Graphenated carbon nanotube

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SEM series of graphenated CNTs with varying foliate density SEM of carbon nanotubes with graphene foliates of varying density, deposited via microwave plasma enhanced CVD.tif
SEM series of graphenated CNTs with varying foliate density

Graphenated carbon nanotubes (G-CNTs) are a relatively new hybrid that combines graphitic foliates grown along the sidewalls of multiwalled or bamboo style carbon nanotubes (CNTs). Yu et al. [1] reported on "chemically bonded graphene leaves" growing along the sidewalls of CNTs. Stoner et al. [2] described these structures as "graphenated CNTs" and reported in their use for enhanced supercapacitor performance. Hsu et al. further reported on similar structures formed on carbon fiber paper, also for use in supercapacitor applications. [3] Pham et al. [4] [5] also reported a similar structure, namely "graphene-carbon nanotube hybrids", grown directly onto carbon fiber paper to form an integrated, binder free, high surface area conductive catalyst support for Proton Exchange Membrane Fuel Cells electrode applications with enhanced performance and durability. The foliate density can vary as a function of deposition conditions (e.g. temperature and time) with their structure ranging from few layers of graphene (< 10) to thicker, more graphite-like. [6]

The fundamental advantage of an integrated graphene-CNT structure is the high surface area three-dimensional framework of the CNTs coupled with the high edge density of graphene. Graphene edges provide significantly higher charge density and reactivity than the basal plane, but they are difficult to arrange in a three-dimensional, high volume-density geometry. CNTs are readily aligned in a high density geometry (i.e., a vertically aligned forest) [7] but lack high charge density surfaces—the sidewalls of the CNTs are similar to the basal plane of graphene and exhibit low charge density except where edge defects exist. Depositing a high density of graphene foliates along the length of aligned CNTs can significantly increase the total charge capacity per unit of nominal area as compared to other carbon nanostructures. [8]

Ismail et al. [9] investigated a continuous synthesis of bulk cotton-like (aerogel) structure of graphenated carbon nanotubes (G-CNTs) via floating catalyst chemical vapor deposition (FCCVD) method. They analysed how changes in the injection rate of the carbon source influenced G-CNTs formation. Their research revealed that an injection rate of 5 ml/h led to optimal synthesis, resulting in improved electrical conductivity and superior gas-sensing capabilities compared to traditional carbon nanotubes (CNTs). Abdullah et al [10] introduced grapeseed oil as a precursor for G-CNTs hybrids, synthesizing mesoporous three-dimensional (3D) G-CNT aerogels with unique morphological features, such as highly disordered multi-wall carbon nanotube (MWCNT) bundles rounded by graphene foliate structures. Yusuf et al [11] conducted a comparative study of G-CNTs as counter electrodes in dye-sensitized solar cells (DSSCs), demonstrating their superior electrical conductivity and catalytic activity compared to standard carbon nanotubes and even conventional platinum layers. Yusuf et al's investigation [12] also highlighted the excellent conductivity of G-CNT sheets, attributing it to their hybrid structure, which presents them as promising candidates to replace conventional platinum as counter electrodes in DSSCs.

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A carbon nanotube (CNT) is a tube made of carbon with a diameter in the nanometre range (nanoscale). They are one of the allotropes of carbon.

<span class="mw-page-title-main">Allotropes of carbon</span> Materials made only out of carbon

Carbon is capable of forming many allotropes due to its valency. Well-known forms of carbon include diamond and graphite. In recent decades, many more allotropes have been discovered and researched, including ball shapes such as buckminsterfullerene and sheets such as graphene. Larger-scale structures of carbon include nanotubes, nanobuds and nanoribbons. Other unusual forms of carbon exist at very high temperatures or extreme pressures. Around 500 hypothetical 3‑periodic allotropes of carbon are known at the present time, according to the Samara Carbon Allotrope Database (SACADA).

<span class="mw-page-title-main">Carbon nanofiber</span>

Carbon nanofibers (CNFs), vapor grown carbon fibers (VGCFs), or vapor grown carbon nanofibers (VGCNFs) are cylindrical nanostructures with graphene layers arranged as stacked cones, cups or plates. Carbon nanofibers with graphene layers wrapped into perfect cylinders are called carbon nanotubes.

<span class="mw-page-title-main">Buckypaper</span> Thin sheet made of aggregated carbon nanotubes

Buckypaper is a thin sheet made from an aggregate of carbon nanotubes or carbon nanotube grid paper. The nanotubes are approximately 50,000 times thinner than a human hair. Originally, it was fabricated as a way to handle carbon nanotubes, but it is also being studied and developed into applications by several research groups, showing promise as vehicle armor, personal armor, and next-generation electronics and displays.

<span class="mw-page-title-main">Nanocomposite</span> Solid material with nano-scale structure

Nanocomposite is a multiphase solid material where one of the phases has one, two or three dimensions of less than 100 nanometers (nm) or structures having nano-scale repeat distances between the different phases that make up the material.

<span class="mw-page-title-main">Potential applications of carbon nanotubes</span>

Carbon nanotubes (CNTs) are cylinders of one or more layers of graphene (lattice). Diameters of single-walled carbon nanotubes (SWNTs) and multi-walled carbon nanotubes (MWNTs) are typically 0.8 to 2 nm and 5 to 20 nm, respectively, although MWNT diameters can exceed 100 nm. CNT lengths range from less than 100 nm to 0.5 m.

<span class="mw-page-title-main">Nanobatteries</span> Type of battery

Nanobatteries are fabricated batteries employing technology at the nanoscale, particles that measure less than 100 nanometers or 10−7 meters. These batteries may be nano in size or may use nanotechnology in a macro scale battery. Nanoscale batteries can be combined to function as a macrobattery such as within a nanopore battery.

<span class="mw-page-title-main">Carbon nanobud</span> Synthetic allotrope of carbon combining carbon nanotube and a fullerene

In nanotechnology, a carbon nanobud is a material that combines carbon nanotubes and spheroidal fullerenes, both allotropes of carbon, forming "buds" attached to the tubes. Carbon nanobuds were discovered and synthesized in 2006.

Organic photovoltaic devices (OPVs) are fabricated from thin films of organic semiconductors, such as polymers and small-molecule compounds, and are typically on the order of 100 nm thick. Because polymer based OPVs can be made using a coating process such as spin coating or inkjet printing, they are an attractive option for inexpensively covering large areas as well as flexible plastic surfaces. A promising low cost alternative to conventional solar cells made of crystalline silicon, there is a large amount of research being dedicated throughout industry and academia towards developing OPVs and increasing their power conversion efficiency.

<span class="mw-page-title-main">Transparent conducting film</span> Optically transparent and electrically conductive material

Transparent conducting films (TCFs) are thin films of optically transparent and electrically conductive material. They are an important component in a number of electronic devices including liquid-crystal displays, OLEDs, touchscreens and photovoltaics. While indium tin oxide (ITO) is the most widely used, alternatives include wider-spectrum transparent conductive oxides (TCOs), conductive polymers, metal grids and random metallic networks, carbon nanotubes (CNT), graphene, nanowire meshes and ultra thin metal films.

The exceptional electrical and mechanical properties of carbon nanotubes have made them alternatives to the traditional electrical actuators for both microscopic and macroscopic applications. Carbon nanotubes are very good conductors of both electricity and heat, and are also very strong and elastic molecules in certain directions. These properties are difficult to find in the same material and very needed for high performance actuators. For current carbon nanotube actuators, multi-walled carbon nanotubes (MWNTs) and bundles of MWNTs have been widely used mostly due to the easiness of handling and robustness. Solution dispersed thick films and highly ordered transparent films of carbon nanotubes have been used for the macroscopic applications.

<span class="mw-page-title-main">Single-walled carbon nanohorn</span>

Single-walled carbon nanohorn is the name given by Sumio Iijima and colleagues in 1999 to horn-shaped sheath aggregate of graphene sheets. Very similar structures had been observed in 1994 by Peter J.F. Harris, Edman Tsang, John Claridge and Malcolm Green. Ever since the discovery of the fullerene, the family of carbon nanostructures has been steadily expanded. Included in this family are single-walled and multi-walled carbon nanotubes, carbon onions and cones and, most recently, SWNHs. These SWNHs with about 40–50 nm in tubule length and about 2–3 nm in diameter are derived from SWNTs and ended by a five-pentagon conical cap with a cone opening angle of ~20o. Moreover, thousands of SWNHs associate with each other to form the ‘dahlia-like' and ‘bud-like’ structured aggregates which have an average diameter of about 80–100 nm. The former consists of tubules and graphene sheets protruding from its surface like petals of a dahlia, while the latter is composed of tubules developing inside the particle itself. Their unique structures with high surface area and microporosity make SWNHs become a promising material for gas adsorption, biosensing, drug delivery, gas storage and catalyst support for fuel cell. Single-walled carbon nanohorns are an example of the family of carbon nanocones.

<span class="mw-page-title-main">Carbon nanotube supported catalyst</span> Novel catalyst using carbon nanotubes as the support instead of the conventional alumina

Carbon nanotube supported catalyst is a novel supported catalyst, using carbon nanotubes as the support instead of the conventional alumina or silicon support. The exceptional physical properties of carbon nanotubes (CNTs) such as large specific surface areas, excellent electron conductivity incorporated with the good chemical inertness, and relatively high oxidation stability makes it a promising support material for heterogeneous catalysis.

<span class="mw-page-title-main">Supercapacitor</span> High-capacity electrochemical capacitor

A supercapacitor (SC), also called an ultracapacitor, is a high-capacity capacitor, with a capacitance value much higher than solid-state capacitors but with lower voltage limits. It bridges the gap between electrolytic capacitors and rechargeable batteries. It typically stores 10 to 100 times more energy per unit volume or mass than electrolytic capacitors, can accept and deliver charge much faster than batteries, and tolerates many more charge and discharge cycles than rechargeable batteries.

<span class="mw-page-title-main">Aerographite</span> Extremely light synthetic foam of tubular carbon molecules

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Potential graphene applications include lightweight, thin, and flexible electric/photonics circuits, solar cells, and various medical, chemical and industrial processes enhanced or enabled by the use of new graphene materials.

<span class="mw-page-title-main">Aerogel</span> Synthetic ultralight solid material

Aerogels are a class of synthetic porous ultralight material derived from a gel, in which the liquid component for the gel has been replaced with a gas, without significant collapse of the gel structure. The result is a solid with extremely low density and extremely low thermal conductivity. Aerogels can be made from a variety of chemical compounds. Silica aerogels feel like fragile styrofoam to the touch, while some polymer-based aerogels feel like rigid foams.

In materials science, vertically aligned carbon nanotube arrays (VANTAs) are a unique microstructure consisting of carbon nanotubes oriented with their longitudinal axis perpendicular to a substrate surface. These VANTAs effectively preserve and often accentuate the unique anisotropic properties of individual carbon nanotubes and possess a morphology that may be precisely controlled. VANTAs are consequently widely useful in a range of current and potential device applications.

A graphene morphology is any of the structures related to, and formed from, single sheets of graphene. 'Graphene' is typically used to refer to the crystalline monolayer of the naturally occurring material graphite. Due to quantum confinement of electrons within the material at these low dimensions, small differences in graphene morphology can greatly impact the physical and chemical properties of these materials. Commonly studied graphene morphologies include the monolayer sheets, bilayer sheets, graphene nanoribbons and other 3D structures formed from stacking of the monolayer sheets.

Porous carbons (PCs) are versatile materials with a wide range of applications, including sensors, actuators, thermal insulation, and energy conversion. Some examples of PCs are graphene and carbon nanotube-based aerogel. Physical properties that make PCs unique are their low density, high conductivity, mechanical flexibility, and stability in extreme environments.

References

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  9. Ismail, Ismayadi; Mamat, Md Shuhazlly; Adnan, Noor Lyana; Yunusa, Zainab; Hasan, Intan Helina (2019-10-14). "Novel 3-Dimensional Cotton-Like Graphenated-Carbon Nanotubes Synthesized via Floating Catalyst Chemical Vapour Deposition Method for Potential Gas-Sensing Applications". Journal of Nanomaterials. 2019: e5717180. doi: 10.1155/2019/5717180 . ISSN   1687-4110.
  10. Abdullah, Hayder Baqer; Irmawati, Ramli; Ismail, Ismayadi; Zaidi, Muhammad Azizan; Abdullah, Ahmad Aimanuddin Amzar (2021-11-11). "Synthesis and morphological study of graphenated carbon nanotube aerogel from grapeseed oil". Journal of Nanoparticle Research. 23 (11): 244. Bibcode:2021JNR....23..244A. doi:10.1007/s11051-021-05363-6. ISSN   1572-896X.
  11. Yusuf, 11) Yusnita (2021). "A Comparative Study of Graphenated-Carbon Nanotubes Cotton and Carbon Nanotubes As Catalysts For Counter Electrode In Dye-Sensitized Solar Cells". Malaysian Journal of Microscopy. 17 (2): 162–174.{{cite journal}}: CS1 maint: numeric names: authors list (link)
  12. Yusuf, Yusnita; Shafie, Suhaidi; Ismail, Ismayadi; Ahmad, Fauzan; Hamidon, Mohd Nizar; Sudhir, Pandey Shyam; Wei, Lei (2023-03-31). "Highly Conductive Graphenated-Carbon Nanotubes Sheet with Graphene Foliates for Counter Electrode Application in Dye-Sensitized Solar Cells". Pertanika Journal of Science and Technology. 31 (3): 1325–1333. doi:10.47836/pjst.31.3.12. ISSN   2231-8526.