystallinity is estimated by different analytical methods and it typically ranges between 10 and 80%, with crystallized polymers often called "semi-crystalline". The properties of semi-crystalline polymers are determined not only by the degree of crystallinity, but also by the size and orientation of the molecular chains.

Alan Neville Gent was an English scientist who contributed to understanding adhesion physics, and fracture of rubbery, crystalline and glassy polymers.

References

  1. Gent, Alan N. (1990). "Cavitation in Rubber: A Cautionary Tale". Rubber Chemistry and Technology. 63 (3): 49–53. doi:10.5254/1.3538266.