Ceramic membrane

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Ceramic membranes are a type of artificial membranes made from inorganic materials (such as alumina, titania, zirconia oxides, silicon carbide or some glassy materials). They are used in membrane operations for liquid filtration.

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By contrast with polymeric membranes, they can be used in separations where aggressive media (acids, strong solvents) are present. They also have excellent thermal stability which makes them usable in high-temperature membrane operations.

Like polymeric membranes, they are either dense or porous.

Researchers have studied ceramic membranes for potential applications in wastewater treatment, gas separation, and membrane reactors. Ceramic membranes typically last longer than polymeric membranes which are more commonly used for these applications. Currently ceramic membranes have not seen widespread usage mainly due to their high cost of production.

Configurations include tubular cross flow and dead-end membranes as well as flat sheet membranes.

Dense membranes

Dense ceramic membranes are used for the purpose of gas separation. Examples are the separation of oxygen from air, or the separation of hydrogen gas from a mixture. Dense ceramic membranes have been studied for process intensification applications to reduce the energy consumption of many technologies used in the petroleum industry. One such application is membrane reactors, through the use of dense oxygen permeable membranes. [1]

Porous membranes

Porous ceramic membranes are chiefly used for gas separation and micro- or nanofiltration. They can be made from both crystalline as well as amorphous solids.

An example of an amorphous membrane is the silica membrane. [2]

An example of a highly porous membrane is the type made of silicon carbide. [3]

Porous ceramic membranes are typically manufactured through a slip coating-sintering process. In this process a support is initially made by sintering particles of a ceramic material into a mold with a binding agent. The surface of this support is then coated in a solution of finer ceramic particles and a polymeric binder. This coating is then sintered to form a porous layer of the membrane. This process can then be repeated to form new layers that are typically formed with smaller part ceramic particles. This repeated process with increasingly small particles creates an anisotropic membrane. [4]

History & manufacturers of ceramic membranes

The first ceramic membranes were produced in France in the 1980s for the purpose of uranium enrichment in the nuclear industry. After many of the nuclear plants were set up in France other industrial application areas for the ceramic membranes were sought out. At the same time academic research on ceramic membranes was conducted. The leading group was directed by Professor Louis Cot at the National Graduate School of Chemistry in Montpellier. The group growth gave rise to the creation of a laboratory fully dedicated to the membrane materials and processes from 1994 and to the European Membrane Institute of Montpellier in 2000. [5] French manufacturers of ceramic membranes include Orelis Environnement (Alsys group), Pall Exekia and Tami Industries. Other companies outside France include CoorsTek (http://www.coorstek.com), Atech (http://www.atech-innovations.com), Inopor, Jiangsu Jiuwu, Meidensha, MetaWater, Liqtech, and Mantec Technical Ceramics Ltd (http://www.mantectechnicalceramics.com/products-services/porous-ceramics/filtration/star-sep-membranes/elements)

While most of the ceramic membrane manufacturers produce the membranes of carriers and membrane layers of alumina oxide, titanium oxide and zirconia oxide only a few manufacturers work with silicon carbide. Silicon carbide requires higher sintering temperatures (>2000 °C) [6] compared to oxide based membranes (1200-1600 °C). [7] The pioneers in developing and commercializing silicon carbide membranes are the Danish company Liqtech, CeraMem (Alsys group) and American company Kemco Systems.

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<span class="mw-page-title-main">Ceramic</span> Inorganic, nonmetallic solid prepared by the action of heat

A ceramic is any of the various hard, brittle, heat-resistant, and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain, and brick.

Sintering Process of forming and bonding material by heat or pressure

Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing process used with metals, ceramics, plastics, and other materials. The nanoparticles in the sintered material diffuse across the boundaries of the particles, fusing the particles together and creating a solid piece.

<span class="mw-page-title-main">Zirconium dioxide</span> Chemical compound

Zirconium dioxide is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabilized cubic structured zirconia, cubic zirconia, is synthesized in various colours for use as a gemstone and a diamond simulant.

<span class="mw-page-title-main">Refractory</span> Materials resistant to decomposition under high temperatures and pressures

In materials science, a refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase, inorganic, non-metallic, porous, and heterogeneous. They are typically composed of oxides or carbides, nitrides etc. of the following elements: silicon, aluminium, magnesium, calcium, boron, chromium and zirconium.

An artificial membrane, or synthetic membrane, is a synthetically created membrane which is usually intended for separation purposes in laboratory or in industry. Synthetic membranes have been successfully used for small and large-scale industrial processes since the middle of twentieth century. A wide variety of synthetic membranes is known. They can be produced from organic materials such as polymers and liquids, as well as inorganic materials. The most of commercially utilized synthetic membranes in separation industry are made of polymeric structures. They can be classified based on their surface chemistry, bulk structure, morphology, and production method. The chemical and physical properties of synthetic membranes and separated particles as well as a choice of driving force define a particular membrane separation process. The most commonly used driving forces of a membrane process in industry are pressure and concentration gradients. The respective membrane process is therefore known as filtration. Synthetic membranes utilized in a separation process can be of different geometry and of respective flow configuration. They can also be categorized based on their application and separation regime. The best known synthetic membrane separation processes include water purification, reverse osmosis, dehydrogenation of natural gas, removal of cell particles by microfiltration and ultrafiltration, removal of microorganisms from dairy products, and Dialysis.

In materials science, the sol–gel process is a method for producing solid materials from small molecules. The method is used for the fabrication of metal oxides, especially the oxides of silicon (Si) and titanium (Ti). The process involves conversion of monomers into a colloidal solution (sol) that acts as the precursor for an integrated network of either discrete particles or network polymers. Typical precursors are metal alkoxides. Sol-gel process is used to produce ceramic nanoparticles.

<span class="mw-page-title-main">Ceramic engineering</span> Science and technology of creating objects from inorganic, non-metallic materials

Ceramic engineering is the science and technology of creating objects from inorganic, non-metallic materials. This is done either by the action of heat, or at lower temperatures using precipitation reactions from high-purity chemical solutions. The term includes the purification of raw materials, the study and production of the chemical compounds concerned, their formation into components and the study of their structure, composition and properties.

<span class="mw-page-title-main">Nanoporous materials</span>

Nanoporous materials consist of a regular organic or inorganic bulk phase in which a porous structure is present. Nanoporous materials exhibit pore diameters that are most appropriately quantified using units of nanometers. The diameter of pores in nanoporous materials is thus typically 100 nanometers or smaller. Pores may be open or closed, and pore connectivity and void fraction vary considerably, as with other porous materials. Open pores are pores that connect to the surface of the material whereas closed pores are pockets of void space within a bulk material. Open pores are useful for molecular separation techniques, adsorption, and catalysis studies. Closed pores are mainly used in thermal insulators and for structural applications.

<span class="mw-page-title-main">Membrane reactor</span>

A membrane reactor is a physical device that combines a chemical conversion process with a membrane separation process to add reactants or remove products of the reaction.

<span class="mw-page-title-main">Thermal barrier coating</span>

Thermal barrier coatings (TBCs) are advanced materials systems usually applied to metallic surfaces operating at elevated temperatures, such as gas turbine or aero-engine parts, as a form of exhaust heat management. These 100 μm to 2 mm thick coatings of thermally insulating materials serve to insulate components from large and prolonged heat loads and can sustain an appreciable temperature difference between the load-bearing alloys and the coating surface. In doing so, these coatings can allow for higher operating temperatures while limiting the thermal exposure of structural components, extending part life by reducing oxidation and thermal fatigue. In conjunction with active film cooling, TBCs permit working fluid temperatures higher than the melting point of the metal airfoil in some turbine applications. Due to increasing demand for more efficient engines running at higher temperatures with better durability/lifetime and thinner coatings to reduce parasitic mass for rotating/moving components, there is significant motivation to develop new and advanced TBCs. The material requirements of TBCs are similar to those of heat shields, although in the latter application emissivity tends to be of greater importance.

Ceramic foam is a tough foam made from ceramics. Manufacturing techniques include impregnating open-cell polymer foams internally with ceramic slurry and then firing in a kiln, leaving only ceramic material. The foams may consist of several ceramic materials such as aluminium oxide, a common high-temperature ceramic, and gets insulating properties from the many tiny air-filled voids within the material.

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Zirconium diboride (ZrB2) is a highly covalent refractory ceramic material with a hexagonal crystal structure. ZrB2 is an ultra-high temperature ceramic (UHTC) with a melting point of 3246 °C. This along with its relatively low density of ~6.09 g/cm3 (measured density may be higher due to hafnium impurities) and good high temperature strength makes it a candidate for high temperature aerospace applications such as hypersonic flight or rocket propulsion systems. It is an unusual ceramic, having relatively high thermal and electrical conductivities, properties it shares with isostructural titanium diboride and hafnium diboride.

<span class="mw-page-title-main">Solid</span> State of matter

Solid is one of the four fundamental states of matter. The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structural rigidity and resistance to a force applied to the surface. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire available volume like a gas. The atoms in a solid are bound to each other, either in a regular geometric lattice, or irregularly. Solids cannot be compressed with little pressure whereas gases can be compressed with little pressure because the molecules in a gas are loosely packed.

<span class="mw-page-title-main">Bioceramic</span>

Bioceramics and bioglasses are ceramic materials that are biocompatible. Bioceramics are an important subset of biomaterials. Bioceramics range in biocompatibility from the ceramic oxides, which are inert in the body, to the other extreme of resorbable materials, which are eventually replaced by the body after they have assisted repair. Bioceramics are used in many types of medical procedures. Bioceramics are typically used as rigid materials in surgical implants, though some bioceramics are flexible. The ceramic materials used are not the same as porcelain type ceramic materials. Rather, bioceramics are closely related to either the body's own materials or are extremely durable metal oxides.

Porous glass is glass that includes pores, usually in the nanometre- or micrometre-range, commonly prepared by one of the following processes: through metastable phase separation in borosilicate glasses (such as in their system SiO2-B2O3-Na2O), followed by liquid extraction of one of the formed phases; through the sol-gel process; or simply by sintering glass powder.

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Membrane technology encompasses the scientific processes used in the construction and application of membranes. Membranes are used to facilitate the transport or rejection of substances between mediums, and the mechanical separation of gas and liquid streams. In the simplest case, filtration is achieved when the pores of the membrane are smaller than the diameter of the undesired substance, such as a harmful microorganism. Membrane technology is commonly used in industries such as water treatment, chemical and metal processing, pharmaceuticals, biotechnology, the food industry, as well as the removal of environmental pollutants.

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<span class="mw-page-title-main">Polymer derived ceramics</span>

Polymer derived ceramics (PDCs) are ceramic materials formed by the pyrolysis of preceramic polymers, usually under inert atmosphere.

References

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