Fluorcarmoite-(BaNa)

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Fluorcarmoite-(BaNa)
General
Category Phosphate
Formula
(repeating unit)
Ba[]Na2Na2[]CaMg13Al(PO4)11(PO3OH)F2
IMA symbol Fcm-BaNa [1]
Crystal system Monoclinic
Crystal class Domatic (m)
(same H-M symbol)
Space group Cc
Unit cell a = 16.40, b = 9.95
c = 24.45 [Å]; β = 105.73° (approximated)
Identification
References [2] [3]

Fluorcarmoite-(BaNa) is a rare phosphate mineral, belonging to arrojadite group, with the formula Ba[]Na2Na2[]CaMg13Al(PO4)11(PO3OH)F2. [2] It is a barium-rich member of the group, as is arrojadite-(BaNa), arrojadite-(BaFe), fluorarrojadite-(BaFe) [3] and an unapproved species ferri-arrojadite-(BaNa). [4] The "-(BaNa)" suffix informs about the dominance of the particular elements (here barium and sodium) at the corresponding structural sites. [5]

Arrojadite group

The arrojadite group is defined in form of the complex, general formula A2B2CaNa2+xM13Al(PO4)11(PO3OH1−x)W2, where:

The two suffixes in the name correspond to A1 and B1 sites. Third suffix may be present in special cases. [6]

Related Research Articles

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<span class="mw-page-title-main">Phosphate mineral</span> Nickel–Strunz 9 ed mineral class number 8 (isolated tetrahedral units, mainly)

Phosphate minerals are minerals that contain the tetrahedrally coordinated phosphate anion, sometimes with arsenate and vanadate substitutions, along with chloride (Cl), fluoride (F), and hydroxide (OH) anions, that also fit into the crystal structure.

<span class="mw-page-title-main">Abenakiite-(Ce)</span> Cyclosilicate mineral

Abenakiite-(Ce) is a mineral of sodium, cerium, neodymium, lanthanum, praseodymium, thorium, samarium, oxygen, sulfur, carbon, phosphorus, and silicon with a chemical formula Na26Ce6(SiO3)6(PO4)6(CO3)6(S4+O2)O. The silicate groups may be given as the cyclic Si6O18 grouping. The mineral is named after the Abenaki, an Algonquian Indian tribe of New England. Its Mohs scale rating is 4 to 5.

<span class="mw-page-title-main">Gedrite</span>

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<span class="mw-page-title-main">Cyrilovite</span> Hydrous sodium iron phosphate mineral

Cyrilovite (NaFe33+(PO4)2(OH)4·2(H2O)) is a hydrous sodium iron phosphate mineral. It is isomorphous and isostructural with wardite, the sodium aluminium counterpart.

<span class="mw-page-title-main">Hureaulite</span> Manganese phosphate mineral

Hureaulite is a manganese phosphate with the formula Mn2+5(PO3OH)2(PO4)2·4H2O. It was discovered in 1825 and named in 1826 for the type locality, Les Hureaux, Saint-Sylvestre, Haute-Vienne, Limousin, France. It is sometimes written as huréaulite, but the IMA does not recommend this for English language text.

This list gives an overview of the classification of non-silicate minerals and includes mostly International Mineralogical Association (IMA) recognized minerals and its groupings. This list complements the List of minerals recognized by the International Mineralogical Association series of articles and List of minerals. Rocks, ores, mineral mixtures, not IMA approved minerals, not named minerals are mostly excluded. Mostly major groups only, or groupings used by New Dana Classification and Mindat.

This list gives an overview of the classification of minerals (silicates) and includes mostly International Mineralogical Association (IMA) recognized minerals and its groupings. This list complements the List of minerals recognized by the International Mineralogical Association series of articles and List of minerals. Rocks, ores, mineral mixtures, non-IMA approved minerals and non-named minerals are mostly excluded.

<span class="mw-page-title-main">Uranocircite</span>

Uranocircite or Uranocircite-II is a uranium mineral with the chemical formula: Ba(UO2)2(PO4)2·10H2O. Uranocircite-I was discredited (the IMA-CMNMC published 'The New IMA List of Minerals', September 2012). It is a phosphate mineral which contains barium and is a green to yellow colour. It has a Mohs hardness of about 2.

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<span class="mw-page-title-main">Hollandite</span> Barium manganese oxide mineral

Hollandite (chemical formula: Ba(Mn4+6Mn3+2)O16) is a manganese oxide mineral. Its structure consists of double chains of MnO6 octahedra delimiting 2 × 2 tunnels. The electrostatic charge created by the Mn3+ for Mn4+ substitution is balanced by cations in the tunnels. Their nature determines the mineral species: Ba for hollandite, K for cryptomelane, Pb for coronadite, Sr for strontiomelane, Tl for thalliomelane, and Na for manjiroite. Pure species are rare and most 2 × 2 tectomanganates contain mixtures of several types of tunnel cations.

<span class="mw-page-title-main">Zirsilite-(Ce)</span> Rare mineral of the eudialyte group

Zirsilite-(Ce) is a very rare mineral of the eudialyte group, with formula (Na,□)12(Ce,Na)3Ca6Mn3Zr3NbSi(Si9O27)2(Si3O9)2O(OH)3(CO3)·H2O. The original formula was extended to show the presence of cyclic silicate groups and the presence of silicon at the M4 site, according to the nomenclature of the eudialyte group. Zirsilite-(Ce) differs from carbokentbrooksite in cerium-dominance over sodium only. Both minerals are intimately associated. The only other currently known representative of the eudialyte group having rare earth elements (in particular cerium, as suggested by the "-Ce)" Levinson suffix in the name) in dominance is johnsenite-(Ce).

Dualite is a very rare and complex mineral of the eudialyte group, its complexity being expressed in its formula Na
30
(Ca,Na,Ce,Sr)
12
(Na,Mn,Fe,Ti)
6
Zr
3
Ti
3
MnSi
51
O
144
(OH,H
2
O,Cl)
9
. The formula is simplified as it does not show the presence of cyclic silicate groups. The name of the mineral comes from its dual nature: zircono- and titanosilicate at once. Dualite has two modules in its structure: alluaivite one and eudialyte one. After alluaivite and labyrinthite it stands for third representative of the eudialyte group with essential titanium.

Reederite-(Y) is a rare mineral with the formula (Na,Mn,Fe)15(Y,REE)2(CO3)9(SO3F)Cl. It is the only known mineral with fluorosulfate (fluorosulfonate). "REE" in the formula stands for rare earth elements other than yttrium, that is mostly cerium, with traces of neodymium, dysprosium, lanthanum and erbium. The formula also includes a Levinson suffix "-(Y)" pointing to the dominance of yttrium at the corresponding site. Reederite-(Y) crystallizes in the hexagonal crystal system with the space group P6, rarely seen among minerals.

Zadovite is an extremely rare mineral with formula BaCa6[(SiO4)(PO4)](PO4)2F. Together with its vanadium-analogue, aradite, zadovite occur in paralavas (type of pyrometamorphic rocks). Both minerals have structures similar to nabimusaite, and these three minerals occur in the Hatrurim Formation of Israel. Structure of all three minerals is related to that of hatrurite. Minerals combining barium, phosphorus and silicon together are scarce.

<span class="mw-page-title-main">Jinshajiangite</span> Rare silicate mineral

Jinshajiangite is a rare silicate mineral named after the Jinshajiang river in China. Its currently accepted formula is BaNaFe4Ti2(Si2O7)2O2(OH)2F. It gives a name of the jinshajiangite group. The mineral is associated with alkaline rocks. In jinshajiangite, there is a potassium-to-barium, calcium-to-sodium, manganese-to-iron and iron-to-titanium diadochy substitution. Jinshajiangite is the iron-analogue of surkhobite and perraultite. It is chemically related to bafertisite, cámaraite and emmerichite. Its structure is related to that of bafertisite. Jinshajiangite is a titanosilicate with heteropolyhedral HOH layers, where the H-layer is a mixed tetrahedral-octahedral layer, and the O-layer is simply octahedral.

Ferro-ferri-hornblende is an amphibole-supergroup mineral with the formula ☐Ca2(Fe2+4Fe3+)(Si7Al)O22(OH)2. It contains essential vacancy (☐). It was discovered in the Traversella mine, Canavese, Torino, Piedmont, Italy.

<span class="mw-page-title-main">Wilancookite</span> Very rare and complex beryllium phosphate

Wilancookite is a very rare and complex beryllium phosphate with the chemical formula (Ba,K,Na)8(Ba,Li,[ ])6Be24P24O96·32H2O. Wilancookite was discovered in pegmatite of the Lavra Ponte do Piauí complex, Jequitinhonha, Minas Gerais, Brazil.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Cámara, F., Bittarello, E., Ciriotti, M.E., Nestola, F., Radica, F., and Bracco, R., 2015. Fluorcarmoite-(BaNa), IMA 2015-062. CNMNCNewsletter No. 27, October 2015, 1229; Mineralogical Magazine 79, 1229–1236
  3. 1 2 "Fluorcarmoite-(BaNa): Fluorcarmoite-(BaNa) mineral information and data". Mindat.org. Retrieved 2016-03-12.
  4. "Ferri-arrojadite-(BaNa): Ferri-arrojadite-(BaNa) mineral information and data". Mindat.org. Retrieved 2016-03-12.
  5. Hatert, F., Mills, S.J., Pasero, M., and Williams, P.A., 2013. CNMNC guidelines for the use of suffixes and prefixes in mineral nomenclature, and for the preservation of historical names. European Journal of Mineralogy 25, 113-115
  6. Chopin, C., Oberti, R., and Cámara, F. 2006. The arrojadite enigma: II. Compositional space, new members and nomenclature of the group. American Mineralogist 91, 1260-1270.