Ion plating

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Ion plating rig
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Ion plated fasteners

Ion plating (IP) is a physical vapor deposition (PVD) process that is sometimes called ion assisted deposition (IAD) or ion vapor deposition (IVD) and is a modified version of vacuum deposition . Ion plating uses concurrent or periodic bombardment of the substrate, and deposits film by atomic-sized energetic particles called ions. Bombardment prior to deposition is used to sputter clean the substrate surface. During deposition the bombardment is used to modify and control the properties of the depositing film. It is important that the bombardment be continuous between the cleaning and the deposition portions of the process to maintain an atomically clean interface. If this interface is not properly cleaned, then it can result into a weaker coating or poor adhesion.

Contents

They are many different processes to vacuum deposited coatings in which they are used for various applications such as corrosion resistance and wear on the material. [1]

Process

In ion plating, the energy, flux and mass of the bombarding species along with the ratio of bombarding particles to depositing particles are important processing variables. The depositing material may be vaporized either by evaporation, sputtering (bias sputtering), arc vaporization or by decomposition of a chemical vapor precursor chemical vapor deposition (CVD). The energetic particles used for bombardment are usually ions of an inert or reactive gas, or, in some cases, ions of the condensing film material ("film ions"). Ion plating can be done in a plasma environment where ions for bombardment are extracted from the plasma or it may be done in a vacuum environment where ions for bombardment are formed in a separate ion gun. The latter ion plating configuration is often called Ion Beam Assisted Deposition (IBAD). By using a reactive gas or vapor in the plasma, films of compound materials can be deposited.

Ion plating is used to deposit hard coatings of compound materials on tools, adherent metal coatings, optical coatings with high densities, and conformal coatings on complex surfaces.

Pros

Cons

Background information on ion plating

The ion plating process was first described in the technical literature by Donald M. Mattox of Sandia National Laboratories in 1964. [3] As described by this article, it was used initially to enhance film adhesion and improve surface coverage. [4]

History

This process was first used in the 1960's and was continued throughout the time by using specific cleaning techniques and film growth reactive and quasi reactive deposition techniques. Sputter cleaning has been used since the 1950's for cleaning scientific surfaces. In the 1970's, high-rate DC magnetron sputtering has shown that bombardment densified the films and helped the hardness of materials. As we further progressed, we learned in 1983 that bombardment was used as concurrent bombardment of inserted gas ions. [4]

See also

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Sputter deposition is a physical vapor deposition (PVD) method of thin film deposition by the phenomenon of sputtering. This involves ejecting material from a "target" that is a source onto a "substrate" such as a silicon wafer. Resputtering is re-emission of the deposited material during the deposition process by ion or atom bombardment. Sputtered atoms ejected from the target have a wide energy distribution, typically up to tens of eV. The sputtered ions can ballistically fly from the target in straight lines and impact energetically on the substrates or vacuum chamber. Alternatively, at higher gas pressures, the ions collide with the gas atoms that act as a moderator and move diffusively, reaching the substrates or vacuum chamber wall and condensing after undergoing a random walk. The entire range from high-energy ballistic impact to low-energy thermalized motion is accessible by changing the background gas pressure. The sputtering gas is often an inert gas such as argon. For efficient momentum transfer, the atomic weight of the sputtering gas should be close to the atomic weight of the target, so for sputtering light elements neon is preferable, while for heavy elements krypton or xenon are used. Reactive gases can also be used to sputter compounds. The compound can be formed on the target surface, in-flight or on the substrate depending on the process parameters. The availability of many parameters that control sputter deposition make it a complex process, but also allow experts a large degree of control over the growth and microstructure of the film.

Substrate is a term used in materials science and engineering to describe the base material on which processing is conducted. Surfaces have different uses, including producing new film or layers of material and being a base to which another substance is bonded.

High-power impulse magnetron sputtering is a method for physical vapor deposition of thin films which is based on magnetron sputter deposition. HIPIMS utilises extremely high power densities of the order of kW⋅cm−2 in short pulses (impulses) of tens of microseconds at low duty cycle of < 10%. Distinguishing features of HIPIMS are a high degree of ionisation of the sputtered metal and a high rate of molecular gas dissociation which result in high density of deposited films. The ionization and dissociation degree increase according to the peak cathode power. The limit is determined by the transition of the discharge from glow to arc phase. The peak power and the duty cycle are selected so as to maintain an average cathode power similar to conventional sputtering (1–10 W⋅cm−2).

The Society of Vacuum Coaters (SVC) is a non-profit, international, professional organisation for individuals who are involved in depositing films and coatings in vacuum or rarefied environments for surface engineering purposes.

References

  1. 1 2 3 4 5 6 7 8 9 10 Lampert, Dr. Carl (3 January 2013). "Vacuum Deposition and Coating Options". pfonline.com. Gardner Business Media. Archived from the original on 16 July 2017. Retrieved 10 October 2019. Ion plating uses energetic ion bombardment during deposition to densify the deposit and control properties of the coating such as stress and microstructure.
  2. "ION PLATED JEWELRY: WHAT IS IT AND HOW IS IT APPLIED?". Shop LC. 13 November 2017.
  3. Mattox, Donald M. (1 September 1964). "Film Deposition Using Accelerated Ions". Electrochemical Technology. 2. Sandia National Laboratories. OCLC   571781676. OSTI   4672659.
  4. 1 2 Mattox, Donald M. (30 November 2000). "Ion plating — past, present and future". Surface and Coatings Technology. 133–134: 517–521.

Further reading