Statement of the theorem
Let
be an eigenstate of
with energy
and let the 'interacting' Hamiltonian be
, where
is a coupling constant and
the interaction term. We define a Hamiltonian
which effectively interpolates between
and
in the limit
and
. Let
denote the evolution operator in the interaction picture. The Gell-Mann and Low theorem asserts that if the limit as
of

exists, then
are eigenstates of
.
When applied to, say, the ground-state, the theorem does not guarantee that the evolved state will be a ground state. In other words, level crossing is not excluded.
Proof
As in the original paper, the theorem is typically proved making use of Dyson's expansion of the evolution operator. Its validity however extends beyond the scope of perturbation theory as has been demonstrated by Molinari. We follow Molinari's method here. Focus on
and let
. From Schrödinger's equation for the time-evolution operator

and the boundary condition
we can formally write

Focus for the moment on the case
. Through a change of variables
we can write

We now demonstrate that
.
Consider a g-independent operator
and its corresponding evolution operator
. We can write

Using the same technique with
, write the equation for
as

The uniqueness of solution implies the identification

Combining thees results, we obtain

This result can be combined with the Schrödinger equation and its adjoint

to obtain

The corresponding equation between
is the same. It can be obtained by pre-multiplying both sides with
, post-multiplying with
and making use of


The other case we are interested in, namely
can be treated in an analogous fashion and yields an additional minus sign in front of the commutator (we are not concerned here with the case where
have mixed signs). In summary, we obtain

We proceed for the negative-times case. For clarity, let
and 

Now using the definition of
we differentiate and eliminate derivatives
using the above expression, finding

where
. We can now let
as by assumption the
in left hand side is finite. We then clearly see that
is an eigenstate of
and the proof is complete.