Extraordinary optical transmission

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Interference pattern of double slits, where the slit width is one third the wavelength. Subwavelength slits.JPG
Interference pattern of double slits, where the slit width is one third the wavelength.

Extraordinary optical transmission (EOT) is the phenomenon of greatly enhanced transmission of light through a subwavelength aperture in an otherwise opaque metallic film which has been patterned with a regularly repeating periodic structure. Generally when light of a certain wavelength falls on a subwavelength aperture, it is diffracted isotropically in all directions evenly, with minimal far-field transmission. This is the understanding from classical aperture theory as described by Bethe. [1] In EOT however, the regularly repeating structure enables much higher transmission efficiency to occur, up to several orders of magnitude greater than that predicted by classical aperture theory. It was first described in 1998. [2] [3]

This phenomenon that was fully analyzed with a microscopic scattering model is partly attributed to the presence of surface plasmon resonances [4] and constructive interference. A surface plasmon (SP) is a collective excitation of the electrons at the junction between a conductor and an insulator and is one of a series of interactions between light and a metal surface called Plasmonics.

Currently, there is experimental evidence of EOT out of the optical range. [5] Analytical approaches also predict EOT on perforated plates with a perfect conductor model. [6] [7] [8] Holes can somewhat emulate plasmons at other regions of the electromagnetic spectrum where they do not exist. [9] [10] [11] Then, the plasmonic contribution is a very particular peculiarity of the EOT resonance and should not be taken as the main contribution to the phenomenon. More recent work has shown a strong contribution from overlapping evanescent wave coupling, [12] which explains why surface plasmon resonance enhances the EOT effect on both sides of a metallic film at optical frequencies, but accounts for the terahertz-range transmission.

Simple analytical explanations of this phenomenon have been elaborated, emphasizing the similarity between arrays of particles and arrays of holes, and establishing that the phenomenon is dominated by diffraction. [13] [14] [15]

Applications

EOT is expected to play an important role in the creation of components of efficient photonic integrated circuits (PICs). Photonic integrated circuits are analogous to electronic circuits but based upon photons instead of electrons.

One of the most ground-breaking results linked to EOT is the possibility to implement a Left-Handed Metamaterial (LHM) by simply stacking hole arrays. [16]

EOT-based chemical and biological sensing (for example, improving ELISA based antibody detection) is another major area of research. [17] [18] [19] [20] [21] [22] [23] [24] Much like in a traditional surface plasmon resonance sensor, the EOT efficiency varies with the wavelength of the incident light, and the value of the in-plane wavevector component. This can be exploited as a means of transducing chemical binding events by measuring a change in the local dielectric constant (due to binding of the target species) as a shift in the spectral location and/or intensity of the EOT peak. Variation of the hole geometry alters the spectral location of the EOT peak such that the chemical binding events can be optically detected at a desired wavelength. [25] EOT-based sensing offers one key advantage over a Kretschmann-style SPR chemical sensor, that of being an inherently nanometer-micrometer scale device; it is therefore particularly amenable to miniaturization [26] .

Related Research Articles

<span class="mw-page-title-main">Plasmon</span> Quasiparticle of charge oscillations in condensed matter

In physics, a plasmon is a quantum of plasma oscillation. Just as light consists of photons, the plasma oscillation consists of plasmons. The plasmon can be considered as a quasiparticle since it arises from the quantization of plasma oscillations, just like phonons are quantizations of mechanical vibrations. Thus, plasmons are collective oscillations of the free electron gas density. For example, at optical frequencies, plasmons can couple with a photon to create another quasiparticle called a plasmon polariton.

<span class="mw-page-title-main">Metamaterial</span> Materials engineered to have properties that have not yet been found in nature

A metamaterial is any material engineered to have a property that is rarely observed in naturally occurring materials. They are made from assemblies of multiple elements fashioned from composite materials such as metals and plastics. These materials are usually arranged in repeating patterns, at scales that are smaller than the wavelengths of the phenomena they influence. Metamaterials derive their properties not from the properties of the base materials, but from their newly designed structures. Their precise shape, geometry, size, orientation and arrangement gives them their smart properties capable of manipulating electromagnetic waves: by blocking, absorbing, enhancing, or bending waves, to achieve benefits that go beyond what is possible with conventional materials.

A superlens, or super lens, is a lens which uses metamaterials to go beyond the diffraction limit. The diffraction limit is a feature of conventional lenses and microscopes that limits the fineness of their resolution depending on the illumination wavelength and the numerical aperture (NA) of the objective lens. Many lens designs have been proposed that go beyond the diffraction limit in some way, but constraints and obstacles face each of them.

Nanophotonics or nano-optics is the study of the behavior of light on the nanometer scale, and of the interaction of nanometer-scale objects with light. It is a branch of optics, optical engineering, electrical engineering, and nanotechnology. It often involves dielectric structures such as nanoantennas, or metallic components, which can transport and focus light via surface plasmon polaritons.

<span class="mw-page-title-main">Surface plasmon</span>

Surface plasmons (SPs) are coherent delocalized electron oscillations that exist at the interface between any two materials where the real part of the dielectric function changes sign across the interface. SPs have lower energy than bulk plasmons which quantise the longitudinal electron oscillations about positive ion cores within the bulk of an electron gas.

A spaser or plasmonic laser is a type of laser which aims to confine light at a subwavelength scale far below Rayleigh's diffraction limit of light, by storing some of the light energy in electron oscillations called surface plasmon polaritons. The phenomenon was first described by David J. Bergman and Mark Stockman in 2003. The word spaser is an acronym for "surface plasmon amplification by stimulated emission of radiation". The first such devices were announced in 2009 by three groups: a 44-nanometer-diameter nanoparticle with a gold core surrounded by a dyed silica gain medium created by researchers from Purdue, Norfolk State and Cornell universities, a nanowire on a silver screen by a Berkeley group, and a semiconductor layer of 90 nm surrounded by silver pumped electrically by groups at the Eindhoven University of Technology and at Arizona State University. While the Purdue-Norfolk State-Cornell team demonstrated the confined plasmonic mode, the Berkeley team and the Eindhoven-Arizona State team demonstrated lasing in the so-called plasmonic gap mode. In 2018, a team from Northwestern University demonstrated a tunable nanolaser that can preserve its high mode quality by exploiting hybrid quadrupole plasmons as an optical feedback mechanism.

Plasmonic nanolithography is a nanolithographic process that utilizes surface plasmon excitations such as surface plasmon polaritons (SPPs) to fabricate nanoscale structures. SPPs, which are surface waves that propagate in between planar dielectric-metal layers in the optical regime, can bypass the diffraction limit on the optical resolution that acts as a bottleneck for conventional photolithography.

<span class="mw-page-title-main">Negative-index metamaterial</span> Material with a negative refractive index

Negative-index metamaterial or negative-index material (NIM) is a metamaterial whose refractive index for an electromagnetic wave has a negative value over some frequency range.

<span class="mw-page-title-main">Terahertz metamaterial</span>

A terahertz metamaterial is a class of composite metamaterials designed to interact at terahertz (THz) frequencies. The terahertz frequency range used in materials research is usually defined as 0.1 to 10 THz.

<span class="mw-page-title-main">Photonic metamaterial</span> Type of electromagnetic metamaterial

A photonic metamaterial (PM), also known as an optical metamaterial, is a type of electromagnetic metamaterial, that interacts with light, covering terahertz (THz), infrared (IR) or visible wavelengths. The materials employ a periodic, cellular structure.

A metamaterial absorber is a type of metamaterial intended to efficiently absorb electromagnetic radiation such as light. Furthermore, metamaterials are an advance in materials science. Hence, those metamaterials that are designed to be absorbers offer benefits over conventional absorbers such as further miniaturization, wider adaptability, and increased effectiveness. Intended applications for the metamaterial absorber include emitters, photodetectors, sensors, spatial light modulators, infrared camouflage, wireless communication, and use in solar photovoltaics and thermophotovoltaics.

<span class="mw-page-title-main">Surface plasmon polariton</span> Electromagnetic waves that travel along an interface

Surface plasmon polaritons (SPPs) are electromagnetic waves that travel along a metal–dielectric or metal–air interface, practically in the infrared or visible-frequency. The term "surface plasmon polariton" explains that the wave involves both charge motion in the metal and electromagnetic waves in the air or dielectric ("polariton").

A plasmonic metamaterial is a metamaterial that uses surface plasmons to achieve optical properties not seen in nature. Plasmons are produced from the interaction of light with metal-dielectric materials. Under specific conditions, the incident light couples with the surface plasmons to create self-sustaining, propagating electromagnetic waves known as surface plasmon polaritons (SPPs). Once launched, the SPPs ripple along the metal-dielectric interface. Compared with the incident light, the SPPs can be much shorter in wavelength.

<span class="mw-page-title-main">Localized surface plasmon</span>

A localized surface plasmon (LSP) is the result of the confinement of a surface plasmon in a nanoparticle of size comparable to or smaller than the wavelength of light used to excite the plasmon. When a small spherical metallic nanoparticle is irradiated by light, the oscillating electric field causes the conduction electrons to oscillate coherently. When the electron cloud is displaced relative to its original position, a restoring force arises from Coulombic attraction between electrons and nuclei. This force causes the electron cloud to oscillate. The oscillation frequency is determined by the density of electrons, the effective electron mass, and the size and shape of the charge distribution. The LSP has two important effects: electric fields near the particle's surface are greatly enhanced and the particle's optical absorption has a maximum at the plasmon resonant frequency. Surface plasmon resonance can also be tuned based on the shape of the nanoparticle. The plasmon frequency can be related to the metal dielectric constant. The enhancement falls off quickly with distance from the surface and, for noble metal nanoparticles, the resonance occurs at visible wavelengths. Localized surface plasmon resonance creates brilliant colors in metal colloidal solutions.

Photonic molecules are a form of matter in which photons bind together to form "molecules". They were first predicted in 2007. Photonic molecules are formed when individual (massless) photons "interact with each other so strongly that they act as though they have mass". In an alternative definition, photons confined to two or more coupled optical cavities also reproduce the physics of interacting atomic energy levels, and have been termed as photonic molecules.

<span class="mw-page-title-main">Plasmonics</span>

Plasmonics or nanoplasmonics refers to the generation, detection, and manipulation of signals at optical frequencies along metal-dielectric interfaces in the nanometer scale. Inspired by photonics, plasmonics follows the trend of miniaturizing optical devices, and finds applications in sensing, microscopy, optical communications, and bio-photonics.

<span class="mw-page-title-main">Dieter Pohl (physicist)</span> German physicist

Dieter Pohl is a German–Swiss physicist. He became known especially for his pioneering works in nano-optics, near field optics (NFO), and plasmonics.

<span class="mw-page-title-main">Electromagnetic metasurface</span>

An electromagnetic metasurface refers to a kind of artificial sheet material with sub-wavelength thickness. Metasurfaces can be either structured or unstructured with subwavelength-scaled patterns in the horizontal dimensions.

Spoof surface plasmons, also known as spoof surface plasmon polaritons and designer surface plasmons, are surface electromagnetic waves in microwave and terahertz regimes that propagate along planar interfaces with sign-changing permittivities. Spoof surface plasmons are a type of surface plasmon polariton, which ordinarily propagate along metal and dielectric interfaces in infrared and visible frequencies. Since surface plasmon polaritons cannot exist naturally in microwave and terahertz frequencies due to dispersion properties of metals, spoof surface plasmons necessitate the use of artificially-engineered metamaterials.

Mark Stockman was a Soviet-born American physicist. He was a professor of physics and astronomy at Georgia State University. Best known for his contributions to plasmonics, Stockman has co-theorized plasmonic lasers, also known as spasers, in 2003.

References

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  25. ↑ Mehdi Tavakoli; Yousef Seyed Jalili; Seyed Mohammad Elahi (2019). "Rayleigh-Wood anomaly approximation with FDTD simulation of plasmonic gold nanohole array for determination of optimum extraordinary optical transmission characteristics". Superlattices and Microstructures. 130: 454–471. Bibcode:2019SuMi..130..454T. doi:10.1016/j.spmi.2019.04.035. S2CID   150365680.
  26. ↑ Lameirinhas, Ricardo A. Marques; N. Torres, Joao Paulo; Baptista, António; M. Martins, Maria Joao (2022). "A Novel Analysis for Light Patterns in Nano Structures". IEEE Photonics Journal. doi:10.1109/JPHOT.2022.3227429.
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