Detackifier

Last updated

A detackifier is a process chemical that is used for reducing tackiness of other substances. Spraying paint and paper making are processes where inputs may need to be detackified or "denatured".

Chemical substance matter of constant composition best characterized by the entities (molecules, formula units, atoms) it is composed of

A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., without breaking chemical bonds. Chemical substances can be simple substances, chemical compounds, or alloys. Chemical elements may or may not be included in the definition, depending on expert viewpoint.

Denaturation (biochemistry) Chemical process by which proteins lose their three-dimensional structure.

Denaturation is a process in which proteins or nucleic acids lose the quaternary structure, tertiary structure, and secondary structure which is present in their native state, by application of some external stress or compound such as a strong acid or base, a concentrated inorganic salt, an organic solvent, radiation or heat. If proteins in a living cell are denatured, this results in disruption of cell activity and possibly cell death. Protein denaturation is also a consequence of cell death. Denatured proteins can exhibit a wide range of characteristics, from conformational change and loss of solubility to aggregation due to the exposure of hydrophobic groups. Denatured proteins lose their 3D structure and therefore cannot function.

Contents

Spray painting

Spray painting with solvent-based or water-based paint creates paint overspray, a waste material that must be effectively neutralized, or "detackified", and collected for disposal. In order to assist in the removal of the oversprayed paint from the air and to provide efficient operation of the down-draft, water-washed paint spray booths utilize paint detackifying chemical agents. The detackification products are commonly introduced into the water that is recirculated in the paint spray booth system. The first purpose is to render the paint non tacky so it does not stick to the booth equipment and foul the paint system. The second purpose is to efficiently collect the paint solids that were sprayed into the system and remove them from the water for disposal.

Spray painting A painting technique where a device sprays a coating through the air onto a surface

Spray painting is a painting technique where a device sprays a coating through the air onto a surface. The most common types employ compressed gas—usually air—to atomize and direct the paint particles. Spray guns evolved from airbrushes, and the two are usually distinguished by their size and the size of the spray pattern they produce. Airbrushes are hand-held and used instead of a brush for detailed work such as photo retouching, painting nails or fine art. Air gun spraying uses equipment that is generally larger. It is typically used for covering large surfaces with an even coating of liquid. Spray guns can be either automated or hand-held and have interchangeable heads to allow for different spray patterns. Single color aerosol paint cans are portable and easy to store.

Paint spray booths for vehicles are typically 100–300 feet in length and usually contain many robotic and manual spray zones. The temperature and humidity are rigorously controlled in these systems. As items are painted in these booths, a certain amount of paint does not contact the article being painted and forms a fine mist of paint in the air space surrounding the article. This paint must be removed from the air. To accomplish this, the contaminated air is pulled through the paint spray booth by exhaust fans. A curtain of circulating water is maintained across the path of the air in such a way that the air must pass through the water curtain to reach the exhaust fans. As the air passes through the water curtain, the paint mist is “scrubbed” from the air and carried to a sump basin (sludge pit), usually located below the paint spray booth. In this area, the paint particles are separated from the water so that the water may be recycled and the paint particles disposed of as paint sludge. The paint detackifiers commonly added to these systems are either melamine-formaldehyde based, based upon acrylic acid chemistry, or chitosan. [1]

Melamine chemical compound

Melamine is an organic compound with the formula C3H6N6. This white solid is a trimer of cyanamide, with a 1,3,5-triazine skeleton. Like cyanamide, it contains 67% nitrogen by mass, and its derivatives have fire retardant properties due to its release of nitrogen gas when burned or charred. Melamine can be combined with formaldehyde and other agents to produce melamine resins. Such resins are characteristically durable thermosetting plastic used in high pressure decorative laminates such as Formica, melamine dinnerware, laminate flooring, and dry erase boards. Melamine foam is used as insulation, soundproofing material and in polymeric cleaning products, such as Magic Eraser.

Formaldehyde Widely used toxic organic compound

Formaldehyde (systematic name methanal) is a naturally occurring organic compound with the formula CH2O (H−CHO). It is the simplest of the aldehydes (R−CHO). The common name of this substance comes from its similarity and relation to formic acid.

Acrylic acid chemical compound

Acrylic acid (IUPAC: propenoic acid) is an organic compound with the formula CH2=CHCOOH. It is the simplest unsaturated carboxylic acid, consisting of a vinyl group connected directly to a carboxylic acid terminus. This colorless liquid has a characteristic acrid or tart smell. It is miscible with water, alcohols, ethers, and chloroform. More than a million tons are produced annually.

The word detackification in the context of spray painting has come to mean more than mere charge-neutralization. In fact, it now means the entire process, which includes both detackification and flocculation. [2]

Flocculation, in the field of chemistry, is a process in which colloids come out of suspension in the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from precipitation in that, prior to flocculation, colloids are merely suspended in a liquid and not actually dissolved in a solution. In the flocculated system, there is no formation of a cake, since all the flocs are in the suspension.

Paper making

Detackifiers reduce the tackiness of pitch-like materials or stickies so that they have less tendency to form agglomerates or deposit onto papermaking equipment or create spots in the product. Pitch is the common term for hydrophobic wood resin material found in the pulp. Resin is a common organic component of wood found in all trees. In paper making, the most widely used detackifier is talc, anionic dispersants, ethoxylated surfactants, and cellulose based detackifiers. [3] The chemical formula of pure talc is magnesium silicate Mg3Si4O10(OH)2. Talc is a soft mineral with a relatively water-hating surface. These two attributes, softness and hydrophobicity are easy to observe when one pinches some talcum powder and then releases it onto the surface of water in a sink. In addition to talc, there are a number of proprietary chemical products that also are marketed as detackifiers. The common feature of these chemicals is that they are weak polyelectrolytes (sometimes cationic), and they have a tendency to form a film at the surface of tacky or hydrophobic suspended matter.

Pitch is a viscoelastic polymer which can be natural or manufactured, derived from petroleum, coal tar, or plants. Various forms of pitch may also be called tar, bitumen, or asphalt. Pitch produced from plants is also known as resin. Some products made from plant resin are also known as rosin.

Resin solid or highly viscous substance of plant or synthetic origin

In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on naturally-occurring resins.

Talc phyllosilicate mineral

Talc is a clay mineral composed of hydrated magnesium silicate with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often in combination with corn starch, is widely used as baby powder. This mineral is used as a thickening agent and lubricant, is an ingredient in ceramics, paint and roofing material, and is also one of the main ingredients in many cosmetic products. It occurs as foliated to fibrous masses, and in an exceptionally rare crystal form. It has a perfect basal cleavage, uneven flat fracture and it is foliated with a two dimensional platy form.

Some of the key rules of thumb for talc are (a) disperse it well, (b) add it to those process streams that are giving the biggest problems, (c) add it early enough to the process with enough agitation, and (d) add enough. If too little talc is used, the talc is merely incorporated into deposits and agglomerates of tacky materials. It makes sense also to use an effective retention aid program in order to retain the talc (and any attached tacky materials), purging the problem from the wet-end system. Similar considerations apply to the use of organic detackifiers. In either case, the best place to start in dealing with deposit problems is chemical analysis. Several major papermaking research groups have equipment for lab-scale simulation of pitch and stickies problems. [4]

See also

Related Research Articles

Varnish transparent, hard, protective finish or film used in painting

Varnish is a clear transparent hard protective finish or film. Varnish has little or no color and has no added pigment as opposed to paint or wood stain which contains pigment. However, some varnish products are marketed as a combined stain and varnish. Varnish is primarily used in wood finishing applications where the natural tones and grains in the wood are intended to be visible. It is applied over wood stains as a final step to achieve a film for gloss and protection. Varnish finishes are usually glossy but may be designed to produce satin or semi-gloss sheens by the addition of "flatting" agents.

Pulp (paper) fibrous material used notably in papermaking

Pulp is a lignocellulosic fibrous material prepared by chemically or mechanically separating cellulose fibres from wood, fiber crops, waste paper, or rags. Many kinds of paper are made from wood with nothing else mixed into them. This includes newspapers, magazines and even toilet paper. Pulp is one of the most abundant raw materials.

Sizing or size is any one of numerous substances that is applied to, or incorporated into, other materials—especially papers and textiles—to act as a protective filler or glaze. Sizing is used in papermaking and textile manufacturing to change the absorption and wear characteristics of those materials.

Kraft process industrial process to extract pure cellulose from wood pulp

The kraft process (also known as kraft pulping or sulfate process) is a process for conversion of wood into wood pulp, which consists of almost pure cellulose fibers, the main component of paper. The kraft process entails treatment of wood chips with a hot mixture of water, sodium hydroxide (NaOH), and sodium sulfide (Na2S), known as white liquor, that breaks the bonds that link lignin, hemicellulose, and cellulose. The technology entails several steps, both mechanical and chemical. It is the dominant method for producing paper. In some situations, the process has been controversial because kraft plants can release odorous products and in some situations produce substantial liquid wastes.

A binder or binding agent is any material or substance that holds or draws other materials together to form a cohesive whole mechanically, chemically, by adhesion or cohesion.

Pulp mill facility which pulps wood or plant fibre

A pulp mill is a manufacturing facility that converts wood chips or other plant fibre source into a thick fibre board which can be shipped to a paper mill for further processing. Pulp can be manufactured using mechanical, semi-chemical or fully chemical methods. The finished product may be either bleached or non-bleached, depending on the customer requirements.

Natural fiber any fiber derived from natural sources such as plants, animals or minerals

Natural fibers or naturalfibres are fibers that are produced by plants, animals, and geological processes. They can be used as a component of composite materials, where the orientation of fibers impacts the properties. Natural fibers can also be matted into sheets to make paper or felt.

Non-woven fabric is a fabric-like material made from staple fibre (short) and long fibres, bonded together by chemical, mechanical, heat or solvent treatment. The term is used in the textile manufacturing industry to denote fabrics, such as felt, which are neither woven nor knitted. Some non-woven materials lack sufficient strength unless densified or reinforced by a backing. In recent years, non-woven have become an alternative to polyurethane foam.

Thermal spraying materials processing technology

Thermal spraying techniques are coating processes in which melted materials are sprayed onto a surface. The "feedstock" is heated by electrical or chemical means.

Building insulation materials insulation material

Building insulation materials are the building materials, which form the thermal envelope of a building or otherwise reduce heat transfer.

Boiler feedwater

Boiler feedwater is an essential part of boiler operations. The feed water is put into the steam drum from a feed pump. In the steam drum the feed water is then turned into steam from the heat. After the steam is used it is then dumped to the main condenser. From the condenser it is then pumped to the deaerated feed tank. From this tank it then goes back to the steam drum to complete its cycle. The feed water is never open to the atmosphere. This cycle is known as a closed system or Rankine cycle.

Defoamer Chemical additive that reduces and hinders the formation of foam in liquids

A defoamer or an anti-foaming agent is a chemical additive that reduces and hinders the formation of foam in industrial process liquids. The terms anti-foam agent and defoamer are often used interchangeably. Commonly used agents are insoluble oils, polydimethylsiloxanes and other silicones, certain alcohols, stearates and glycols. The additive is used to prevent formation of foam or is added to break a foam already formed.

Deinking is the industrial process of removing printing ink from paperfibers of recycled paper to make deinked pulp.

A fixation agent is a chemical that is capable to fixate one substance to another substance that the first substance have little affinity to.

Hydrophobic silica is a form of silicon dioxide that has hydrophobic groups chemically bonded to the surface. The hydrophobic groups are normally alkyl or polydimethylsiloxane chains. Hydrophobic silica can be processed in different ways; such as fumed silica, precipitated silica, and aerosol assisted self assembly, all existing in the form of nanoparticles.

When recycling post-consumer paper, stickies are tacky substances contained in the paper pulp and process water systems of paper machines. Stickies have the potential to contaminate the components either within or around the equipment necessary in the Stages of Manufacturing that a Paper Mill follows in its Developed Process, but would have otherwise excluded it in its routine cleaning and maintenance procedures. Contaminations of paper that are classified as tacky are also called stickies. The main sources for stickies are recycled paper, waxes, and soft adhesives.

Haden Drysys International played a major part in the development of the paint finishing industry. It was one of the world’s leading high quality paint finishing systems suppliers. Originally based in Birmingham, England the Company moved to then based in Auburn Hills in the United States in the 1990s. As a tier one supplier, it completed projects in over 60 countries. In 2000, the Company reported sales of $300,000,000. It posted its largest ever sales of $573,516,911 in 1995, including a $220,000,000 complete paintshop at Land Rover in Solihull, England. This huge job had great significance to the automotive sector in Britain and this plant still produces the third most vehicles of all plants in the British motor industry.

The surface chemistry of paper is responsible for many important paper properties, such as gloss, waterproofing, and printability. Many components are used in the paper-making process that affect the surface.

Alkenylsuccinic anhydrides chemical compound

Alkenyl succinic anhydrides (ASA) are modified five-membered succinic anhydrides bearing a branched iso-alkenyl chain (C14 to C22). They are colorless, and usually viscous liquids. They are widely used, especially in surface sizing of paper, paperboard, and cardboard, as well as in the hydrophobicization of cellulose fibers. Products treated with it show reduced penetration of aqueous media, such as inks or drinks (like milk or fruit juices).

References

  1. Albu, Mike; Bui,Nang The Use of Chitosan in Paint Detackification accessed 04/12
  2. A Green Detackifier for Paint Sludge accessed 04/2012
  3. Novel Cellulose-based Detackifier for Efficient Pulp Mill Pitch Control; accessed 04/12
  4. Mini-Encyclopedia of Papermaking Wet-End Chemistry accessed 04/2012