Durium

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Durium is a highly durable synthetic resin developed in 1929. It was used in phonograph record production, as well as in the casting process for metallic type and in the aeronautics industry.

Synthetic resins are industrially produced resins, typically viscous substances that convert into rigid polymers by the process of curing. In order to undergo curing, resins typically contain reactive end groups, such as acrylates or epoxides. Some synthetic resins have properties similar to natural plant resins, but many do not.

Contents

Origin

It is a resorcinol-formaldehyde resin, the result of research by Hal T Beans, professor of chemistry at Columbia University. [1]

Resorcinol chemical compound

Resorcinol (or resorcin) is an organic compound with the formula C6H4(OH)2. It is one of three isomeric benzenediols, the 1,3-isomer (or meta-isomer). It is a white, water-soluble solid.

Formaldehyde Widely used toxic organic compound

Formaldehyde (systematic name methanal) is a naturally occurring organic compound with the formula CH2O (H−CHO). It is the simplest of the aldehydes (R−CHO). The common name of this substance comes from its similarity and relation to formic acid.

Columbia University Private Ivy League research university in New York City

Columbia University is a private Ivy League research university in New York City. Established in 1754 near the Upper West Side region of Manhattan, Columbia is the oldest institution of higher education in New York and the fifth-oldest institution of higher learning in the United States. It is one of nine colonial colleges founded prior to the Declaration of Independence, seven of which belong to the Ivy League. It has been ranked by numerous major education publications as among the top ten universities in the world.

Properties

The resin is flexible, tasteless, odorless, fire and waterproof. It is highly resistant to heat and was heated to 230 °C (446 °F) in production of records. It is fast-setting, reducing the production cost of items made from it.

Applications

Being resistant to fire and water, the resin was used as a substitute for varnish on aeronautical parts.

It was commercialized by Durium Products Company (renamed Durium Products, Inc., from 1931) as the medium for Hit of the Week records, from 1930 to 1932. The resin was bonded to a cardboard substrate and, being much lighter than its predecessor shellac, was sold at newstands for only 15 cents per disc. [2]

Shellac spirit varnish produced from the resin secreted by lac insects on trees in the forests of India and Thailand

Shellac is a resin secreted by the female lac bug, on trees in the forests of India and Thailand. It is processed and sold as dry flakes (pictured) and dissolved in alcohol to make liquid shellac, which is used as a brush-on colorant, food glaze and wood finish. Shellac functions as a tough natural primer, sanding sealant, tannin-blocker, odour-blocker, stain, and high-gloss varnish. Shellac was once used in electrical applications as it possesses good insulation qualities and it seals out moisture. Phonograph and 78 rpm gramophone records were made of it until they were replaced by vinyl long-playing records from the 1950s onwards.

Related Research Articles

Bakelite Early form of plastic

Bakelite or polyoxybenzylmethylenglycolanhydride was the first plastic made from synthetic components. It is a thermosetting phenol formaldehyde resin, formed from a condensation reaction of phenol with formaldehyde. It was developed by the Belgian-American chemist Leo Baekeland in Yonkers, New York, in 1907.

Thermoplastic plastic that becomes soft when heated and hard when cooled

A thermoplastic, or thermosoftening plastic, is a plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling.

Epoxy family of polymer

Epoxy refers to any of the basic components or cured end products of epoxy resins, as well as a colloquial name for the epoxide functional group. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups.

A heat shield is designed to protect an object from overheating by dissipating, reflecting or simply absorbing heat. The term is most often used in reference to exhaust heat management and to systems for dissipation of heat due to friction.

Acrylonitrile butadiene styrene organic polymer

Acrylonitrile butadiene styrene (ABS) (chemical formula (C8H8)x·​(C4H6)y·​(C3H3N)z) is a common thermoplastic polymer. Its glass transition temperature is approximately 105 °C (221 °F). ABS is amorphous and therefore has no true melting point.

Hit of the Week Records

Hit of the Week was an American record label founded in 1930 that sold low-priced records made of Durium instead of the usual shellac.

Phenol formaldehyde resin chemical compound

Phenol formaldehyde resins (PF) or phenolic resins are synthetic polymers obtained by the reaction of phenol or substituted phenol with formaldehyde. Used as the basis for Bakelite, PFs were the first commercial synthetic resins (plastics). They have been widely used for the production of molded products including billiard balls, laboratory countertops, and as coatings and adhesives. They were at one time the primary material used for the production of circuit boards but have been largely replaced with epoxy resins and fiberglass cloth, as with fire-resistant FR-4 circuit board materials.

Polyimide polymer of imide monomers

Polyimide is a polymer of imide monomers. Polyimides have been in mass production since 1955. With their high heat-resistance, polyimides enjoy diverse applications in roles demanding rugged organic materials, e.g. high temperature fuel cells, displays, and various military roles. A classic polyimide is Kapton, which is produced by condensation of pyromellitic dianhydride and 4,4'-oxydianiline.

Fibre-reinforced plastic (FRP) is a composite material made of a polymer matrix reinforced with fibres. The fibres are usually glass, carbon, aramid, or basalt. Rarely, other fibres such as paper, wood, or asbestos have been used. The polymer is usually an epoxy, vinyl ester, or polyester thermosetting plastic, though phenol formaldehyde resins are still in use.

Hot-melt adhesive solvent-free and at room temperature more or less solid products which are applied to the adhesive surface when hot

Hot melt adhesive (HMA), also known as hot glue, is a form of thermoplastic adhesive that is commonly sold as solid cylindrical sticks of various diameters designed to be applied using a hot glue gun. The gun uses a continuous-duty heating element to melt the plastic glue, which the user pushes through the gun either with a mechanical trigger mechanism on the gun, or with direct finger pressure. The glue squeezed out of the heated nozzle is initially hot enough to burn and even blister skin. The glue is tacky when hot, and solidifies in a few seconds to one minute. Hot melt adhesives can also be applied by dipping or spraying, and are popular with hobbyists and crafters both for affixing and as an inexpensive alternative to resin casting.

Silicone rubber is an elastomer composed of silicone—itself a polymer—containing silicon together with carbon, hydrogen, and oxygen. Silicone rubbers are widely used in industry, and there are multiple formulations. Silicone rubbers are often one- or two-part polymers, and may contain fillers to improve properties or reduce cost. Silicone rubber is generally non-reactive, stable, and resistant to extreme environments and temperatures from −55 to 300 °C while still maintaining its useful properties. Due to these properties and its ease of manufacturing and shaping, silicone rubber can be found in a wide variety of products, including: voltage line insulators, automotive applications; cooking, baking, and food storage products; apparel such as undergarments, sportswear, and footwear; electronics; medical devices and implants; and in home repair and hardware with products such as silicone sealants.

Polyester category of polymers

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Countertop

A countertop is a horizontal work surface in kitchens or other food preparation areas, bathrooms or lavatories, and workrooms in general. It is frequently installed upon and supported by cabinets. The surface is positioned at an ergonomic height for the user and the particular task for which it is designed. A countertop may be constructed of various materials with different attributes of functionality, durability, and aesthetics. The countertop may have built-in appliances, or accessory items relative to the intended application.

The NORYL family of modified resins consists of amorphous blends of Polyphenylene Oxides (PPO) or polyphenylene ether (PPE) resins with polystyrene. They combine the inherent benefits of PPE resin, with excellent dimensional stability, good processability and low density.

Sheet moulding compound (SMC) or sheet moulding composite is a ready to mould glass-fibre reinforced polyester material primarily used in compression moulding. The sheet is provided in rolls weighing up to 1000 kg. Alternatively the resin and related materials may be mixed on site when a producer wants greater control over the chemistry and filler.

Plastic bottle bottle constructed of plastic

A plastic bottle is a bottle constructed from high-density plastic. Plastic bottles are typically used to store liquids such as water, soft drinks, motor oil, cooking oil, medicine, shampoo, milk, and ink. The size ranges from very small sample bottles to large carboys. Consumer blow molded containers often have integral handles or are shaped to facilitate grasping.

Fire-safe polymers are polymers that are resistant to degradation at high temperatures. There is need for fire-resistant polymers in the construction of small, enclosed spaces such as skyscrapers, boats, and airplane cabins. In these tight spaces, ability to escape in the event of a fire is compromised, increasing fire risk. In fact, some studies report that about 20% of victims of airplane crashes are killed not by the crash itself but by ensuing fires. Fire-safe polymers also find application as adhesives in aerospace materials, insulation for electronics, and in military materials such as canvas tenting.

Plastic material of a wide range of synthetic or semi-synthetic organic solids

Plastic is material consisting of any of a wide range of synthetic or semi-synthetic organic compounds that are malleable and so can be molded into solid objects.

Impregnation resins are slightly viscous, organic liquids that are used in the forest products industry for wood modification. They typically contain formaldehyde and are composed of dimers and trimers of the main molecule. These can become polymer solutions upon curing inside of a wood substrate, imparting stabilizing properties. Impregnation of these resins involves a vacuum chamber procedure that completely disperses the resin into the wood. Once inside of the wood, the resin can diffuse into the cell wall and enhance the physical strength of the wood even further.

References

  1. "UNBREAKABLE DISKS MADE OF NEW RESIN; Phonograph Records, Flexible and Cheap, Use Durium, Product of Dr. H.T. Beans. UNHURT BY HAMMER BLOWS Compound Which Withstands Heat of Molten Lead Expected to Find Many Industrial Uses". The New York Times. 4 January 1930. Retrieved 30 March 2018.
  2. "Science: Durium Records". Time Magazine. 17 February 1930. Retrieved 30 March 2018.