Groutite | |
---|---|
General | |
Category | Oxide mineral |
Formula (repeating unit) | Mn3+O(OH) |
IMA symbol | Gro [1] |
Strunz classification | 4.FD.10 |
Crystal system | Orthorhombic |
Crystal class | Dipyramidal (mmm) H-M symbol: (2/m 2/m 2/m) |
Space group | Pbnm |
Unit cell | a = 4.56, b = 10.7 c = 2.87 [Å]; Z = 4 |
Identification | |
Color | Jet-black |
Crystal habit | Wedge or lens-shaped crystals; acicular, striated prisms |
Twinning | Reported, unknown law |
Cleavage | Perfect on {010}; less perfect on {100} |
Fracture | Uneven |
Tenacity | Brittle |
Mohs scale hardness | 3.5 - 4.0 |
Luster | Brilliant submetallic to adamantine |
Streak | Dark brown |
Diaphaneity | Opaque |
Specific gravity | 4.144 |
Optical properties | Biaxial (+) |
Refractive index | nα = 2.100 - 2.200 nγ = 2.100 |
Pleochroism | Very strong; X = very dark brown to black; Y = yellowish brown |
2V angle | Measured: 40° to 50° |
References | [2] [3] [4] |
Groutite is a manganese oxide mineral with formula Mn3+O(OH). It is a member of the diaspore group and is trimorphous with manganite and feitknechtite. It forms lustrous black crystals in the orthorhombic system.
It occurs in weathered banded iron formations, metamorphosed manganese ore bodies and hydrothermal ore environments. [2] It was first described in 1945 for an occurrence in the Mahnomen mine, Cuyuna Range, Crow Wing County, Minnesota and named for petrologist Frank Fitch Grout (1880–1958), of the University of Minnesota. [4]
Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6. It crystallizes in the trigonal system, and cleaves with rhombohedral carbonate cleavage in three directions. The crystal structure of rhodochrosite is a rhombohedral system, which is a subset of the trigonal system. The carbonate ions (CO3) are arranged in a triangular planar configuration, and the manganese ions (Mn) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octahedra and CO3 triangles are linked together to form a three-dimensional structure. Crystal twinning often is present. It is often confused with the manganese silicate, rhodonite, but is distinctly softer. Rhodochrosite is formed by the oxidation of manganese ore, and is found in South Africa, China, and the Americas. It is officially listed as one of the National symbols of Argentina.
Smithsonite, also known as zinc spar, is the mineral form of zinc carbonate (ZnCO3). Historically, smithsonite was identified with hemimorphite before it was realized that they were two different minerals. The two minerals are very similar in appearance and the term calamine has been used for both, leading to some confusion. The distinct mineral smithsonite was named in 1832 by François Sulpice Beudant in honor of English chemist and mineralogist James Smithson (c.1765–1829), who first identified the mineral in 1802.
Pyrolusite is a mineral consisting essentially of manganese dioxide (MnO2) and is important as an ore of manganese. It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers. The specific gravity is about 4.8. Its name is from the Greek for fire and to wash, in reference to its use as a way to remove tints from glass.
Manganite is a mineral composed of manganese oxide-hydroxide, MnO(OH), crystallizing in the monoclinic system (pseudo-orthorhombic). Crystals of manganite are prismatic and deeply striated parallel to their length; they are often grouped together in bundles. The color is dark steel-grey to iron-black, and the luster brilliant and submetallic. The streak is dark reddish brown. The hardness is 4, and the specific gravity is 4.3. There is a perfect cleavage parallel to the brachypinacoid, and less-perfect cleavage parallel to the prism faces. Twinned crystals are not infrequent.
Rhodonite is a manganese inosilicate, with the formula (Mn, Fe, Mg, Ca)SiO3, and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (its name comes from Ancient Greek ῥόδον (rhódon) 'rose'), often tending to brown due to surface oxidation. The rose-red hue is caused by the manganese cation (Mn2+).
The mineral group tantalite [(Fe, Mn)Ta2O6] is the primary source of the chemical element tantalum, a corrosion (heat and acid) resistant metal. It is chemically similar to columbite, and the two are often grouped together as a semi-singular mineral called coltan or "columbite-tantalite" in many mineral guides. However, tantalite has a much greater specific gravity than columbite (8.0+ compared to columbite's 5.2). Iron-rich tantalite is the mineral tantalite-(Fe) or ferrotantalite and manganese-rich is tantalite-(Mn) or manganotantalite.
Tephroite is the manganese endmember of the olivine group of nesosilicate minerals with the formula Mn2SiO4. A solid solution series exists between tephroite and its analogues, the group endmembers fayalite and forsterite. Divalent iron or magnesium may readily replace manganese in the olivine crystal structure.
Adamite is a zinc arsenate hydroxide mineral, Zn2AsO4OH. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with copper substitutions in the mineral structure. Olivenite is a copper arsenate that is isostructural with adamite and there is considerable substitution between zinc and copper resulting in an intermediate called cuproadamite. Zincolivenite is a recently discovered mineral being an intermediate mineral with formula CuZn(AsO4)(OH). Manganese, cobalt, and nickel also substitute in the structure. An analogous zinc phosphate, tarbuttite, is known.
Ferberite is the iron endmember of the manganese - iron wolframite solid solution series. The manganese endmember is hübnerite. Ferberite is a black monoclinic mineral composed of iron(II) tungstate, FeWO4.
Tokyoite is a rare barium manganese vanadate mineral with the chemical formula: Ba2(Mn3+,Fe3+)OH(VO4)2. It is the manganese analogue of the iron rich gamagarite and the barium analogue of the lead vanadate, brackebuschite.
Childrenite is a rare hydrated phosphate mineral with elements iron, manganese, aluminium, phosphorus, oxygen and hydrogen. Its chemical formula is (Fe2+
,Mn)2+
AlPO
4(OH)
2•H
2O and it has a molecular weight of 229.83 g/mol. Its specific gravity is 3.2 and it has a Mohs hardness of 4.5 to 5. It is usually translucent and non-fluorescent, with imperfect cleavage. It has a vitreous lustre with a white streak, and is brown or yellow in color. It has a conchoidal, uneven fracture, and an orthorhombic crystal system.
Galaxite, also known as 'mangan-spinel' is an isometric mineral belonging to the spinel group of oxides with the ideal chemical formula Mn2+Al2O4.
Geigerite is a mineral, a complex hydrous manganese arsenate with formula: Mn5(AsO3OH)2(AsO4)2·10H2O. It forms triclinic pinacoidal, vitreous, colorless to red to brown crystals. It has a Mohs hardness of 3 and a specific gravity of 3.05.
Piemontite is a sorosilicate mineral in the monoclinic crystal system with the chemical formula Ca2(Al,Mn3+,Fe3+)3(SiO4)(Si2O7)O(OH). It is a member of the epidote group.
Allactite is a rare arsenate mineral of metamorphosed manganese zinc ore deposits. It is found in Sweden and New Jersey, US. Its name originated from Greek αλλάκτειν (allaktein) meaning "to change", referring to the strong pleochroism of the mineral.
Pyroxmangite has the general chemical formula of MnSiO3. It is the high-pressure, low-temperature dimorph of rhodonite.
Nambulite is a lithium bearing manganese silicate mineral with the chemical formula (Li,Na)Mn4Si5O14(OH). It is named after the mineralogist, Matsuo Nambu (born 1917) of Tohoko University, Japan, who is known for his research in manganese minerals. The mineral was first discovered in the Funakozawa Mine of northeastern Japan, a metasedimentary manganese ore.
Sonolite is a mineral with formula Mn9(SiO4)4(OH,F)2. The mineral was discovered in 1960 in the Sono mine in Kyoto Prefecture, Japan. In 1963, it was identified as a new mineral and named after the Sono mine.
Sarkinite, synonymous with chondrarsenite and polyarsenite, is a mineral with formula Mn2(AsO4)(OH). The mineral is named for the Greek word σάρκιυος, meaning made of flesh, for its red color and greasy luster. The mineral was first noted in Sweden in 1865 as chondrarsenite, though not identified as sarkinite until 1885.
Manganvesuvianite is a rare mineral with formula Ca19Mn3+(Al,Mn3+,Fe3+)10(Mg,Mn2+)2(Si2O7)4(SiO4)10O(OH)9. The mineral is red to nearly black in color. Discovered in South Africa and described in 2002, it was so named for the prevalence of manganese in its composition and its relation to vesuvianite.