Naomi J. Halas is the Stanley C. Moore Professor in Electrical and Computer Engineering, and professor of biomedical engineering, chemistry, and physics at Rice University. She is also the founding director of Rice University Laboratory for Nanophotonics, and the Smalley-Curl Institute. She invented the first nanoparticle with tunable plasmonic resonances, which are controlled by their shape and structure, and has won numerous awards for her pioneering work in the field of nanophotonics and plasmonics. She was also part of a team that developed the first dark pulse soliton in 1987 while working for IBM.
Surface-enhanced Raman spectroscopy or surface-enhanced Raman scattering (SERS) is a surface-sensitive technique that enhances Raman scattering by molecules adsorbed on rough metal surfaces or by nanostructures such as plasmonic-magnetic silica nanotubes. The enhancement factor can be as much as 1010 to 1011, which means the technique may detect single molecules.
Harry Albert Atwater, Jr. is an American physicist and materials scientist and is the Otis Booth Leadership Chair of the division of engineering and applied science at the California Institute of Technology. Currently he is the Howard Hughes Professor of Applied Physics and Materials Science and the director for the Liquid Sunlight Alliance (LiSA), a Department of Energy Hub program for solar fuels. Atwater's scientific effort focuses on nanophotonic light-matter interactions and solar energy conversion. His current research in energy centers on high efficiency photovoltaics, carbon capture and removal, and photoelectrochemical processes for generation of solar fuels. His research has resulted in world records for solar photovoltaic conversion and photoelectrochemical water splitting. His work also spans fundamental nanophotonic phenomena, in plasmonics and 2D materials, and also applications including active metasurfaces and optical propulsion.
Plasmonic nanolithography is a nanolithographic process that utilizes surface plasmon excitations such as surface plasmon polaritons (SPPs) to fabricate nanoscale structures. SPPs, which are surface waves that propagate in between planar dielectric-metal layers in the optical regime, can bypass the diffraction limit on the optical resolution that acts as a bottleneck for conventional photolithography.
A plasmonic-enhanced solar cell, commonly referred to simply as plasmonic solar cell, is a type of solar cell that converts light into electricity with the assistance of plasmons, but where the photovoltaic effect occurs in another material.
A plasmonic metamaterial is a metamaterial that uses surface plasmons to achieve optical properties not seen in nature. Plasmons are produced from the interaction of light with metal-dielectric materials. Under specific conditions, the incident light couples with the surface plasmons to create self-sustaining, propagating electromagnetic waves known as surface plasmon polaritons (SPPs). Once launched, the SPPs ripple along the metal-dielectric interface. Compared with the incident light, the SPPs can be much shorter in wavelength.
Plasmonic nanoparticles are particles whose electron density can couple with electromagnetic radiation of wavelengths that are far larger than the particle due to the nature of the dielectric-metal interface between the medium and the particles: unlike in a pure metal where there is a maximum limit on what size wavelength can be effectively coupled based on the material size.
A localized surface plasmon (LSP) is the result of the confinement of a surface plasmon in a nanoparticle of size comparable to or smaller than the wavelength of light used to excite the plasmon. When a small spherical metallic nanoparticle is irradiated by light, the oscillating electric field causes the conduction electrons to oscillate coherently. When the electron cloud is displaced relative to its original position, a restoring force arises from Coulombic attraction between electrons and nuclei. This force causes the electron cloud to oscillate. The oscillation frequency is determined by the density of electrons, the effective electron mass, and the size and shape of the charge distribution. The LSP has two important effects: electric fields near the particle's surface are greatly enhanced and the particle's optical absorption has a maximum at the plasmon resonant frequency. Surface plasmon resonance can also be tuned based on the shape of the nanoparticle. The plasmon frequency can be related to the metal dielectric constant. The enhancement falls off quickly with distance from the surface and, for noble metal nanoparticles, the resonance occurs at visible wavelengths. Localized surface plasmon resonance creates brilliant colors in metal colloidal solutions.
Tip-enhanced Raman spectroscopy (TERS) is a variant of surface-enhanced Raman spectroscopy (SERS) that combines scanning probe microscopy with Raman spectroscopy. High spatial resolution chemical imaging is possible via TERS, with routine demonstrations of nanometer spatial resolution under ambient laboratory conditions, or better at ultralow temperatures and high pressure.
Graphene is a 2D nanosheet with atomic thin thickness in terms of 0.34 nm. Due to the ultrathin thickness, graphene showed many properties that are quite different from their bulk graphite counterparts. The most prominent advantages are known to be their high electron mobility and high mechanical strengths. Thus, it exhibits potential for applications in optics and electronics especially for the development of wearable devices as flexible substrates. More importantly, the optical absorption rate of graphene is 2.3% in the visible and near-infrared region. This broadband absorption characteristic also attracted great attention of the research community to exploit the graphene-based photodetectors/modulators.
Plasmon coupling is a phenomenon that occurs when two or more plasmonic particles approach each other to a distance below approximately one diameter's length. Upon the occurrence of plasmon coupling, the resonance of individual particles start to hybridize, and their resonance spectrum peak wavelength will shift, depending on how surface charge density distributes over the coupled particles. At a single particle's resonance wavelength, the surface charge densities of close particles can either be out of phase or in phase, causing repulsion or attraction and thus leading to increase (blueshift) or decrease (redshift) of hybridized mode energy. The magnitude of the shift, which can be the measure of plasmon coupling, is dependent on the interparticle gap as well as particles geometry and plasmonic resonances supported by individual particles. A larger redshift is usually associated with smaller interparticle gap and larger cluster size.
Prashant Jain is an Indian-born American scientist and a professor of chemistry at the University of Illinois Urbana–Champaign where his research laboratory studies the interaction of light with matter, designs nanoparticle catalysts, and develops methods for mimicking plant photosynthesis. He is a Fellow of the American Association for the Advancement of Science and the Royal Society of Chemistry, a TR35 inventor, a Sloan Fellow, a PECASE recipient, a Royal Society of Chemistry Beilby medalist, and a top-cited researcher in chemical sciences.
So-Jung Park 박소정(朴昭靜) is a professor of chemistry at Ewha Womans University, Republic of Korea. Her research considers the self-assembly of nanoparticles and functional molecules for biomedical and optoelectronic devices. She serves as Associate Editor of ACS Applied Materials & Interfaces and Nanoscale.
Single-Entity Electrochemistry (SEE) refers to the electroanalysis of an individual unit of interest. A unique feature of SEE is that it unifies multiple different branches of electrochemistry. Single-Entity Electrochemistry pushes the bounds of the field as it can measure entities on a scale of 100 microns to angstroms. Single-Entity Electrochemistry is important because it gives the ability to view how a single molecule, or cell, or "thing" affects the bulk response, and thus the chemistry that might have gone unknown otherwise. The ability to monitor the movement of one electron or ion from one unit to another is valuable, as many vital reactions and mechanisms undergo this process. Electrochemistry is well suited for this measurement due to its incredible sensitivity. Single-Entity Electrochemistry can be used to investigate nanoparticles, wires, vesicles, nanobubbles, nanotubes, cells, and viruses, and other small molecules and ions. Single-entity electrochemistry has been successfully used to determine the size distribution of particles as well as the number of particles present inside a vesicle or other similar structures
Giulia Tagliabue is an Italian engineer specialized in nanophotonics. She is a professor at EPFL's School of Engineering, where she leads the Laboratory of Nanoscience for Energy Technologies (LNET).
Rizia Bardhan is an Indian origin American biomolecular engineer who is an Associate Professor of Chemical & Biological Engineering at Iowa State University. She is Associate Editor of ACS Applied Materials & Interfaces.
Bin Liu is a chemist who is Professor and Provost's Chair at the National University of Singapore. Her research considers polymer chemistry and organic functional materials. She was appointed Vice President of Research and Technology in 2019. She was awarded the 2021 Royal Society of Chemistry Centenary Prize.
Mark Stockman was a Soviet-born American physicist. He was a professor of physics and astronomy at Georgia State University. Best known for his contributions to plasmonics, Stockman has co-theorized plasmonic lasers, also known as spasers, in 2003.
In chemistry, plasmonic catalysis is a type of catalysis that uses plasmons to increase the rate of a chemical reaction. A plasmonic catalyst is made up of a metal nanoparticle surface which generates localized surface plasmon resonances (LSPRs) when excited by light. These plasmon oscillations create an electron-rich region near the surface of the nanoparticle, which can be used to excite the electrons of nearby molecules.
Christy F. Landes is an American physical chemist who is the Jerry A. Walker Endowed Chair in chemistry at the University of Illinois Urbana-Champaign. She previously was the Kenneth S. Pitzer-Schlumberger Chair at Rice University. She seeks to understand the structure-function relationships in biological processes and materials. She was appointed a National Academy of Sciences Kavli Fellow in 2019.
