Forensic glass analysis is the application and analysis of glass to determine details about a crime. Glass evidence comes in many forms in various types of criminal cases. Glass can be analyzed to understand its origin using comparative analysis which may include measurements relating to physical match, refractive index, density and elemental analysis. It is also possible to analyze glass fractures to better understand the angle, direction and sequence of force as well as the projectile used.
Glass analysis is applicable to a wide range of forensic cases. In burglary or rape cases, window pane may be broken and analyzed. [1] In assaults, broken glass bottles may be found and analyzed in addition to glass fragments that may remain on clothing. [1] Glass analysis is also applicable to motor vehicle crashes, particularly hit and run cases, as glass from headlights can be analyzed. [1]
Depending on the form of the evidence, glass analysis can be collected in several ways. When possible, it is preferred that the entire item of evidence, such as a glass fragment or sweater with glass shards, is collected. [2] Glass evidence can also take on the form of trace evidence. In these cases, trace evidence lifters, forensic vacuums or tweezers can aid in the collection of the glass evidence. [2] Small glass fragments or shards can be secured in a pharmacist's fold and in an envelope. [2] It is also important that the location from where the glass was recovered is noted. [1] When it is suspected that an individual has small glass fragments on their person, their hair can be combed and caught on examination paper in an attempt to recover potential glass fragments. [1] In addition to combing the hair, the individual can remove their clothes on examination paper which can then be sealed and saved for examination at a later time. [1]
It is possible to compare multiple glass fragments using the techniques described below in order to understand if the glass fragments can be excluded as originating from the same source.
Two glass fragments may be physically matched with one another. This may exclude the glass fragments from having originated from a different source. [3]
The refractive index of a glass fragment may be determined and compared with that of another glass fragment in order to understand if they can be excluded from having originated from the same source. [3] The refractive index can be determined using immersion methods as well as automated methods. [3] Immersion methods entail the use of liquids with known refractive indices. The glass fragments are immersed in the liquids, often oils, and Becke lines are examined according to the Becke line test. [3] Automated methods entail a camera and computer which make measurements of glass fragments in varying temperatures. [3]
The density of a glass fragment can be determined using a density meter. [3] The density of a glass fragment will depend on the batch characteristics and composition. Although, density is tested less frequently than refractive indices, it can be used to determine if two glass fragments more likely originated from a different source. [3]
Many techniques can be used to understand the elemental composition of a glass fragment. Glass fragments from the same source have the same elemental composition and thus, elemental analysis enables an analyst to understand if multiple glass fragments likely do or do not originate from the same source.
There are many techniques that can be used for elemental analysis of glass. These include scanning electron microscopy-x-ray spectroscopy, x-ray fluorescence spectroscopy, mass spectrometry, optical emission spectroscopy and inductively coupled plasma methods. [4]
Glass fractures can be analyzed in order to determine which side of the glass was force applied that ultimately resulted in its fracture. For example, determining which side of a window was smashed in order to cause it to break may help crime scene investigators understand if someone broke in through the window or broke out through it. On the other hand, if there are multiple fractures on a pane of glass, they can be analyzed to determine what was the order in which the fractures were made. Analysis of glass fractures may also provide insight about the direction through which the projectile came from and may provide hints about what the projectile was that cause the fracture.
When a projectile, such as a rock or bullet, hits a pane of glass, radial and concentric fractures form. These are often the key components of glass fracture analysis.
When a high velocity projectile, such as a bullet, fractures a pane of glass, it can leave what is known as a cone fracture. [5] A cone fracture is a hole in a glass pane surrounded by radial and concentric fractures. The hole is narrower at the point of entry and widens towards the exit point, giving the appearance of a cone. [5]
The shape of the hole formed by a projectile may also give information about the angle through which the force was delivered. A symmetrical hole could be formed by a projectile hitting the glass at a 90-degree angle, while elliptical holes can be formed by projectiles hitting a pane of glass from the left or right side. [5]
The side from which a glass fracture was made can be determined by examining the radial fractures of a glass fracture. The 3R rule is used to make a determination about which direction a fracture was formed from. The 3R rule states "radial fractures make right angles to the rear." By examining the radial fractures and the direction in which they form a right angle, the rear side of the pane of glass (opposite the side the force was applied) can be determined.
When multiple fractures are made to a pane of glass, it is possible to understand the order in which those fractures were made by examining the radial fractures. Radial fractures end when they cross paths with another existing fracture line, thereby producing a method to understand the order in which multiple fractures were made. [5]
Forensic glass analysis research has been conducted for many years. The first forensic book published on analyzing glass was written by Hans Gross. [6] This book focused on exit, entry and the order of multiple bullet holes in glass for reconstruction purposes. [6] Gross' research was confirmed in 1931 by Matwejeff when he also conducted experiments similar to Gross' and his own. [6] From his own research, he was the first to show Wallner lines, also shown as conchoidal or rib lines. [6] The first case in forensic glass fragments analysis was published by Marris when glass fragments found tied a suspect to the crime scene. [6] Based on the work by Marris and Matwejeff, F.G Tryhorn also published writing in this field that explained examinations of glass including chemical composition. [6] Further research in this field was done by Nelson and Revell in 1967, followed by Coleman and Goode who used neutron activity for element analysis. [7]
Many research projects and government groups continue to update and strengthen the field of forensic glass analysis. [7] An example of a group is the Scientific Working Group on Materials (SWGMAT). [7] This group creates and creates analytical guild lines to improve glass analysis, beginning in the 1990s. [7] From laboratory trials to accepted methods, the field of forensic glass analysis is able to standardize emerging practices. [7]
Inductively coupled plasma mass spectrometry (ICP-MS) is a type of mass spectrometry that uses an inductively coupled plasma to ionize the sample. It atomizes the sample and creates atomic and small polyatomic ions, which are then detected. It is known and used for its ability to detect metals and several non-metals in liquid samples at very low concentrations. It can detect different isotopes of the same element, which makes it a versatile tool in isotopic labeling.
Gemology or gemmology is the science dealing with natural and artificial gemstone materials. It is a geoscience and a branch of Stoneology and mineralogy. Some jewelers are academically trained gemologists and are qualified to identify and evaluate gems.
In archaeology, in particular of the Stone Age, lithic reduction is the process of fashioning stones or rocks from their natural state into tools or weapons by removing some parts. It has been intensely studied and many archaeological industries are identified almost entirely by the lithic analysis of the precise style of their tools and the chaîne opératoire of the reduction techniques they used.
A ricochet is a rebound, bounce, or skip off a surface, particularly in the case of a projectile. Most ricochets are caused by accident and while the force of the deflection decelerates the projectile, it can still be energetic and almost as dangerous as before the deflection. The possibility of ricochet is one of the reasons for the common firearms safety rule "Never shoot a bullet at a flat, hard surface." Ricochets can occur with any caliber, but short or round ricocheting bullets may not produce the audible whine caused by tumbling irregular shapes. Ricochets are a hazard of shooting because, for as long as they retain sufficient velocity, ricocheting bullets or bullet fragments may cause collateral damage to animals, objects, or even the person who fired the shot.
Forensic linguistics, legal linguistics, or language and the law is the application of linguistic knowledge, methods, and insights to the forensic context of law, language, crime investigation, trial, and judicial procedure. It is a branch of applied linguistics.
Petrography is a branch of petrology that focuses on detailed descriptions of rocks. Someone who studies petrography is called a petrographer. The mineral content and the textural relationships within the rock are described in detail. The classification of rocks is based on the information acquired during the petrographic analysis. Petrographic descriptions start with the field notes at the outcrop and include macroscopic description of hand-sized specimens. The most important petrographer's tool is the petrographic microscope. The detailed analysis of minerals by optical mineralogy in thin section and the micro-texture and structure are critical to understanding the origin of the rock.
Trace evidence occurs when objects make contact, and material is transferred. This type of evidence is usually not visible to the naked eye and requires specific tools and techniques to be located and obtained. Due to this, trace evidence is often overlooked, and investigators must be trained to detect it. When it comes to an investigation trace evidence can come in many different forms and is found in a wide variety of cases. This evidence can link a victim to suspects and a victim or suspect to the crime scene.
A polarimeter is a scientific instrument used to measure optical rotation: the angle of rotation caused by passing linearly polarized light through an optically active substance.
A refractometer is a laboratory or field device for the measurement of an index of refraction (refractometry). The index of refraction is calculated from the observed refraction angle using Snell's law. For mixtures, the index of refraction then allows the concentration to be determined using mixing rules such as the Gladstone–Dale relation and Lorentz–Lorenz equation.
Optical mineralogy is the study of minerals and rocks by measuring their optical properties. Most commonly, rock and mineral samples are prepared as thin sections or grain mounts for study in the laboratory with a petrographic microscope. Optical mineralogy is used to identify the mineralogical composition of geological materials in order to help reveal their origin and evolution.
Crime reconstruction or crime scene reconstruction is the forensic science discipline in which one gains "explicit knowledge of the series of events that surround the commission of a crime using deductive and inductive reasoning, physical evidence, scientific methods, and their interrelationships". Gardner and Bevel explain that crime scene reconstruction "involves evaluating the context of a scene and the physical evidence found there in an effort to identify what occurred and in what order it occurred." Chisum and Turvey explain that "[h]olistic crime reconstruction is the development of actions and circumstances based on the system of evidence discovered and examined in relation to a particular crime. In this philosophy, all elements of evidence that come to light in a given case are treated as interdependent; the significance of each piece, each action, and each event falls and rises on the backs of the others."
Accident analysis is a process carried out in order to determine the cause or causes of an accident so as to prevent further accidents of a similar kind. It is part of accident investigation or incident investigation. These analyses may be performed by a range of experts, including forensic scientists, forensic engineers or health and safety advisers. Accident investigators, particularly those in the aircraft industry, are colloquially known as "tin-kickers". Health and safety and patient safety professionals prefer using the term "incident" in place of the term "accident". Its retrospective nature means that accident analysis is primarily an exercise of directed explanation; conducted using the theories or methods the analyst has to hand, which directs the way in which the events, aspects, or features of accident phenomena are highlighted and explained. These analyses are also invaluable in determining ways to prevent future incidents from occurring. They provide good insight by determining root causes, into what failures occurred that lead to the incident.
Fractography is the study of the fracture surfaces of materials. Fractographic methods are routinely used to determine the cause of failure in engineering structures, especially in product failure and the practice of forensic engineering or failure analysis. In material science research, fractography is used to develop and evaluate theoretical models of crack growth behavior.
Forensic photography may refer to the visual documentation of different aspects that can be found at a crime scene. It may include the documentation of the crime scene, or physical evidence that is either found at a crime scene or already processed in a laboratory. Forensic photography differs from other variations of photography because crime scene photographers usually have a very specific purpose for capturing each image. As a result, the quality of forensic documentation may determine the result of an investigation; in the absence of good documentation, investigators may find it impossible to conclude what did or did not happen.
Low-energy ion scattering spectroscopy (LEIS), sometimes referred to simply as ion scattering spectroscopy (ISS), is a surface-sensitive analytical technique used to characterize the chemical and structural makeup of materials. LEIS involves directing a stream of charged particles known as ions at a surface and making observations of the positions, velocities, and energies of the ions that have interacted with the surface. Data that is thus collected can be used to deduce information about the material such as the relative positions of atoms in a surface lattice and the elemental identity of those atoms. LEIS is closely related to both medium-energy ion scattering (MEIS) and high-energy ion scattering, differing primarily in the energy range of the ion beam used to probe the surface. While much of the information collected using LEIS can be obtained using other surface science techniques, LEIS is unique in its sensitivity to both structure and composition of surfaces. Additionally, LEIS is one of a very few surface-sensitive techniques capable of directly observing hydrogen atoms, an aspect that may make it an increasingly more important technique as the hydrogen economy is being explored.
Rutherford backscattering spectrometry (RBS) is an analytical technique used in materials science. Sometimes referred to as high-energy ion scattering (HEIS) spectrometry, RBS is used to determine the structure and composition of materials by measuring the backscattering of a beam of high energy ions (typically protons or alpha particles) impinging on a sample.
Forensic materials engineering, a branch of forensic engineering, focuses on the material evidence from crime or accident scenes, seeking defects in those materials which might explain why an accident occurred, or the source of a specific material to identify a criminal. Many analytical methods used for material identification may be used in investigations, the exact set being determined by the nature of the material in question, be it metal, glass, ceramic, polymer or composite. An important aspect is the analysis of trace evidence such as skid marks on exposed surfaces, where contact between dissimilar materials leaves material traces of one left on the other. Provided the traces can be analysed successfully, then an accident or crime can often be reconstructed. Another aim will be to determine the cause of a broken component using the technique of fractography.
Polymer characterization is the analytical branch of polymer science.
Detection of fire accelerants is the process that a fire investigator uses to determine if fire accelerants were used at a fire scene. This process involves a combination of both field work and laboratory analysis by fire investigators and chemists.
Mortuary archaeology is the study of human remains in their archaeological context. This is a known sub-field of bioarchaeology, which is a field that focuses on gathering important information based on the skeleton of an individual. Bioarchaeology stems from the practice of human osteology which is the anatomical study of skeletal remains. Mortuary archaeology, as well as the overarching field it resides in, aims to generate an understanding of disease, migration, health, nutrition, gender, status, and kinship among past populations. Ultimately, these topics help to produce a picture of the daily lives of past individuals. Mortuary archaeologists draw upon the humanities, as well as social and hard sciences to have a full understanding of the individual.
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