Greenockite

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Greenockite
Greenockite-259580.jpg
Greenockite crystals from Tsumeb Mine, Namibia (Picture width 1 mm)
General
Category Sulfide mineral
Formula CdS
IMA symbol Gnk [1]
Strunz classification 2.CB.45
Crystal system Hexagonal
Crystal class Dihexagonal pyramidal (6mm)
(same H-M symbol)
Space group P63mc
Unit cell a = 4.136
c = 6.713 [Å]; Z = 2
Structure
Jmol (3D) Interactive image
Identification
Formula mass 144.48
ColorHoney yellow, citron yellow, orange yellow
Crystal habit Colloform – forming from a gel or colloidal mass; encrustations – forms crust-like aggregates on matrix; radial – crystals radiate from a center without producing stellar forms (e.g. stibnite)
Twinning Rare on {1122} forming trillings
Cleavage Distinct on {1122}, imperfect on {0001}
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness3.0–3.5
Luster Adamantine to resinous
Streak Yellow orange to brick red
Diaphaneity Nearly opaque to translucent
Specific gravity 4.8–4.9
Optical propertiesUniaxial (−)
Refractive index nω = 2.529 nε = 2.506
Birefringence δ = 0.023
Pleochroism Weak
Ultraviolet fluorescence yellow-orange fluorescence under UV when rich in zinc[ citation needed ]
Other characteristicsToxic
References [2] [3] [4]

Greenockite, also cadmium blende or cadmium ochre (obsolete) is a rare cadmium bearing metal sulfide mineral consisting of cadmium sulfide (CdS) in crystalline form. Greenockite crystallizes in the hexagonal system. It occurs as massive encrustations and as hemimorphic six-sided pyramidal crystals which vary in color from a honey yellow through shades of red to brown. The Mohs hardness is 3 to 3.5 and the specific gravity is 4.8 to 4.9.

Contents

Greenockite belongs to the wurtzite group and is isostructural with it at high temperatures. It is also isostructural with sphalerite at low temperatures. It occurs with other sulfide minerals such as sphalerite and galena, and is the only ore mineral of cadmium. Most cadmium is recovered as a byproduct of copper, zinc, and lead mining. It is also known from the lead-zinc districts of the central United States.

It was first recognized in 1840 in Bishopton, Scotland, during the cutting of a tunnel for the Glasgow, Paisley and Greenock Railway. The mineral was named after the land owner Lord Greenock (1783–1859). [3] [5]

Use

Greenockite, also known as "cadmium ochre", was used as a yellow pigment prior to cadmium being recognized as a toxic element. The extracted cadmium has various industrial use, such as electrical nickel-cadmium (NiCd) rechargeable batteries, electroplating, high temp alloys, plating steel and other metals that corrode easily, and use in control rods for some nuclear reactors.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Handbook of Mineralogy
  3. 1 2 Mindat
  4. Webmineral
  5. "Glasgow museum site". Archived from the original on 2012-07-16. Retrieved 2005-08-02.
Crystal structure of greenockite Greenockite-3D-balls.png
Crystal structure of greenockite