Fluorcarmoite-(BaNa)

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Fluorcarmoite-(BaNa)
General
Category Phosphate
Formula
(repeating unit)		Ba[]Na2Na2[]CaMg13Al(PO4)11(PO3OH)F2
IMA symbol Fcm-BaNa [1]
Crystal system Monoclinic
Crystal class Domatic (m)
(same H-M symbol)
Space group Cc
Unit cell a = 16.40, b = 9.95
c = 24.45 [Å]; β = 105.73° (approximated)
Identification
References [2] [3]

Fluorcarmoite-(BaNa) is a rare phosphate mineral, belonging to arrojadite group, with the formula Ba[]Na2Na2[]CaMg13Al(PO4)11(PO3OH)F2. [2] It is a barium-rich member of the group, as is arrojadite-(BaNa), arrojadite-(BaFe), fluorarrojadite-(BaFe) [3] and an unapproved species ferri-arrojadite-(BaNa). [4] The "-(BaNa)" suffix informs about the dominance of the particular elements (here barium and sodium) at the corresponding structural sites. [5]

Arrojadite group

The arrojadite group is defined in form of the complex, general formula A2B2CaNa2+xM13Al(PO4)11(PO3OH1−x)W2, where:

The two suffixes in the name correspond to A1 and B1 sites. Third suffix may be present in special cases. [6]

Related Research Articles

<span class="mw-page-title-main">Glaucophane</span>

Glaucophane is the name of a mineral and a mineral group belonging to the sodic amphibole supergroup of the double chain inosilicates, with the chemical formula ☐Na2(Mg3Al2)Si8O22(OH)2.

<span class="mw-page-title-main">Phosphate mineral</span> Nickel–Strunz 9 ed mineral class number 8 (isolated tetrahedral units, mainly)

Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−) anion, sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions, along with chloride (Cl−), fluoride (F−), and hydroxide (OH−) anions, that also fit into the crystal structure.

<span class="mw-page-title-main">Apophyllite</span> Phyllosilicate mineral

The name apophyllite refers to a specific group of phyllosilicates, a class of minerals. Originally, the group name referred to a specific mineral, but was redefined in 1978 to stand for a class of minerals of similar chemical makeup that comprise a solid solution series, and includes the members fluorapophyllite-(K), fluorapophyllite-(Na), hydroxyapophyllite-(K). The name apophyllite is derived from the Greek ἀποφυλλίζω apophylliso, meaning "it flakes off", a reference to this class's tendency to flake apart when heated, due to water loss. Exfoliation of apophyllite is also possible by treating it with acids or simply by rubbing it. These minerals are typically found as secondary minerals in vesicles in basalt or other volcanic rocks. A recent change (2008) in the nomenclature system used for this group was approved by the International Mineralogical Association, removing the prefixes from the species names and using suffixes to designate the species. A subsequent nomenclature change approved by the International Mineralogical Association in 2013 renamed the minerals to include both suffixes and prefixes, as shown above.

<span class="mw-page-title-main">Chondrodite</span>

Chondrodite is a nesosilicate mineral with formula (Mg,Fe)
5(SiO
4)
2(F,OH,O)
2. Although it is a fairly rare mineral, it is the most frequently encountered member of the humite group of minerals. It is formed in hydrothermal deposits from locally metamorphosed dolomite. It is also found associated with skarn and serpentinite. It was discovered in 1817 at Pargas in Finland, and named from the Greek for "granule", which is a common habit for this mineral.

<span class="mw-page-title-main">Gedrite</span>

Gedrite is a crystal belonging to the orthorhombic ferromagnesian subgroup of the amphibole supergroup of the double chain inosilicate minerals with the ideal chemical formula Mg2(Mg3Al2)(Si6Al2)O22(OH)2.

<span class="mw-page-title-main">Alluaudite</span>

Alluaudite is a relatively common alkaline manganese iron phosphate mineral with the chemical formula (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3. It occurs as metasomatic replacement in granitic pegmatites and within phosphatic nodules in shales.

<span class="mw-page-title-main">Kaersutite</span> Calcic titanium bearing amphibole mineral

Kaersutite is a dark brown to black double chain calcic titanium bearing amphibole mineral with formula: NaCa2(Mg3Ti4+Al)(Si6Al2)O22(O)2.

<span class="mw-page-title-main">Woodhouseite</span>

Woodhouseite belongs to the beudantite group AB3(XO4)(SO4)(OH)6 where A = Ba, Ca, Pb or Sr, B = Al or Fe and X = S, As or P. Minerals in this group are isostructural with each other and also with minerals in the crandallite and alunite groups. They crystallise in the rhombohedral system with space group R3m and crystals are usually either tabular {0001} or pseudo-cubic to pseudo-cuboctahedral. Woodhouseite was named after Professor Charles Douglas Woodhouse (1888–1975), an American mineralogist and mineral collector from the University of California, Santa Barbara, US, and one-time General Manager of Champion Sillimanite, Inc.

<span class="mw-page-title-main">Zemannite</span>

Zemannite is a very rare oxide mineral with the chemical formula Mg0.5ZnFe3+[TeO3]3·4.5H2O. It crystallizes in the hexagonal crystal system and forms small prismatic brown crystals. Because of the rarity and small crystal size, zemannite has no applications and serves as a collector's item.

<span class="mw-page-title-main">Benstonite</span> Ba,Ca,Mg-mixed carbonate mineral

Benstonite is a mineral with formula Ba6Ca6Mg(CO3)13. Discovered in 1954, the mineral was described in 1961 and named after Orlando J. Benston (1901–1966).

<span class="mw-page-title-main">Hollandite</span>

Hollandite (chemical formula: Ba(Mn4+6Mn3+2)O16) is an oxide mineral. It is the barium-manganese (III) endmember of the coronadite group.

Dachiardite-K is a rare zeolite-group mineral with the formula K4(Si20Al4O48)•13H2O. It is the potassium-analogue of dachiardite-Ca and dachiardite-Na, as suggested by the suffix "-K".

<span class="mw-page-title-main">Jinshajiangite</span>

Jinshajiangite is a rare silicate mineral named after the Jinshajiang river in China. Its currently accepted formula is BaNaFe4Ti2(Si2O7)2O2(OH)2F. It gives a name of the jinshajiangite group. The mineral is associated with alkaline rocks. In jinshajiangite, there is a potassium-to-barium, calcium-to-sodium, manganese-to-iron and iron-to-titanium diadochy substitution. Jinshajiangite is the iron-analogue of surkhobite and perraultite. It is chemically related to bafertisite, cámaraite and emmerichite. Its structure is related to that of bafertisite. Jinshajiangite is a titanosilicate with heteropolyhedral HOH layers, where the H-layer is a mixed tetrahedral-octahedral layer, and the O-layer is simply octahedral.

Ferro-ferri-hornblende is an amphibole-supergroup mineral with the formula ☐Ca2(Fe2+4Fe3+)(Si7Al)O22(OH)2. It contains essential vacancy (☐). It was discovered in the Traversella mine, Canavese, Torino, Piedmont, Italy.

Maneckiite is a rare phosphate mineral with the formula(Na[])Ca2Fe2+2(Fe3+Mg)Mn2(PO4)6•2H2O. It was found in Michałkowa, Góry Sowie Block, Lower Silesia, Poland.

Wiklundite is a rare and complex arsenite-silicate mineral with the chemical formula Pb2(Mn2+,Zn)3(Fe3+,Mn2+)2(Mn2+,Mg)19(As3+O3)2(Si,As5+O4)6(OH)18Cl6. The mineral characterizes in a large c unit cell parameter. It was found in Långban, Sweden - a home for many rare and exotic minerals.

<span class="mw-page-title-main">Wilancookite</span> Very rare and complex beryllium phosphate

Wilancookite is a very rare and complex beryllium phosphate with the chemical formula (Ba,K,Na)8(Ba,Li,[ ])6Be24P24O96·32H2O. Wilancookite was discovered in pegmatite of the Lavra Ponte do Piauí complex, Jequitinhonha, Minas Gerais, Brazil.

References

  1. ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Cámara, F., Bittarello, E., Ciriotti, M.E., Nestola, F., Radica, F., and Bracco, R., 2015. Fluorcarmoite-(BaNa), IMA 2015-062. CNMNCNewsletter No. 27, October 2015, 1229; Mineralogical Magazine 79, 1229–1236
  3. 1 2 "Fluorcarmoite-(BaNa): Fluorcarmoite-(BaNa) mineral information and data". Mindat.org. Retrieved 2016-03-12.
  4. ↑ "Ferri-arrojadite-(BaNa): Ferri-arrojadite-(BaNa) mineral information and data". Mindat.org. Retrieved 2016-03-12.
  5. ↑ Hatert, F., Mills, S.J., Pasero, M., and Williams, P.A., 2013. CNMNC guidelines for the use of suffixes and prefixes in mineral nomenclature, and for the preservation of historical names. European Journal of Mineralogy 25, 113-115
  6. ↑ Chopin, C., Oberti, R., and Cámara, F. 2006. The arrojadite enigma: II. Compositional space, new members and nomenclature of the group. American Mineralogist 91, 1260-1270.


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