Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vapourise, but when it does, a flame is a characteristic indicator of the reaction. While the activation energy must be overcome to initiate combustion, the heat from a flame may provide enough energy to make the reaction self-sustaining. Combustion is often a complicated sequence of elementary radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot enough that incandescent light in the form of either glowing or a flame is produced. A simple example can be seen in the combustion of hydrogen and oxygen into water vapor, a reaction commonly used to fuel rocket engines. This reaction releases 242 kJ/mol of heat and reduces the enthalpy accordingly :
In thermodynamics and engineering, a heat engine is a system that converts heat to mechanical energy, which can then be used to do mechanical work. It does this by bringing a working substance from a higher state temperature to a lower state temperature. A heat source generates thermal energy that brings the working substance to the high temperature state. The working substance generates work in the working body of the engine while transferring heat to the colder sink until it reaches a low temperature state. During this process some of the thermal energy is converted into work by exploiting the properties of the working substance. The working substance can be any system with a non-zero heat capacity, but it usually is a gas or liquid. During this process, some heat is normally lost to the surroundings and is not converted to work. Also, some energy is unusable because of friction and drag.
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, radiation, and physical properties of matter. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology.
The thermodynamic free energy is a concept useful in the thermodynamics of chemical or thermal processes in engineering and science. The change in the free energy is the maximum amount of work that a thermodynamic system can perform in a process at constant temperature, and its sign indicates whether a process is thermodynamically favorable or forbidden. Since free energy usually contains potential energy, it is not absolute but depends on the choice of a zero point. Therefore, only relative free energy values, or changes in free energy, are physically meaningful.
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, thermal convection, thermal radiation, and transfer of energy by phase changes. Engineers also consider the transfer of mass of differing chemical species, either cold or hot, to achieve heat transfer. While these mechanisms have distinct characteristics, they often occur simultaneously in the same system.
A recuperator is a special purpose counter-flow energy recovery heat exchanger positioned within the supply and exhaust air streams of an air handling system, or in the exhaust gases of an industrial process, in order to recover the waste heat. Generally, they are used to extract heat from the exhaust and use it to preheat air entering the combustion system. In this way they use waste energy to heat the air, offsetting some of the fuel, and thereby improves the energy efficiency of the system as a whole.
Thermofluids is a branch of science and engineering encompassing four intersecting fields:
A feedwater heater is a power plant component used to pre-heat water delivered to a steam generating boiler. Preheating the feedwater reduces the irreversibilities involved in steam generation and therefore improves the thermodynamic efficiency of the system. This reduces plant operating costs and also helps to avoid thermal shock to the boiler metal when the feedwater is introduced back into the steam cycle.
The Claus process is the most significant gas desulfurizing process, recovering elemental sulfur from gaseous hydrogen sulfide. First patented in 1883 by the chemist Carl Friedrich Claus, the Claus process has become the industry standard.
In thermodynamics, the thermal efficiency is a dimensionless performance measure of a device that uses thermal energy, such as an internal combustion engine, a steam turbine or a steam engine, a boiler, furnace, or a refrigerator for example. For a heat engine, thermal efficiency is the fraction of the energy added by heat that is converted to net work output. In the case of a refrigeration or heat pump cycle, thermal efficiency is the ratio of net heat output for heating, or removal for cooling, to energy input.
Waste heat is heat that is produced by a machine, or other process that uses energy, as a byproduct of doing work. All such processes give off some waste heat as a fundamental result of the laws of thermodynamics. Waste heat has lower utility than the original energy source. Sources of waste heat include all manner of human activities, natural systems, and all organisms, for example, incandescent light bulbs get hot, a refrigerator warms the room air, a building gets hot during peak hours, an internal combustion engine generates high-temperature exhaust gases, and electronic components get warm when in operation.
The Clausthal University of Technology is an institute of technology in Clausthal-Zellerfeld, Lower Saxony, Germany. The small public university is regularly ranked among the Top German universities in engineering by CHE University Rankings. More than 30 % of students and 20 % of academic staff come from abroad, making it one of the most international universities in Germany. The university is best known for the prominent corporate leaders among its former students. In 2011, five of the 30 leading companies within the German stock index had alumni of TUC on their management board. Two of them as CEO.
Thermal engineering is a specialized sub-discipline of mechanical engineering that deals with the movement of heat energy and transfer. The energy can be transferred between two mediums or transformed into other forms of energy. A thermal engineer will have knowledge of thermodynamics and the process to convert generated energy from thermal sources into chemical, mechanical, or electrical energy. Many process plants use a wide variety of machines that utilize components that use heat transfer in some way. Many plants use heat exchangers in their operations. A thermal engineer must allow the proper amount of energy to be transferred for correct use. Too much and the components could fail, too little and the system will not function at all. Thermal engineers must have an understanding of economics and the components that they will be servicing or interacting with. Some components that a thermal engineer could work with include heat exchangers, heat sinks, bi-metals strips, radiators and many more. Some systems that require a thermal engineer include; Boilers, heat pumps, water pumps, engines, and more.
In thermodynamics, heat is energy in transfer to or from a thermodynamic system, by mechanisms other than thermodynamic work or transfer of matter. The various mechanisms of energy transfer that define heat are stated in the next section of this article.
Nikolay Nikolayevich Dobrokhotov was a Soviet scientist and metallurgist, Honored Worker of Science and Technology of the Ukrainian SSR, Academician of the Ukrainian SSR Academy of Sciences.
Yeram Sarkis Touloukian was a professor of mechanical engineering and director of the Thermophysical Properties Research Center at Purdue University in West Lafayette, Indiana. He was world-renowned for his work in thermophysics and his name has become synonymous with the field of thermophysical properties.
Computational fluid dynamics (CFD) are used to understand complex thermal flow regimes in power plants. The thermal power plant may be divided into different subsectors and the CFD analysis applied to critical equipment/components - mainly different types of heat exchangers - which are of crucial significance for efficient and trouble free long-term operation of the plant.
Martin Faulstich is a German research scientist. He is a professor at the Clausthal University of Technology, chairman of the German Advisory Council on the Environment and the managing director of the Clausthal Institute of Environmental Technology (CUTEC) in Clausthal-Zellerfeld.
Milivoje Kostic, is a Serbian-American thermodynamicist and professor emeritus of mechanical engineering at Northern Illinois University, Licensed Professional Engineer (PE) in Illinois, and Editor-in-Chief of the Thermodynamics section of the journal Entropy. He is an expert in energy fundamentals and applications, including nanotechnology, with emphasis on efficiency, efficient energy use and energy conservation, and environment and sustainability.
Wolfgang Arlt is a German thermodynamicist. Until his retirement in 2018, he was professor at the TU Berlin and since 2004 at the Friedrich-Alexander-Universität Erlangen-Nürnberg.
