The term heterostrain was proposed in 2018 in the context of materials science to simplify the designation of possible strain situations in van der Waals heterostructures where two (or more) two-dimensional materials are stacked on top of each other. [1] These layers can experience the same deformation (homostrain) or different deformations (heterostrain). In addition to twist, heterostrain can have important consequences on the electronic [2] [3] and optical [4] properties of the resulting structure. As such, the control of heterostrain [5] [6] is emerging as a sub-field of straintronics in which the properties of 2D materials are controlled by strain. Recent works have reported a deterministic control of heterostrain by sample processing [7] or with the tip of an AFM [8] of particular interest in twisted heterostructures. Heterostrain alone (without twist) has also been identified as a parameter to tune the electronic properties of van der Waals structures as for example in twisted graphene layers with biaxial heterostrain. [9]
Heterostrain is constructed from the Greek prefix hetero- (different) and the noun strain. It means that the two layers constituting the structure are subject to different strains. [1] This is in contrast with homostrain in which the two layers as subject to the same strain. [1] Heterostrain is designated as "relative strain" by some authors. [10]
For simplicity, the case of two graphene layers is considered. The description can be generalized for the case of different 2D materials forming an heterostructure.
In nature, the two graphene layers usually stack with a shift of half a unit cell. This configuration is the most energetically favorable and is found in graphite. If one layer is strained while the other is left intact, a moiré pattern signaling the regions where the atomic lattices of the two layers are in or out of registry. The shape of the moiré pattern depends on the type of strain.
In General, a layer can be deformed by an arbitrary combination of both types of heterostrain.
Heterostrain can be measured by scanning tunneling microscope which provides images showing both the atomic lattice of the first layer and the moiré superlattice. Relating the atomic lattice to the moiré lattice allows to determine entirely the relative arrangement of the layers (biaxial, uniaxial heterostrain and twist). [11] The method is immune to calibration artifacts which affect the image of the two layers identically which cancels out in the relative measurement. Alternatively, with a well calibrated microscope and if biaxial heterostrain is low enough, it is possible to determine twist and uniaxial heterostrain from the knowledge of the moiré period in all directions. [12] On the contrary it is much more difficult to determine homostrain which necessitates a calibration sample.
Heterostrain is generated during the fabrication of the 2D materials stack. It can result from a meta-stable configuration during bottom up assembly [1] or from the layer manipulation in the tear and stack technique. [13] It has been shown to be ubiquitous in twisted graphene layers near the magic twist angle and to be the main factor in the flat band width of those systems. [2] [3] Heterostrain has a much larger impact on electronic properties than homostrain. [1] It explains some of the sample variability which had previously been puzzeling. [3] [14] Research is now moving towards understanding the impact of spatial fluctuations of heterostrain. [15]
In mathematics and physics, a soliton is a nonlinear, self-reinforcing, localized wave packet that is strongly stable, in that it preserves its shape while propagating freely, at constant velocity, and recovers it even after collisions with other such localized wave packets. Its remarkable stability can be traced to a balanced cancellation of nonlinear and dispersive effects in the medium. Solitons were subsequently found to provide stable solutions of a wide class of weakly nonlinear dispersive partial differential equations describing physical systems.
In mathematics, physics, and art, moiré patterns or moiré fringes are large-scale interference patterns that can be produced when a partially opaque ruled pattern with transparent gaps is overlaid on another similar pattern. For the moiré interference pattern to appear, the two patterns must not be completely identical, but rather displaced, rotated, or have slightly different pitch.
A superlattice is a periodic structure of layers of two materials. Typically, the thickness of one layer is several nanometers. It can also refer to a lower-dimensional structure such as an array of quantum dots or quantum wells.
A Wigner crystal is the solid (crystalline) phase of electrons first predicted by Eugene Wigner in 1934. A gas of electrons moving in a uniform, inert, neutralizing background will crystallize and form a lattice if the electron density is less than a critical value. This is because the potential energy dominates the kinetic energy at low densities, so the detailed spatial arrangement of the electrons becomes important. To minimize the potential energy, the electrons form a bcc lattice in 3D, a triangular lattice in 2D and an evenly spaced lattice in 1D. Most experimentally observed Wigner clusters exist due to the presence of the external confinement, i.e. external potential trap. As a consequence, deviations from the b.c.c or triangular lattice are observed. A crystalline state of the 2D electron gas can also be realized by applying a sufficiently strong magnetic field. However, it is still not clear whether it is the Wigner crystallization that has led to observation of insulating behaviour in magnetotransport measurements on 2D electron systems, since other candidates are present, such as Anderson localization.
A topological insulator is a material whose interior behaves as an electrical insulator while its surface behaves as an electrical conductor, meaning that electrons can only move along the surface of the material.
Silicene is a two-dimensional allotrope of silicon, with a hexagonal honeycomb structure similar to that of graphene. Contrary to graphene, silicene is not flat, but has a periodically buckled topology; the coupling between layers in silicene is much stronger than in multilayered graphene; and the oxidized form of silicene, 2D silica, has a very different chemical structure from graphene oxide.
Bilayer graphene is a material consisting of two layers of graphene. One of the first reports of bilayer graphene was in the seminal 2004 Science paper by Geim and colleagues, in which they described devices "which contained just one, two, or three atomic layers"
Transition-metal dichalcogenide (TMD or TMDC) monolayers are atomically thin semiconductors of the type MX2, with M a transition-metal atom (Mo, W, etc.) and X a chalcogen atom (S, Se, or Te). One layer of M atoms is sandwiched between two layers of X atoms. They are part of the large family of so-called 2D materials, named so to emphasize their extraordinary thinness. For example, a MoS2 monolayer is only 6.5 Å thick. The key feature of these materials is the interaction of large atoms in the 2D structure as compared with first-row transition-metal dichalcogenides, e.g., WTe2 exhibits anomalous giant magnetoresistance and superconductivity.
In materials science, the term single-layer materials or 2D materials refers to crystalline solids consisting of a single layer of atoms. These materials are promising for some applications but remain the focus of research. Single-layer materials derived from single elements generally carry the -ene suffix in their names, e.g. graphene. Single-layer materials that are compounds of two or more elements have -ane or -ide suffixes. 2D materials can generally be categorized as either 2D allotropes of various elements or as compounds.
Band-gap engineering is the process of controlling or altering the band gap of a material. This is typically done to semiconductors by controlling the composition of alloys, constructing layered materials with alternating compositions, or by inducing strain either epitaxially or topologically. A band gap is the range in a solid where no electron state can exist. The band gap of insulators is much larger than in semiconductors. Conductors or metals have a much smaller or nonexistent band gap than semiconductors since the valence and conduction bands overlap. Controlling the band gap allows for the creation of desirable electrical properties.
A two-dimensional semiconductor is a type of natural semiconductor with thicknesses on the atomic scale. Geim and Novoselov et al. initiated the field in 2004 when they reported a new semiconducting material graphene, a flat monolayer of carbon atoms arranged in a 2D honeycomb lattice. A 2D monolayer semiconductor is significant because it exhibits stronger piezoelectric coupling than traditionally employed bulk forms. This coupling could enable applications. One research focus is on designing nanoelectronic components by the use of graphene as electrical conductor, hexagonal boron nitride as electrical insulator, and a transition metal dichalcogenide as semiconductor.
A rapidly increasing list of graphene production techniques have been developed to enable graphene's use in commercial applications.
Dirac cones, named after Paul Dirac, are features that occur in some electronic band structures that describe unusual electron transport properties of materials like graphene and topological insulators. In these materials, at energies near the Fermi level, the valence band and conduction band take the shape of the upper and lower halves of a conical surface, meeting at what are called Dirac points.
Eva Yocheved Andrei is an American condensed matter physicist, currently a Distinguished Professor and Board of Governors Professor at Rutgers University. Her research focuses on emergent properties of matter arising from collective behavior of many particles, especially low-dimensional phenomena under low temperatures and high magnetic fields.
Twistronics is the study of how the angle between layers of two-dimensional materials can change their electrical properties. Materials such as bilayer graphene have been shown to have vastly different electronic behavior, ranging from non-conductive to superconductive, that depends sensitively on the angle between the layers. The term was first introduced by the research group of Efthimios Kaxiras at Harvard University in their theoretical treatment of graphene superlattices.
Pablo Jarillo-Herrero is a Spanish physicist and current Cecil and Ida Green Professor of Physics at Massachusetts Institute of Technology (MIT).
Antonio Helio de Castro Neto is a Brazilian-born physicist. He is the founder and director of the Centre for Advanced 2D Materials at the National University of Singapore. He is a condensed matter theorist known for his work in the theory of metals, magnets, superconductors, graphene and two-dimensional materials. He is a distinguished professor in the Departments of Materials Science Engineering, and Physics and a professor at the Department of Electrical and Computer Engineering. He was elected as a fellow of the American Physical Society in 2003. In 2011 he was elected as a fellow of the American Association for the Advancement of Science.
Straintronics is the study of how folds and mechanically induced stresses in a layer of two-dimensional materials can change their electrical properties. It is distinct from twistronics in that the latter involves changes in the angle between two layers of 2D material. However, in such multi-layers if strain is applied to only one layers, which is called heterostrain, strain can have similar effect as twist in changing electronic properties. It is also distinct from, but similar to, the piezoelectric effects which are created by bending, twisting, or squeezing of certain material.
Aron Pinczuk was an Argentine-American experimental condensed matter physicist who was professor of physics and professor of applied physics at Columbia University. He was known for his work on correlated electronic states in two dimensional systems using photoluminescence and resonant inelastic light scattering methods. He was a fellow of the American Physical Society, the American Association for the Advancement of Science and the American Academy of Arts and Sciences.
A Josephson diode is an electronic device that superconducts electrical current in one direction and is resistive in the other direction. The device is a Josephson junction exhibiting a superconducting diode effect (SDE). It is an example of a quantum material Josephson junction (QMJJ), where the weak link in the junction is a quantum material. The Josephson diode effect can occur in superconducting devices where time reversal symmetry and inversion symmetry are broken.