Cone-in-cone structures are secondary sedimentary structures that form in association with deeper burial and diagenesis. They consist of concentric inter-bedded cones of calcite or more rarely gypsum, siderite or pyrite. [1] [2] [3] [4] Although several mechanisms may be responsible for the formation of cone-in-cone structures, displacive crystal mechanism is preferred. It accounts for the most uniform and consistent explanation of growth and why cone-in-cone can occur with such variable composition.
Cone-in-cone structures are identifiable by their distinctive conical appearance. They are composed of concentric cones nested inside each other. The actual composition of the cones is variable and dependent on the environment in which they were formed, with the majority of the cone-in-cone structures being composed of calcite with thin layers of clay between cones. There are also, more rarely, structures composed of siderite, gypsum, pyrite. Often the cone-in-cone will be found as features of calcite layers within a shale, [5] and rarely within a dedolomite (calcitized dolomite). [6]
Cone-in-cone structures should not be confused with either shatter cones such as are produced by meteorite impacts, or with shear cones like those developed in coals. Both these structures differ from cone-in-cone structures in that they are the product of very high instantaneous stresses. Thus they have a spatial dependence on impact areas for the former and fault zones for the latter, whereas cone-in-cone structures do not. [7]
The formation of cone-in-cone structures has been attributed to:
In all cases the common trend is for crystal formation to begin within partially consolidated sediment. As cone-in-cone formation happens it begins to take up more and more space within the sediment bed which begins to cause pressure. The pressure results in the cone shape, as parts of the structure are under greater or lesser pressures and grow differentially based on these varying pressures. The nature of displacement from crystal growth has led many to believe that most of the actual precipitation occurs very early during shallow burial. Some have concluded that, based upon 18O depleted values from some of the cone-in-cone material that they can form later, perhaps at hundreds of meters of burial depth. [3]
Cone-in-cone structures have been known since the late 1700s, and people have attempted to explain the reasons for their formations. One of the earlier explanations was actually on par with the currently accepted methods for formation as discussed above. Some of the other methods offered for their formation were given by Shaub (1937). [9] It was suggested that the formation of cone-in-cone resulted from volume shrinkage and slow dewatering of highly saturated and loosely packed materials. He suggests that partially developed conical surfaces are also possible as a result of pressure developed from overlying sediments under conditions where a unilateral release of horizontal pressure may become effective. He goes on to suggest that the current explanations of his time are inadequate to cover the structure and its formation. He even suggested that formation due to crystallization was not consistent. [9] This growth due to crystallization is a significant portion of the currently accepted mode of formation.
Limestone is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of CaCO3. Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life.
Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2Si2O5(OH)4) and tiny fragments (silt-sized particles) of other minerals, especially quartz and calcite. Shale is characterized by its tendency to split into thin layers (laminae) less than one centimeter in thickness. This property is called fissility. Shale is the most common sedimentary rock.
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles to settle in place. The particles that form a sedimentary rock are called sediment, and may be composed of geological detritus (minerals) or biological detritus. The geological detritus originated from weathering and erosion of existing rocks, or from the solidification of molten lava blobs erupted by volcanoes. The geological detritus is transported to the place of deposition by water, wind, ice or mass movement, which are called agents of denudation. Biological detritus was formed by bodies and parts of dead aquatic organisms, as well as their fecal mass, suspended in water and slowly piling up on the floor of water bodies. Sedimentation may also occur as dissolved minerals precipitate from water solution.
Diagenesis is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a role as sediments become buried much deeper in the Earth's crust. In the early stages, the transformation of poorly consolidated sediments into sedimentary rock (lithification) is simply accompanied by a reduction in porosity and water expulsion, while their main mineralogical assemblages remain unaltered. As the rock is carried deeper by further deposition above, its organic content is progressively transformed into kerogens and bitumens. The process of diagenesis excludes surface alteration (weathering) and deep metamorphism. There is no sharp boundary between diagenesis and metamorphism, but the latter occurs at higher temperatures and pressures. Hydrothermal solutions, meteoric groundwater, rock porosity, permeability, dissolution/precipitation reactions, and time are all influential factors.
Amphibolite is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flaky) structure. The small flakes of black and white in the rock often give it a salt-and-pepper appearance.
A concretion is a hard, compact mass formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular shapes also occur. The word 'concretion' is derived from the Latin concretio "(act of) compacting, condensing, congealing, uniting", itself from con meaning 'together' and crescere meaning "to grow". Concretions form within layers of sedimentary strata that have already been deposited. They usually form early in the burial history of the sediment, before the rest of the sediment is hardened into rock. This concretionary cement often makes the concretion harder and more resistant to weathering than the host stratum.
Ooids are small, spheroidal, "coated" (layered) sedimentary grains, usually composed of calcium carbonate, but sometimes made up of iron- or phosphate-based minerals. Ooids usually form on the sea floor, most commonly in shallow tropical seas. After being buried under additional sediment, these ooid grains can be cemented together to form a sedimentary rock called an oolite. Oolites usually consist of calcium carbonate; these belong to the limestone rock family. Pisoids are similar to ooids, but are larger than 2 mm in diameter, often considerably larger, as with the pisoids in the hot springs at Carlsbad in the Czech Republic.
Siltstone, also known as aleurolite, is a clastic sedimentary rock that is composed mostly of silt. It is a form of mudrock with a low clay mineral content, which can be distinguished from shale by its lack of fissility.
The matrix or groundmass of a rock is the finer-grained mass of material in which larger grains, crystals, or clasts are embedded.
The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both structures contain the disulfide S22− ion, having a short bonding distance between the sulfur atoms. The structures differ in how these di-anions are arranged around the Fe2+ cations. Marcasite is lighter and more brittle than pyrite. Specimens of marcasite often crumble and break up due to the unstable crystal structure.
Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone, which is composed of calcite or aragonite (different crystal forms of CaCO3), and dolomite rock (also known as dolostone), which is composed of mineral dolomite (CaMg(CO3)2). They are usually classified based on texture and grain size. Importantly, carbonate rocks can exist as metamorphic and igneous rocks, too. When recrystallized carbonate rocks are metamorphosed, marble is created. Rare igneous carbonate rocks even exist as intrusive carbonatites and, even rarer, there exists volcanic carbonate lava.
Zeolite facies describes the mineral assemblage resulting from the pressure and temperature conditions of low-grade metamorphism.
Red beds are sedimentary rocks, typically consisting of sandstone, siltstone, and shale, that are predominantly red in color due to the presence of ferric oxides. Frequently, these red-colored sedimentary strata locally contain thin beds of conglomerate, marl, limestone, or some combination of these sedimentary rocks. The ferric oxides, which are responsible for the red color of red beds, typically occur as a coating on the grains of sediments comprising red beds. Classic examples of red beds are the Permian and Triassic strata of the western United States and the Devonian Old Red Sandstone facies of Europe.
Clastic rocks are composed of fragments, or clasts, of pre-existing minerals and rock. A clast is a fragment of geological detritus, chunks, and smaller grains of rock broken off other rocks by physical weathering. Geologists use the term clastic to refer to sedimentary rocks and particles in sediment transport, whether in suspension or as bed load, and in sediment deposits.
Authigenesis is the process whereby a mineral or sedimentary rock deposit is generated where it is found or observed. Such deposits are described as authigenic. Authigenic sedimentary minerals form during or after sedimentation by precipitation or recrystallization as opposed to detrital minerals, which are weathered by water or wind and transported to the depositional location. Authigenic sediments are the main constituents of deep sea sedimentation, compared to shallow waters or land where detrital sediments are more common.
Neomorphism refers to the wet metamorphic process in which diagenetic alterations systematically transform minerals into either polymorphs or crystalline structures that are structurally identical to the rock(s) from which they developed.
Liesegang rings are colored bands of cement observed in sedimentary rocks that typically cut across bedding. These secondary (diagenetic) sedimentary structures exhibit bands of (authigenic) minerals that are arranged in a regular repeating pattern. Liesegang rings are distinguishable from other sedimentary structures by their concentric or ring-like appearance. The precise mechanism from which Liesegang rings form is not entirely known and is still under research, but there is a precipitation process that is thought to be the catalyst for Liesegang ring formation, referred to as the Ostwald-Liesegang supersaturation-nucleation-depletion cycle. Though Liesegang rings are considered a frequent occurrence in sedimentary rocks, rings composed of iron oxide can also occur in permeable igneous and metamorphic rocks that have been chemically weathered.
Shallow water marine environment refers to the area between the shore and deeper water, such as a reef wall or a shelf break. This environment is characterized by oceanic, geological and biological conditions, as described below. The water in this environment is shallow and clear, allowing the formation of different sedimentary structures, carbonate rocks, coral reefs, and allowing certain organisms to survive and become fossils.
Egg taphonomy is the study of the decomposition and fossilization of eggs. The processes of egg taphonomy begin when the egg either hatches or dies. Eggshell fragments are robust and can often travel great distances before burial. More complete egg specimens gradually begin to fill with sediment, which hardens as minerals precipitate out of water percolating through pores or cracks in the shell. Throughout the fossilization process the calcium carbonate composing the eggshell generally remains unchanged, allowing scientists to study its original structure. However, egg fossils buried under sediments at great depth can be subjected to heat, pressure and chemical processes that can alter the structure of its shell through a process called diagenesis.
Automicrite is autochthonous micrite, that is, a carbonate mud precipitated in situ and made up of fine-grained calcite or aragonite micron-sized crystals. It precipitates on the sea floor or within the sediment as an authigenic mud thanks to physicochemical, microbial, photosynthetic and biochemical processes. It has peculiar fabrics and uniform mineralogical and chemical composition.