Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement that hardens (cures) over time. Concrete is the third-most-used substance in the world after water, and is the most widely used building material. Its usage worldwide, ton for ton, is twice that of steel, wood, plastics, and aluminium combined. Globally, the ready-mix concrete industry, the largest segment of the concrete market, is projected to exceed $600 billion in revenue by 2025. This widespread use results in a number of environmental impacts. Most notably, the production process for cement produces large volumes of greenhouse gas emissions, leading to net 8% of global emissions. Other environmental concerns include widespread illegal sand mining, impacts on the surrounding environment such as increased surface runoff or urban heat island effect, and potential public health implications from toxic ingredients. Significant research and development is being done to try to reduce the emissions or make concrete a source of carbon sequestration, and increase recycled and secondary raw materials content into the mix to achieve a circular economy. Concrete is expected to be a key material for structures resilient to climate disasters, as well as a solution to mitigate the pollution of other industries, capturing wastes such as coal fly ash or bauxite tailings and residue.
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel (aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource.
Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th century by Joseph Aspdin, and is usually made from limestone. It is a fine powder, produced by heating limestone and clay minerals in a kiln to form clinker, grinding the clinker, and adding 2 to 3 percent of gypsum. Several types of Portland cement are available. The most common, called ordinary Portland cement (OPC), is grey, but white Portland cement is also available. Its name is derived from its resemblance to Portland stone which was quarried on the Isle of Portland in Dorset, England. It was named by Joseph Aspdin who obtained a patent for it in 1824. His son William Aspdin is regarded as the inventor of "modern" Portland cement due to his developments in the 1840s.
Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term "lime" connotes calcium-containing inorganic materials, in which carbonates, oxides and hydroxides of calcium, silicon, magnesium, aluminium, and iron predominate. By contrast, quicklime specifically applies to the single chemical compound calcium oxide. Calcium oxide that survives processing without reacting in building products such as cement is called free lime.
A concrete masonry unit (CMU) is a standard-size rectangular block used in building construction. CMUs are some of the most versatile building products available because of the wide variety of appearances that can be achieved using them.
Fly ash, flue ash, coal ash, or pulverised fuel ash – plurale tantum: coal combustion residuals (CCRs) – is a coal combustion product that is composed of the particulates that are driven out of coal-fired boilers together with the flue gases. Ash that falls to the bottom of the boiler's combustion chamber is called bottom ash. In modern coal-fired power plants, fly ash is generally captured by electrostatic precipitators or other particle filtration equipment before the flue gases reach the chimneys. Together with bottom ash removed from the bottom of the boiler, it is known as coal ash.
A cenosphere is a lightweight, inert, hollow sphere made largely of silica and alumina and filled with air or inert gas, typically produced as a coal combustion byproduct at thermal power plants. The color of cenospheres varies from gray to almost white and their density is about 0.4–0.8 g/cm3 (0.014–0.029 lb/cu in), which gives them a great buoyancy.
Silica fume, also known as microsilica, is an amorphous (non-crystalline) polymorph of silicon dioxide, silica. It is an ultrafine powder collected as a by-product of the silicon and ferrosilicon alloy production and consists of spherical particles with an average particle diameter of 150 nm. The main field of application is as pozzolanic material for high performance concrete.
Concrete recycling is the use of rubble from demolished concrete structures. Recycling is cheaper and more ecological than trucking rubble to a landfill. Crushed rubble can be used for road gravel, revetments, retaining walls, landscaping gravel, or raw material for new concrete. Large pieces can be used as bricks or slabs, or incorporated with new concrete into structures, a material called urbanite.
Pozzolans are a broad class of siliceous and aluminous materials which, in themselves, possess little or no cementitious value but which will, in finely divided form and in the presence of water, react chemically with calcium hydroxide (Ca(OH)2) at ordinary temperature to form compounds possessing cementitious properties. The quantification of the capacity of a pozzolan to react with calcium hydroxide and water is given by measuring its pozzolanic activity. Pozzolana are naturally occurring pozzolans of volcanic origin.
Cement clinker is a solid material produced in the manufacture of Portland cement as an intermediary product. Clinker occurs as lumps or nodules, usually 3 millimetres (0.12 in) to 25 millimetres (0.98 in) in diameter. It is produced by sintering limestone and aluminosilicate materials such as clay during the cement kiln stage.
Geopolymers are inorganic, typically ceramic, alumino-silicate forming long-range, covalently bonded, non-crystalline (amorphous) networks. Obsidian fragments are a component of some geopolymer blends. Commercially produced geopolymers may be used for fire- and heat-resistant coatings and adhesives, medicinal applications, high-temperature ceramics, new binders for fire-resistant fiber composites, toxic and radioactive waste encapsulation and new cements for concrete. The properties and uses of geopolymers are being explored in many scientific and industrial disciplines: modern inorganic chemistry, physical chemistry, colloid chemistry, mineralogy, geology, and in other types of engineering process technologies. The field of geopolymers is a part of polymer science, chemistry and technology that forms one of the major areas of materials science.
Foam Index test is a rapid method to determine the relative levels of Air Entraining Agent (AEA) needed during concrete mixing, with or without mineral additives like combustion fly ash, that control air void volumes within cured concrete.
Roman concrete, also called opus caementicium, was used in construction in ancient Rome. Like the modern equivalent, Roman concrete was based on a hydraulic-setting cement added to an aggregate.
Concrete is produced in a variety of compositions, finishes and performance characteristics to meet a wide range of needs.
Mulalo Doyoyo is a South African engineer, inventor, and professor.
Geopolymer cement is a binding system that hardens at room temperature.
The environmental impact of concrete, its manufacture, and its applications, are complex, driven in part by direct impacts of construction and infrastructure, as well as by CO2 emissions; between 4-8% of total global CO2 emissions come from concrete. Many depend on circumstances. A major component is cement, which has its own environmental and social impacts and contributes largely to those of concrete.
Energetically modified cements (EMCs) are a class of cements made from pozzolans, silica sand, blast furnace slag, or Portland cement. The term "energetically modified" arises by virtue of the mechanochemistry process applied to the raw material, more accurately classified as "high energy ball milling" (HEBM). This causes, amongst others, a thermodynamic transformation in the material to increase its chemical reactivity. For EMCs, the HEBM process used is a unique form of specialised vibratory milling discovered in Sweden and applied only to cementitious materials, here called "EMC Activation".
Foam concrete, also known as Lightweight Cellular Concrete (LCC), Low Density Cellular Concrete (LDCC), and other terms is defined as a cement-based slurry, with a minimum of 20% foam entrained into the plastic mortar. As mostly no coarse aggregate is used for production of foam concrete the correct term would be called mortar instead of concrete; it may be called "foamed cement" as well. The density of foam concrete usually varies from 400 kg/m3 to 1600 kg/m3. The density is normally controlled by substituting fully or part of the fine aggregate with foam.
