Gaussian broadening

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Gaussian broadening refers to broadening effects in spectral lines, these can be produced by Doppler broadening.

This effect is similar to Gaussian blur effect in image processing produced by convolution with the Gaussian function.

The term is named after Carl Friedrich Gauss.


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Spectral line shape describes the form of a feature, observed in spectroscopy, corresponding to an energy change in an atom, molecule or ion. This shape is also referred to as the spectral line profile. Ideal line shapes include Lorentzian, Gaussian and Voigt functions, whose parameters are the line position, maximum height and half-width. Actual line shapes are determined principally by Doppler, collision and proximity broadening. For each system the half-width of the shape function varies with temperature, pressure and phase. A knowledge of shape function is needed for spectroscopic curve fitting and deconvolution.