Dielectric elastomers (DEs) are smart material systems that produce large strains and are promising for Soft robotics, Artificial muscle, etc. They belong to the group of electroactive polymers (EAP). DE actuators (DEA) transform electric energy into mechanical work and vice versa. Thus, they can be used as both actuators, sensors, and energy-harvesting devices. They have high elastic energy density and fast response due to being lightweight, highly stretchable, and operating under the electrostatic principle. They have been investigated since the late 1990s. Many prototype applications exist. Every year, conferences are held in the US [1] and Europe. [2]
A DEA is a compliant capacitor (see image), where a passive elastomer film is sandwiched between two compliant electrodes. When a voltage is applied, the electrostatic pressure arising from the Coulomb forces acts between the electrodes. The electrodes squeeze the elastomer film. The equivalent electromechanical pressure is twice the electrostatic pressure and is given by:
where is the vacuum permittivity, is the dielectric constant of the polymer and is the thickness of the elastomer film in the current state (during deformation). Usually, strains of DEA are in the order of 10–35%, maximum values reach 300% (the acrylic elastomer VHB 4910, commercially available from 3M, which also supports a high elastic energy density and a high electrical breakdown strength.)
Replacing the electrodes with soft hydrogels allows ionic transport to replace electron transport. Aqueous ionic hydrogels can deliver potentials of multiple kilovolts, despite the onset of electrolysis at below 1.5 V. [3] [4]
The difference between the capacitance of the double layer and the dielectric leads to a potential across the dielectric that can be millions of times greater than that across the double layer. Potentials in the kilovolt range can be realized without electrochemically degrading the hydrogel. [3] [4]
Deformations are well controlled, reversible, and capable of high-frequency operation. The resulting devices can be perfectly transparent. High-frequency actuation is possible. Switching speeds are limited only by mechanical inertia. The hydrogel's stiffness can be thousands of times smaller than the dielectric's, allowing actuation without mechanical constraint across a range of nearly 100% at millisecond speeds. They can be biocompatible. [3] [4]
Remaining issues include drying of the hydrogels, ionic build-up, hysteresis, and electrical shorting. [3] [4]
Early experiments in semiconductor device research relied on ionic conductors to investigate field modulation of contact potentials in silicon and to enable the first solid-state amplifiers. Work since 2000 has established the utility of electrolyte gate electrodes. Ionic gels can also serve as elements of high-performance, stretchable graphene transistors. [4]
Films of carbon powder or grease loaded with carbon black were early choices as electrodes for the DEAs. Such materials have poor reliability and are not available with established manufacturing techniques. Improved characteristics can be achieved with liquid metal, sheets of graphene, coatings of carbon nanotubes, surface-implanted layers of metallic nanoclusters and corrugated or patterned metal films. [4] [5]
These options offer limited mechanical properties, sheet resistances, switching times and easy integration. Silicones and acrylic elastomers are other alternatives.
The requirements for an elastomer material are:
Mechanically prestretching the elastomer film offers the possibility of enhancing the electrical breakdown strength. Further reasons for prestretching include:
The elastomers show a visco-hyperelastic behavior. Models that describe large strains and viscoelasticity are required for the calculation of such actuators.
Materials used in research include graphite powder, silicone oil / graphite mixtures, gold electrodes. The electrode should be conductive and compliant. Compliance is important so that the elastomer is not constrained mechanically when elongated. [4]
Films of polyacrylamide hydrogels formed with salt water can be laminated onto the dielectric surfaces, replacing electrodes. [4]
DEs based on silicone (PDMS) and natural rubber are promising research fields. [6] Properties such as fast response times and efficiency are superior using natural rubber based DEs compared to VHB (acrylic elastomer) based DEs for strains under 15%. [7]
Dielectric elastomer actuators are to be designed so as to avoid the phenomenon of dielectric breakdown in their whole course of motion. In addition to the dielectric breakdown, DEAs are susceptible to another failure mode, referred to as the electromechanical instability, which arises due to nonlinear interaction between the electrostatic and the mechanical restoring forces. In several cases, the electromechanical instability precedes the dielectric breakdown. The instability parameters (critical voltage and the corresponding maximum stretch) are dependent on several factors, such as the level of prestretch, temperature, and the deformation dependent permittivity. Additionally, they also depend on the voltage waveform used to drive the actuator. [8]
Configurations include:
Dielectric elastomers offer multiple potential applications with the potential to replace many electromagnetic actuators, pneumatics and piezo actuators. A list of potential applications include:
In electromagnetism, a dielectric is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the material as they do in an electrical conductor, because they have no loosely bound, or free, electrons that may drift through the material, but instead they shift, only slightly, from their average equilibrium positions, causing dielectric polarisation. Because of dielectric polarisation, positive charges are displaced in the direction of the field and negative charges shift in the direction opposite to the field. This creates an internal electric field that reduces the overall field within the dielectric itself. If a dielectric is composed of weakly bonded molecules, those molecules not only become polarised, but also reorient so that their symmetry axes align to the field.
Capacitance is the capability of a material object or device to store electric charge. It is measured by the charge in response to a difference in electric potential, expressed as the ratio of those quantities. Commonly recognized are two closely related notions of capacitance: self capacitance and mutual capacitance. An object that can be electrically charged exhibits self capacitance, for which the electric potential is measured between the object and ground. Mutual capacitance is measured between two components, and is particularly important in the operation of the capacitor, an elementary linear electronic component designed to add capacitance to an electric circuit.
An actuator is a component of a machine that produces force, torque, or displacement, usually in a controlled way, when an electrical, pneumatic or hydraulic input is supplied to it in a system. An actuator converts such an input signal into the required form of mechanical energy. It is a type of transducer. In simple terms, it is a "mover".
A hydrogel is a biphasic material, a mixture of porous, permeable solids and at least 10% by weight or volume of interstitial fluid composed completely or mainly by water. In hydrogels the porous permeable solid is a water insoluble three dimensional network of natural or synthetic polymers and a fluid, having absorbed a large amount of water or biological fluids. These properties underpin several applications, especially in the biomedical area. Many hydrogels are synthetic, but some are derived from nature. The term 'hydrogel' was coined in 1894.
Smart materials, also called intelligent or responsive materials, are designed materials that have one or more properties that can be significantly changed in a controlled fashion by external stimuli, such as stress, moisture, electric or magnetic fields, light, temperature, pH, or chemical compounds. Smart materials are the basis of many applications, including sensors and actuators, or artificial muscles, particularly as electroactive polymers (EAPs).
Electrorheological (ER) fluids are suspensions of extremely fine non-conducting but electrically active particles in an electrically insulating fluid. The apparent viscosity of these fluids changes reversibly by an order of up to 100,000 in response to an electric field. For example, a typical ER fluid can go from the consistency of a liquid to that of a gel, and back, with response times on the order of milliseconds. The effect is sometimes called the Winslow effect after its discoverer, the American inventor Willis Winslow, who obtained a US patent on the effect in 1947 and wrote an article published in 1949.
An electroactive polymer (EAP) is a polymer that exhibits a change in size or shape when stimulated by an electric field. The most common applications of this type of material are in actuators and sensors. A typical characteristic property of an EAP is that they will undergo a large amount of deformation while sustaining large forces.
Comb-drives are microelectromechanical actuators, often used as linear actuators, which utilize electrostatic forces that act between two electrically conductive combs. Comb drive actuators typically operate at the micro- or nanometer scale and are generally manufactured by bulk micromachining or surface micromachining a silicon wafer substrate.
Capacitors are manufactured in many styles, forms, dimensions, and from a large variety of materials. They all contain at least two electrical conductors, called plates, separated by an insulating layer (dielectric). Capacitors are widely used as parts of electrical circuits in many common electrical devices.
In electrical engineering, a capacitor is a device that stores electrical energy by accumulating electric charges on two closely spaced surfaces that are insulated from each other. The capacitor was originally known as the condenser, a term still encountered in a few compound names, such as the condenser microphone. It is a passive electronic component with two terminals.
Ionic polymer–metal composites (IPMCs) are synthetic composite nanomaterials that display artificial muscle behavior under an applied voltage or electric field. IPMCs are composed of an ionic polymer like Nafion or Flemion whose surfaces are chemically plated or physically coated with conductors such as platinum or gold. Under an applied voltage, ion migration and redistribution due to the imposed voltage across a strip of IPMCs result in a bending deformation. Also, IPMCs can be ionic hydrogel which is being immersed in an electrolyte solution and connected to the electric field indirectly.
The exceptional electrical and mechanical properties of carbon nanotubes have made them alternatives to the traditional electrical actuators for both microscopic and macroscopic applications. Carbon nanotubes are very good conductors of both electricity and heat, and are also very strong and elastic molecules in certain directions. These properties are difficult to find in the same material and very needed for high performance actuators. For current carbon nanotube actuators, multi-walled carbon nanotubes (MWNTs) and bundles of MWNTs have been widely used mostly due to the easiness of handling and robustness. Solution dispersed thick films and highly ordered transparent films of carbon nanotubes have been used for the macroscopic applications.
Ferroelectric polymers are a group of crystalline polar polymers that are also ferroelectric, meaning that they maintain a permanent electric polarization that can be reversed, or switched, in an external electric field.
Nanofluidic circuitry is a nanotechnology aiming for control of fluids in nanometer scale. Due to the effect of an electrical double layer within the fluid channel, the behavior of nanofluid is observed to be significantly different compared with its microfluidic counterparts. Its typical characteristic dimensions fall within the range of 1–100 nm. At least one dimension of the structure is in nanoscopic scale. Phenomena of fluids in nano-scale structure are discovered to be of different properties in electrochemistry and fluid dynamics.
A device generating linear or rotational motion using carbon nanotube(s) as the primary component, is termed a nanotube nanomotor. Nature already has some of the most efficient and powerful kinds of nanomotors. Some of these natural biological nanomotors have been re-engineered to serve desired purposes. However, such biological nanomotors are designed to work in specific environmental conditions. Laboratory-made nanotube nanomotors on the other hand are significantly more robust and can operate in diverse environments including varied frequency, temperature, mediums and chemical environments. The vast differences in the dominant forces and criteria between macroscale and micro/nanoscale offer new avenues to construct tailor-made nanomotors. The various beneficial properties of carbon nanotubes makes them the most attractive material to base such nanomotors on.
A nanogenerator is a compact device that converts mechanical or thermal energy into electricity, serving as an energy harvesting solution for small, wireless autonomous devices. It taps into ambient energy sources like solar, wind, thermal differentials, and kinetic energy, enabling power generation for applications such as wearable electronics and wireless sensor networks. Nanogenerators utilize ambient background energy readily available in the environment, such as temperature gradients from machinery operation, electromagnetic energy in urban areas, or even motion vibrations during activities like walking. This approach offers a means to power low-energy electronics without the need for conventional fuel sources.
Artificial muscles, also known as muscle-like actuators, are materials or devices that mimic natural muscle and can change their stiffness, reversibly contract, expand, or rotate within one component due to an external stimulus. The three basic actuation responses– contraction, expansion, and rotation can be combined within a single component to produce other types of motions. Conventional motors and pneumatic linear or rotary actuators do not qualify as artificial muscles, because there is more than one component involved in the actuation.
The history of electrovibration goes back to 1954. It was first discovered by accident and E. Mallinckrodt, A. L. Hughes and W. Sleator Jr. reported “... that dragging a dry finger over a conductive surface covered with a thin insulating layer and excited with a 110 V signal, created a characteristic rubbery feeling”. In their experiment, the finger and the metal surface create a capacitive setup. The attraction force created between the finger and the surface was too weak to perceive, but it generated a rubbery sensation when the finger was moving on the surface. This sensation was named "electrovibration" by the group. From around early 2010 Senseg and Disney Research are developing technology that could bring electrovibration to modern touchscreen devices.
Soft robotics is a subfield of robotics that concerns the design, control, and fabrication of robots composed of compliant materials, instead of rigid links. In contrast to rigid-bodied robots built from metals, ceramics and hard plastics, the compliance of soft robots can improve their safety when working in close contact with humans.
Mohsen (MO) Shahinpoor is an Iranian American engineer, scientist, and academician. He is a professor and Director at the University of Maine College of Engineering, Department of Mechanical Engineering. He is also a professor in the Graduate School of Biomedical Science and Engineering at the University of Maine.
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