This article needs additional citations for verification .(November 2013) |
The Explosive Shipping Classification System exists as part of the United Nations Recommendations on the Transport of Dangerous Good: Model Regulations. [lower-alpha 1] [1] [2] The system describes the classification of explosives, divisions within that class that describe the type of hazard they present and compatibility groups that identify the specific type of explosive substance, and what articles are compatible for transport and storage.
Substances and goods subject to these regulation are assigned to one of 9 Classes detailed within the UN Model Regulations, determined by the predominant hazard of the substance or goods. Class 1 Goods and Substances are classified as Explosives, under the UN Explosive Hazard Classification System and Codes that is also outlined within the International Ammunition Technical Guideline (IATG).
Class 1 goods are subdivided further into one of 6 distinct divisions, that describes the predominant explosive hazard that exists if that article was to detonate or activate while in transport or storage. These divisions are as follows:
Explosive article are assigned a Class and a Division to determine a specific Hazard Division (HD) under this regulation, following a classification process and a number of tests. Under the UN Dangerous Goods classification, explosive hazard Divisions are awarded using the UN Manual of Criteria and Tests, by following the process flow chart '10.3 Procedure for assignment to a division of the class of explosives' and conducting the appropriate tests either UN series 5, series 6, or series 7 tests. [3] Series 5 tests are used to determine if an article can be assigned to HD1.5 'Very Insensitive Explosive'; series 6 tests are used to determine the classification of an article within Hazard Divisions 1.1, 1.2, 1.3, or 1.4; and series 7 tests are used to determine if an article can be assigned to HD 1.6 as an article containing predominantly 'Extremely Insensitive Explosives'.
Generally speaking Dangerous Goods should not be transported together in the same container, this includes the shipment of different kinds of explosives, as the potential for an inadvertent detonation can increase dramatically if two highly incompatible explosives are transported together. To enable efficient transportation and storage, and , to allow the transportation of some explosives together, a further classification system is used called compatibility groups (CGs). Compatibility groups helps to group explosives of a similar type together, or allow the transportation of combinations that have been deemed safe. Hazard divisions and compatibility groups don't classify specific explosive compounds or substances, but rather a HD and CG classifies a specific article of explosive, including its packaging.
Compatibility groups further divide Class 1 explosives on the basis of the type explosive compound and risk of activation, or for CG 'S' the article's packaging, in order to determine which types of explosives are safe to transport with each other. Most explosives will be classified into groups, A, B, C, D, E, F and S. The other groups classify It is possible that two articles containing a number of the same explosive product (i.e. electric detonators) with different inner and outer packaging, could have Hazard Classifications of 1.2B and 1.4S, making one of the articles significantly safer to transport with other explosives.
The following is a list of compatibility groups, and a description of the substances or articles in that group. [4] A substance is an explosive compound on its own; an article is an end user explosive product.
Hazard Division | Compatibility Group | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
A | B | C | D | E | F | G | H | J | K | L | N | S | |
1.1 | 1.1A | 1.1B | 1.1C | 1.1D | 1.1E | 1.1F | 1.1G | 1.1J | 1.1L | ||||
1.2 | 1.2B | 1.2C | 1.2D | 1.2E | 1.2F | 1.2G | 1.2H | 1.2J | 1.2K | 1.2L | |||
1.3 | 1.3C | 1.3F | 1.3G | 1.3H | 1.3J | 1.3K | 1.3L | ||||||
1.4 | 1.4B | 1.4C | 1.4D | 1.4E | 1.4F | 1.4G | 1.4S | ||||||
1.5 | 1.5D | ||||||||||||
1.6 | 1.6N |
Compatibility Group → Explosive Hazard ↓ | A | B | C | D | E | F | G | H | J | K | L | N | S |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1.1Mass explosion | 1.1A Mercury fulminate, Lead azide Etc. | 1.1B Blasting caps, ingitors | 1.1C | 1.1D Detonating cord, explosive boosters, blackpowder, most secondary explosives | 1.1E | 1.1F | 1.1G Flash powder, Bulk Salutes, very large fireworks | 1.1J Liquid fuelled cruise missiles and torpedoes, incendiary bombs | 1.1L | ||||
1.2Projection, no mass explosion | 1.2B Detonating fuzes | 1.2C Rocket motors, propelling charges | 1.2D Hand grenades, shaped charges | 1.2E Rockets with bursting charges | 1.2F | 1.2G Large fireworks, practice grenades | 1.2H White phosphorus grenades | 1.2J | 1.2K Chemical shells | 1.2L Hypergolic fuelled rocket motors | |||
1.3Fire, minor blast | 1.3C Smokeless powder, rocket motors | 1.3F Fuzed hand grenades | 1.3G Display Fireworks, smoke grenades, flares | 1.3H | 1.3J | 1.3K | 1.3L Hypergolic fuelled rocket motors | ||||||
1.4Minor hazard | 1.4B Blasting Caps | 1.4C Model rocket motors | 1.4D Det. Cord | 1.4E | 1.4F | 1.4G Consumer Fireworks, Proximate Pyro | 1.4S Proximate Pyro, Blasting Caps, Small Arms Ammunition | ||||||
1.5Very insensitive, mass explosion | 1.5D Blasting Agents | ||||||||||||
1.6Extremely insensitive | 1.6N |
In some cases it may be appropriate and safe to mix explosives when transporting or storing them, certain compatibility groups may be mixed with others and still remain safe.
Compatibility Group | A | B | C | D | E | F | G | H | J | K | L | N | S |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
A | a. | ||||||||||||
B | X | Xg. | |||||||||||
C | X | Xc,d, | Xc. | Xf. | Xd. | Xg. | |||||||
D | Xc,d, | X | Xc. | Xf. | Xd. | Xg. | |||||||
E | Xc. | Xc. | X | Xf. | Xd. | Xg. | |||||||
F | X | Xg. | |||||||||||
G | Xf. | Xf. | Xf. | X | Xg. | ||||||||
H | X | Xg. | |||||||||||
J | X | Xg. | |||||||||||
K | X | Xg. | |||||||||||
L | Xb. | ||||||||||||
N | Xd. | Xd. | Xd. | X | Xg. | ||||||||
S | Xg. | Xg. | Xg. | Xg. | Xg. | Xg. | Xg. | Xg. | Xg. | Xg. | X |
X Denotes compatibility groups that can be mixed in transport.
Detonators/blasting caps, may not be packaged together with any other explosive.
a. Different explosives of compatibility group A should be packaged separately
b. Explosives of compatibility group L shall only be packed with an identical explosive.
c. Explosive articles of the compatibility group C, D, or E may be packed together, and the whole packaged shall be treated as belonging to compatibility group E.
d. Explosive articles of the compatibility group C and D may be packed together, and the whole packaged shall be treated as belonging to compatibility group D.
e. Explosive articles of the compatibility group C, D, E or N may be packed together, and the whole packaged shall be treated as belonging to compatibility group D.
f. Explosive belonging to the compatibility group G except for fireworks, may be packaged together with compatibility groups C, D, and E, provided they are not carried in the same compartment, carry box, or vehicle, and the whole packaged shall be treated as belonging to compatibility group E.
g. Explosive of compatibility group S, may be packaged together with explosives of any other group, except A or L, and the combined packaged may be treated as belonging to any of the compatibility groups most appropriate, except S.
An explosive is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances.
A detonator, sometimes called a blasting cap in the US, is a small sensitive device used to provoke a larger, more powerful but relatively insensitive secondary explosive of an explosive device used in commercial mining, excavation, demolition, etc.
C-4 or Composition C-4 is a common variety of the plastic explosive family known as Composition C, which uses RDX as its explosive agent. C-4 is composed of explosives, plastic binder, plasticizer to make it malleable, and usually a marker or odorizing taggant chemical. C-4 has a texture similar to modelling clay and can be molded into any desired shape. C-4 is relatively insensitive and can be detonated only by the shock wave from a detonator or blasting cap.
A UN number is a four-digit number that identifies hazardous materials, and articles in the framework of international trade and transport. Some hazardous substances have their own UN numbers, while sometimes groups of chemicals or products with similar properties receive a common UN number. A chemical in its solid state may receive a different UN number than the liquid phase if its hazardous properties differ significantly; substances with different levels of purity may also receive different UN numbers.
A safety data sheet (SDS), material safety data sheet (MSDS), or product safety data sheet (PSDS) is a document that lists information relating to occupational safety and health for the use of various substances and products. SDSs are a widely used system for cataloguing information on chemicals, chemical compounds,chemical mixtures. SDS information may include instructions for the safe use and potential hazards associated with a particular material or product, along with spill-handling procedures. The older MSDS formats could vary from source to source within a country depending on national requirements; however, the newer SDS format is internationally standardized.
Figure of Insensitivity is an inverse scale of measure of the impact sensitivity of an explosive substance. In this particular context the term 'Insensitivity' refers to the likelihood of initiation/detonation by impact, friction, electrostatic discharge, application of flame, etc. It is a quantitative measure of the level of stimulus required to cause explosive decomposition.
Dangerous goods, abbreviated DG, are substances that when transported are a risk to health, safety, property or the environment. Certain dangerous goods that pose risks even when not being transported are known as hazardous materials. An example for dangerous goods is hazardous waste which is waste that has substantial or potential threats to public health or the environment.
Shock sensitivity is a comparative measure of the sensitivity to sudden compression of an explosive chemical compound. Determination of the shock sensitivity of a material intended for practical use is one important aspect of safety testing of explosives. A variety of tests and indices are in use, of which one of the more common is the Rotter Impact Test with results expressed as FoI At least four other impact tests are in common use, while various "gap tests" are used to measure sensitivity to blast shock.
ADR, formally the Agreement of 30 September 1957 concerning the International Carriage of Dangerous Goods by Road is a 1957 United Nations treaty that governs transnational transport of hazardous materials. "ADR" is derived from the French name for the treaty: Accord relatif au transport international des marchandises Dangereuses par Route). Until 31 December 2020, the treaty was fully named European Agreement concerning the International Carriage of Dangerous Goods by Road. However, as the word "European" might have given the impression that the treaty was only open for accession to European states, an amendment was decided in the end of 2019.
In electrical and safety engineering, hazardous locations are places where fire or explosion hazards may exist. Sources of such hazards include gases, vapors, dust, fibers, and flyings, which are combustible or flammable. Electrical equipment installed in such locations can provide an ignition source, due to electrical arcing, or high temperatures. Standards and regulations exist to identify such locations, classify the hazards, and design equipment for safe use in such locations.
The Globally Harmonized System of Classification and Labelling of Chemicals (GHS) is an internationally agreed-upon standard managed by the United Nations that was set up to replace the assortment of hazardous material classification and labelling schemes previously used around the world. Core elements of the GHS include standardized hazard testing criteria, universal warning pictograms, and safety data sheets which provide users of dangerous goods relevant information with consistent organization. The system acts as a complement to the UN numbered system of regulated hazardous material transport. Implementation is managed through the UN Secretariat. Although adoption has taken time, as of 2017, the system has been enacted to significant extents in most major countries of the world. This includes the European Union, which has implemented the United Nations' GHS into EU law as the CLP Regulation, and United States Occupational Safety and Health Administration standards.
A combustible material is a material that can burn in air under certain conditions. A material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort and a flammable material catches fire immediately on exposure to flame.
The HAZMAT Class 2 in United States law includes all gases which are compressed and stored for transportation. Class 2 has three divisions: Flammable, Non-Flammable/Non-Poisonous, and Poisonous. This classification is based on the United Nations' Recommendations on the Transport of Dangerous Goods - Model Regulations. In Canada, the Transportation of Dangerous Goods Regulations, or TDGR, are also based on the UN Model Regulations and contain the same three divisions.
Hazmat Class 1 are explosive materials which are any substance or article, including a device, which is designed to function by explosion or which, by chemical reaction within itself is able to function in a similar manner even if not designed to function by explosion.
Hazard statements form part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). They are intended to form a set of standardized phrases about the hazards of chemical substances and mixtures that can be translated into different languages. As such, they serve the same purpose as the well-known R-phrases, which they are intended to replace.
Hazard pictograms form part of the international Globally Harmonized System of Classification and Labelling of Chemicals (GHS). Two sets of pictograms are included within the GHS: one for the labelling of containers and for workplace hazard warnings, and a second for use during the transport of dangerous goods. Either one or the other is chosen, depending on the target audience, but the two are not used together. The two sets of pictograms use the same symbols for the same hazards, although certain symbols are not required for transport pictograms. Transport pictograms come in wider variety of colors and may contain additional information such as a subcategory number.
Musk xylene is a synthetic musk fragrance which mimics natural musk. It has been used as a perfume fixative in a wide variety of consumer products, and is still used in some cosmetics and fragrances.
The UN Recommendations on the Transport of Dangerous Goods are contained in the UN Model Regulations prepared by the Subcommittee of Experts on the Transport of Dangerous Goods of the United Nations Economic and Social Council (ECOSOC). They cover the transport of dangerous goods by all modes of transport except by bulk tanker. They are not obligatory or legally binding on individual countries, but have gained a wide degree of international acceptance: they form the basis of several international agreements and many national laws.
The Australian Dangerous Goods Code is promulgated by The Advisory Committee on Transport of Dangerous Goods. The most current version is the seventh edition, 7.7 released in 2020 and mandated from October 1 2021. Read in conjunction with accompanying national and State laws, the document creates a significant level of standardisation for the transportation of dangerous goods in Australia.
Air travel with firearms and ammunition involves a number of laws, regulations and practices that travelers with firearms or ammunition must comply with and should be familiar with before travel. The main rules are set by the International Air Transport Association (IATA), but there are a number of local variations between airlines and local laws that sometimes are conflicting.