Infrared spectroscopy is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. It is used to study and identify chemical substances or functional groups in solid, liquid, or gaseous forms. It can be used to characterize new materials or identify and verify known and unknown samples. The method or technique of infrared spectroscopy is conducted with an instrument called an infrared spectrometer which produces an infrared spectrum. An IR spectrum can be visualized in a graph of infrared light absorbance on the vertical axis vs. frequency, wavenumber or wavelength on the horizontal axis. Typical units of wavenumber used in IR spectra are reciprocal centimeters, with the symbol cm−1. Units of IR wavelength are commonly given in micrometers, symbol μm, which are related to the wavenumber in a reciprocal way. A common laboratory instrument that uses this technique is a Fourier transform infrared (FTIR) spectrometer. Two-dimensional IR is also possible as discussed below.
Differential scanning calorimetry (DSC) is a thermoanalytical technique in which the difference in the amount of heat required to increase the temperature of a sample and reference is measured as a function of temperature. Both the sample and reference are maintained at nearly the same temperature throughout the experiment. Generally, the temperature program for a DSC analysis is designed such that the sample holder temperature increases linearly as a function of time. The reference sample should have a well-defined heat capacity over the range of temperatures to be scanned. Additionally, the reference sample must be stable, of high purity, and must not experience much change across the temperature scan. Typically, reference standards have been metals such as indium, tin, bismuth, and lead, but other standards such as polyethylene and fatty acids have been proposed to study polymers and organic compounds, respectively.
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a mass spectrum, a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures.
Thiophene is a heterocyclic compound with the formula C4H4S. Consisting of a planar five-membered ring, it is aromatic as indicated by its extensive substitution reactions. It is a colorless liquid with a benzene-like odor. In most of its reactions, it resembles benzene. Compounds analogous to thiophene include furan (C4H4O), selenophene (C4H4Se) and pyrrole (C4H4NH), which each vary by the heteroatom in the ring.
Gas chromatography–mass spectrometry (GC–MS) is an analytical method that combines the features of gas-chromatography and mass spectrometry to identify different substances within a test sample. Applications of GC–MS include drug detection, fire investigation, environmental analysis, explosives investigation, food and flavor analysis, and identification of unknown samples, including that of material samples obtained from planet Mars during probe missions as early as the 1970s. GC–MS can also be used in airport security to detect substances in luggage or on human beings. Additionally, it can identify trace elements in materials that were previously thought to have disintegrated beyond identification. Like liquid chromatography–mass spectrometry, it allows analysis and detection even of tiny amounts of a substance.
In 1976 two identical Viking program landers each carried four types of biological experiments to the surface of Mars. The first successful Mars landers, Viking 1 and Viking 2, then carried out experiments to look for biosignatures of microbial life on Mars. The landers each used a robotic arm to pick up and place soil samples into sealed test containers on the craft.
Thermogravimetric analysis or thermal gravimetric analysis (TGA) is a method of thermal analysis in which the mass of a sample is measured over time as the temperature changes. This measurement provides information about physical phenomena, such as phase transitions, absorption, adsorption and desorption; as well as chemical phenomena including chemisorptions, thermal decomposition, and solid-gas reactions.
Mudstone, a type of mudrock, is a fine-grained sedimentary rock whose original constituents were clays or muds. Mudstone is distinguished from shale by its lack of fissility.
The Thermal and Evolved Gas Analyzer (TEGA) is a scientific instrument aboard the Phoenix spacecraft, a Mars lander which landed and operated on the planet Mars in 2008. TEGA's design is based on experience gained from the failed Mars Polar Lander. Soil samples taken from the Martian surface by the robot arm are eventually delivered to the TEGA, where they are heated in an oven to about 1,000 °C. This heat causes the volatile compounds to be given off as gases which are sent to a mass spectrometer for analysis. This spectrometer is adjusted to measure particularly the isotope ratios for oxygen, carbon, nitrogen, and heavier gases. Detection values are as low as 10 parts per billion. The Phoenix TEGA has 8 ovens, which are enough for 8 samples.
Martian soil is the fine regolith found on the surface of Mars. Its properties can differ significantly from those of terrestrial soil, including its toxicity due to the presence of perchlorates. The term Martian soil typically refers to the finer fraction of regolith. So far, no samples have been returned to Earth, the goal of a Mars sample-return mission, but the soil has been studied remotely with the use of Mars rovers and Mars orbiters.
The Aeolis quadrangle is one of a series of 30 quadrangle maps of Mars used by the United States Geological Survey (USGS) Astrogeology Research Program. The Aeolis quadrangle is also referred to as MC-23 . The Aeolis quadrangle covers 180° to 225° W and 0° to 30° south on Mars, and contains parts of the regions Elysium Planitia and Terra Cimmeria. A small part of the Medusae Fossae Formation lies in this quadrangle.
Rosalind Franklin, previously known as the ExoMars rover, is a planned robotic Mars rover, part of the international ExoMars programme led by the European Space Agency and the Russian Roscosmos State Corporation. The mission was scheduled to launch in July 2020, but was postponed to 2022. The 2022 Russian invasion of Ukraine has caused an indefinite delay of the programme, as the member states of the ESA voted to suspend the joint mission with Russia; in July 2022, ESA terminated its cooperation on the project with Russia. As of May 2022, the launch of the rover is not expected to occur before 2028 due to the need for a new non-Russian landing platform.
Sample Analysis at Mars (SAM) is a suite of instruments on the Mars Science Laboratory Curiosity rover. The SAM instrument suite will analyze organics and gases from both atmospheric and solid samples. It was developed by the NASA Goddard Space Flight Center, the Laboratoire des Atmosphères Milieux Observations Spatiales (LATMOS) associated to the Laboratoire Inter-Universitaire des Systèmes Atmosphériques (LISA), and Honeybee Robotics, along with many additional external partners.
The Mars Organic Molecule Analyser (MOMA) is a mass spectrometer-based instrument on board the Rosalind Franklin rover to be launched in 2028 to Mars on an astrobiology mission. It will search for organic compounds in the collected soil samples. By characterizing the molecular structures of detected organics, MOMA can provide insights into potential molecular biosignatures. MOMA will be able to detect organic molecules at concentrations as low as 10 parts-per-billion by weight (ppbw). MOMA examines solid crushed samples exclusively; it does not perform atmospheric analyses.
The Urey instrument, or Urey: Mars Organic and Oxidant Detector was a developmental spacecraft instrument for detecting organic compounds including amino acids.
Dawn Yvonne Sumner is an American geologist, planetary scientist, and astrobiologist. She is a professor at the University of California, Davis. Sumner's research includes evaluating microbial communities in Antarctic lakes, exploration of Mars via the Curiosity rover, and characterization of microbial communities in the lab and from ancient geologic samples. She is an investigator on the NASA Mars Science Laboratory (MSL) and was Chair of the UC Davis Department of Earth & Planetary Sciences from 2014 to 2016. She is Fellow of the Geological Society of America.
The reported presence of methane in the atmosphere of Mars is of interest to many geologists and astrobiologists, as methane may indicate the presence of microbial life on Mars, or a geochemical process such as volcanism or hydrothermal activity.
Jennifer Eigenbrode is an interdisciplinary astrobiologist who works at NASA's Goddard Space Flight Center. She specializes in organic chemistry, geology, and organic bio-geochemistry of martian and ocean-world environments.
The Bagnold Dunes is a 35-kilometre-long (22 mi) group of dark grey dunes in the Gale Crater on Mars. They are named after Ralph Alger Bagnold, who crossed the Libyan Desert and was one of the first explorers to acquire a deep understanding of the physics behind sand dunes. The dunes migrate around 0.4 metres (1.3 ft) every Earth year.
Sushil K. Atreya is a planetary scientist, educator, and researcher. Atreya is a professor of Climate and Space Sciences and Engineering at the University of Michigan, Ann Arbor.
