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Deuterium (or hydrogen-2, symbol 2
H
or D, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other being protium, or hydrogen-1). The nucleus of a deuterium atom, called a deuteron, contains one proton and one neutron, whereas the far more common protium has no neutrons in the nucleus. Deuterium has a natural abundance in Earth's oceans of about one atom of deuterium among every 6,420 atoms of hydrogen (see heavy water). Thus deuterium accounts for approximately 0.0156% by number (0.0312% by mass) of all the naturally occurring hydrogen in the oceans (i.e., 4.85×1013 tonnes of deuterium – mainly in form of HOD and only rarely in form of D2O – in 1.4×1018 tonnes of water), while protium accounts for 99.98%. The abundance of deuterium changes slightly from one kind of natural water to another (see Vienna Standard Mean Ocean Water)
Heavy water is a form of water whose hydrogen atoms are all deuterium rather than the common hydrogen-1 isotope that makes up most of the hydrogen in normal water. The presence of the heavier hydrogen isotope gives the water different nuclear properties, and the increase in mass gives it slightly different physical and chemical properties when compared to normal water.
The Manhattan Project was a program of research and development undertaken during World War II to produce the first nuclear weapons. It was led by the United States in collaboration with the United Kingdom and with support from Canada. From 1942 to 1946, the project was under the direction of Major General Leslie Groves of the U.S. Army Corps of Engineers. Nuclear physicist J. Robert Oppenheimer was the director of the Los Alamos Laboratory that designed the bombs. The Army program was designated the Manhattan District, as its first headquarters were in Manhattan; the name gradually superseded the official codename, Development of Substitute Materials, for the entire project. The project absorbed its earlier British counterpart, Tube Alloys. The Manhattan Project employed nearly 130,000 people at its peak and cost nearly US$2 billion, over 80 percent of which was for building and operating the plants that produced the fissile material. Research and production took place at more than 30 sites across the US, the UK, and Canada.
Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slow to react with air under standard conditions because a passivation layer of nickel oxide forms on the surface that prevents further corrosion. Even so, pure native nickel is found in Earth's crust only in tiny amounts, usually in ultramafic rocks, and in the interiors of larger nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere.
Sulfur (also spelled sulphur in British English) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with the chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature.
Isotope separation is the process of concentrating specific isotopes of a chemical element by removing other isotopes. The use of the nuclides produced is varied. The largest variety is used in research. By tonnage, separating natural uranium into enriched uranium and depleted uranium is the largest application. In the following text, mainly uranium enrichment is considered. This process is crucial in the manufacture of uranium fuel for nuclear power plants, and is also required for the creation of uranium-based nuclear weapons. Plutonium-based weapons use plutonium produced in a nuclear reactor, which must be operated in such a way as to produce plutonium already of suitable isotopic mix or grade.
Hydrogen sulfide is a chemical compound with the formula H2S. It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777.
NRX was a heavy-water-moderated, light-water-cooled, nuclear research reactor at the Canadian Chalk River Laboratories, which came into operation in 1947 at a design power rating of 10 MW (thermal), increasing to 42 MW by 1954. At the time of its construction, it was Canada's most expensive science facility and the world's most powerful nuclear research reactor. NRX was remarkable both in terms of its heat output and the number of free neutrons it generated. When a nuclear reactor such as NRX is operating, its nuclear chain reaction generates many free neutrons. In the late 1940s, NRX was the most intense neutron source in the world.
The Girdler sulfide (GS) process, also known as the Geib–Spevack (GS) process, is an industrial production method for filtering out of natural water the heavy water (deuterium oxide = D2O) which is used in particle research, in deuterium NMR spectroscopy, deuterated solvents for proton NMR spectroscopy, in heavy water nuclear reactors (as a coolant and moderator) and in deuterated drugs.
Tube Alloys was the research and development programme authorised by the United Kingdom, with participation from Canada, to develop nuclear weapons during the Second World War. Starting before the Manhattan Project in the United States, the British efforts were kept classified, and as such had to be referred to by code even within the highest circles of government.
The Quebec Agreement was a secret agreement between the United Kingdom and the United States outlining the terms for the coordinated development of the science and engineering related to nuclear energy and specifically nuclear weapons. It was signed by Winston Churchill and Franklin D. Roosevelt on 19 August 1943, during World War II, at the First Quebec Conference in Quebec City, Quebec, Canada.
The Metallurgical Laboratory was a scientific laboratory at the University of Chicago that was established in February 1942 to study and use the newly discovered chemical element plutonium. It researched plutonium's chemistry and metallurgy, designed the world's first nuclear reactors to produce it, and developed chemical processes to separate it from other elements. In August 1942 the lab's chemical section was the first to chemically separate a weighable sample of plutonium, and on 2 December 1942, the Met Lab produced the first controlled nuclear chain reaction, in the reactor Chicago Pile-1, which was constructed under the stands of the university's old football stadium, Stagg Field.
In organic chemistry, thioketones are organosulfur compounds related to conventional ketones in which the oxygen has been replaced by a sulfur. Instead of a structure of R2C=O, thioketones have the structure R2C=S, which is reflected by the prefix "thio-" in the name of the functional group. Thus the simplest thioketone is thioacetone, the sulfur analog of acetone. Unhindered alkylthioketones typically tend to form polymers or rings.
The X-10 Graphite Reactor is a decommissioned nuclear reactor at Oak Ridge National Laboratory in Oak Ridge, Tennessee. Formerly known as the Clinton Pile and X-10 Pile, it was the world's second artificial nuclear reactor, and the first designed and built for continuous operation. It was built during World War II as part of the Manhattan Project.
The Montreal Laboratory was a program established by the National Research Council of Canada during World War II to undertake nuclear research in collaboration with the United Kingdom, and to absorb some of the scientists and work of the Tube Alloys nuclear project in Britain. It became part of the Manhattan Project, and designed and built some of the world's first nuclear reactors.
Operation LAC was a United States Army Chemical Corps operation which dispersed microscopic zinc cadmium sulfide (ZnCdS) particles over much of the United States and Canada in order to test dispersal patterns and the geographic range of chemical or biological weapons.
Karl-Hermann Geib was a German physical chemist who, in 1943, developed the "dual temperature exchange sulphide process" which is regarded as the "most cost-effective process for producing heavy water". A parallel development of this process was achieved by Jerome S. Spevack at Columbia University and became the basis of post-World War II production of heavy water in the United States at the only remaining facilities located at Wabash River Ordnance Works, near Dana and Newport, Indiana, and the Savannah River Site.
Britain initiated the first research project to design an atomic bomb in 1941. Building on this work, Britain prompted the United States to recognise how important this type of research was, helped the U.S. to start the Manhattan Project in 1942, and supplied crucial expertise and materials that contributed to the project's successful completion in time to influence the end of the Second World War.
The P-9 Project was the codename given during World War II to the Manhattan Project's heavy water production program. The Cominco operation at Trail, British Columbia, was upgraded to produce heavy water. DuPont built three plants in the United States: at the Morgantown Ordnance Works, near Morgantown, West Virginia; at the Wabash River Ordnance Works, near Dana and Newport, Indiana; and at the Alabama Ordnance Works, near Childersburg and Sylacauga, Alabama. The American plants operated from 1943 until 1945. The Canadian plant at Trail continued in operation until 1956. Three nuclear reactors were built using the heavy water produced by the P-9 Project: Chicago Pile 3 at Argonne, and ZEEP and NRX at the Chalk River Laboratories in Canada.
Heavy metals are generally defined as metals with relatively high densities, atomic weights, or atomic numbers. The criteria used, and whether metalloids are included, vary depending on the author and context. In metallurgy, for example, a heavy metal may be defined on the basis of density, whereas in physics the distinguishing criterion might be atomic number, while a chemist would likely be more concerned with chemical behaviour. More specific definitions have been published, none of which have been widely accepted. The definitions surveyed in this article encompass up to 96 out of the 118 known chemical elements; only mercury, lead and bismuth meet all of them. Despite this lack of agreement, the term is widely used in science. A density of more than 5 g/cm3 is sometimes quoted as a commonly used criterion and is used in the body of this article.
References
- ↑ "Mrs Jerome Spevack: Wife of Inventor". The Standard-Star . July 20, 1973. p. 2.
- ↑ U.S. patent 2,787,526 , Jerome S Spevack, filed 11 November, 1943
- ↑ Castell, Lutz (2003). Time, Quantum and Information. Google Books: Springer Science+Business Media. p. 37. ISBN 978-3-642-07892-7.
- ↑ Canada Enters the Nuclear Age: A Technical History of Atomic Energy. Google Books: Atomic Energy of Canada Limited. 1977. p. 337. ISBN 978-0-7735-1601-4.
- ↑ "Spevack wins suits over heavy water". American Chemical Society . Vol. 52, no. 30. American Chemical Society. July 29, 1974. p. 17. doi:10.1021/cen-v052n030.p017.
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