Kondo insulator

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Dispersion relation of conduction band and localized states. Unhybridized.png
Dispersion relation of conduction band and localized states.
Hybridization and forming of an indirect energy (hybridization) gap due to the coherent Kondo screening of the local moments by the sea of conduction electrons. Hybridization.png
Hybridization and forming of an indirect energy (hybridization) gap due to the coherent Kondo screening of the local moments by the sea of conduction electrons.
In case of Kondo insulators the Fermi level (chemical potential) is located in the hybridization gap. Kondo insulator.png
In case of Kondo insulators the Fermi level (chemical potential) is located in the hybridization gap.

In solid-state physics, Kondo insulators (also referred as Kondo semiconductors and heavy fermion semiconductors) are understood as materials with strongly correlated electrons, that open up a narrow band gap (in the order of 10 meV) at low temperatures with the chemical potential lying in the gap, whereas in heavy fermion materials the chemical potential is located in the conduction band.

Contents

The band gap opens up at low temperatures due to hybridization of localized electrons (mostly f-electrons) with conduction electrons, a correlation effect known as the Kondo effect. As a consequence, a transition from metallic behavior to insulating behavior is seen in resistivity measurements. The band gap could be either direct or indirect. Most studied Kondo insulators are FeSi, Ce3Bi4Pt3, SmB6, YbB12, and CeNiSn, although As of 2016 there are over a dozen known Kondo insulators. [1]

Historical overview

In 1969, Menth et al. found no magnetic ordering in SmB6 down to 0.35 K and a change from metallic to insulating behavior in the resistivity measurement with decreasing temperature. They interpreted this phenomenon as a change of the electronic configuration of Sm. [2]

In 1992, Gabriel Aeppli and Zachary Fisk found a descriptive way to explain the physical properties of Ce3Bi4Pt3 and CeNiSn. They called the materials Kondo insulators, showing Kondo lattice behavior near room temperature, but becoming semiconducting with very small energy gaps (a few Kelvin to a few tens of Kelvin) when decreasing the temperature. [3]

Transport properties

At high temperatures the localized f-electrons form independent local magnetic moments. According to the Kondo effect, the dc-resistivity of Kondo insulators shows a logarithmic temperature-dependence. At low temperatures, the local magnetic moments are screened by the sea of conduction electrons, forming a so-called Kondo resonance. The interaction of the conduction band with the f-orbitals results in a hybridization and an energy gap . If the chemical potential lies in the hybridization gap, an insulating behavior can be seen in the dc-resistivity at low temperatures.

In recent times, angle-resolved photoemission spectroscopy experiments provided direct imaging of band-structure, hybridization and flat band topology in Kondo insulators and related compounds. [4]

Related Research Articles

<span class="mw-page-title-main">Condensed matter physics</span> Branch of physics

Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases, that arise from electromagnetic forces between atoms and electrons. More generally, the subject deals with condensed phases of matter: systems of many constituents with strong interactions among them. More exotic condensed phases include the superconducting phase exhibited by certain materials at extremely low cryogenic temperatures, the ferromagnetic and antiferromagnetic phases of spins on crystal lattices of atoms, the Bose–Einstein condensates found in ultracold atomic systems, and liquid crystals. Condensed matter physicists seek to understand the behavior of these phases by experiments to measure various material properties, and by applying the physical laws of quantum mechanics, electromagnetism, statistical mechanics, and other physics theories to develop mathematical models and predict the properties of extremely large groups of atoms.

A semiconductor is a material that has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity generally falls as its temperature rises; metals behave in the opposite way. In many cases their conducting properties may be altered in useful ways by introducing impurities ("doping") into the crystal structure. When two differently doped regions exist in the same crystal, a semiconductor junction is created. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called "metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical element for fabricating most electronic circuits.

<span class="mw-page-title-main">Kondo effect</span> Physical phenomenon due to impurities

In physics, the Kondo effect describes the scattering of conduction electrons in a metal due to magnetic impurities, resulting in a characteristic change i.e. a minimum in electrical resistivity with temperature. The cause of the effect was first explained by Jun Kondo, who applied third-order perturbation theory to the problem to account for scattering of s-orbital conduction electrons off d-orbital electrons localized at impurities. Kondo's calculation predicted that the scattering rate and the resulting part of the resistivity should increase logarithmically as the temperature approaches 0 K. Extended to a lattice of magnetic impurities, the Kondo effect likely explains the formation of heavy fermions and Kondo insulators in intermetallic compounds, especially those involving rare earth elements such as cerium, praseodymium, and ytterbium, and actinide elements such as uranium. The Kondo effect has also been observed in quantum dot systems.

<span class="mw-page-title-main">Semimetal</span> Metal with a small negative indirect band-gap

A semimetal is a material with a small energy overlap between the bottom of the conduction band and the top of the valence band, but they do not overlap in momentum space. According to electronic band theory, solids can be classified as insulators, semiconductors, semimetals, or metals. In insulators and semiconductors the filled valence band is separated from an empty conduction band by a band gap. For insulators, the magnitude of the band gap is larger than that of a semiconductor. Because of the slight overlap between the conduction and valence bands, semimetals have no band gap and a small density of states at the Fermi level. A metal, by contrast, has an appreciable density of states at the Fermi level because the conduction band is partially filled.

<span class="mw-page-title-main">Hubbard model</span> Approximate model used to describe the transition between conducting and insulating systems

The Hubbard model is an approximate model used to describe the transition between conducting and insulating systems. It is particularly useful in solid-state physics. The model is named for John Hubbard.

<span class="mw-page-title-main">Mott insulator</span> Materials classically predicted to be conductors, that are actually insulators

Mott insulators are a class of materials that are expected to conduct electricity according to conventional band theories, but turn out to be insulators. These insulators fail to be correctly described by band theories of solids due to their strong electron–electron interactions, which are not considered in conventional band theory. A Mott transition is a transition from a metal to an insulator, driven by the strong interactions between electrons. One of the simplest models that can capture Mott transition is the Hubbard model.

In materials science, heavy fermion materials are a specific type of intermetallic compound, containing elements with 4f or 5f electrons in unfilled electron bands. Electrons are one type of fermion, and when they are found in such materials, they are sometimes referred to as heavy electrons. Heavy fermion materials have a low-temperature specific heat whose linear term is up to 1000 times larger than the value expected from the free electron model. The properties of the heavy fermion compounds often derive from the partly filled f-orbitals of rare-earth or actinide ions, which behave like localized magnetic moments.

<span class="mw-page-title-main">Mesoscopic physics</span> Subdiscipline of condensed matter physics that deals with materials of an intermediate size

Mesoscopic physics is a subdiscipline of condensed matter physics that deals with materials of an intermediate size. These materials range in size between the nanoscale for a quantity of atoms and of materials measuring micrometres. The lower limit can also be defined as being the size of individual atoms. At the microscopic scale are bulk materials. Both mesoscopic and macroscopic objects contain many atoms. Whereas average properties derived from constituent materials describe macroscopic objects, as they usually obey the laws of classical mechanics, a mesoscopic object, by contrast, is affected by thermal fluctuations around the average, and its electronic behavior may require modeling at the level of quantum mechanics.

The quantum spin Hall state is a state of matter proposed to exist in special, two-dimensional semiconductors that have a quantized spin-Hall conductance and a vanishing charge-Hall conductance. The quantum spin Hall state of matter is the cousin of the integer quantum Hall state, and that does not require the application of a large magnetic field. The quantum spin Hall state does not break charge conservation symmetry and spin- conservation symmetry.

<span class="mw-page-title-main">Topological insulator</span> State of matter with insulating bulk but conductive boundary

A topological insulator is a material whose interior behaves as an electrical insulator while its surface behaves as an electrical conductor, meaning that electrons can only move along the surface of the material.

Samarium monochalcogenides are chemical compounds with the composition SmX, where Sm stands for the lanthanide element samarium and X denotes any one of three chalcogen elements, sulfur, selenium or tellurium, resulting in the compounds SmS, SmSe or SmTe. In these compounds, samarium formally exhibits oxidation state +2, whereas it usually assumes the +3 state, resulting in chalcogenides with the chemical formula Sm2X3.

<span class="mw-page-title-main">Piers Coleman</span> British-American physicist

Piers Coleman is a British-born theoretical physicist, working in the field of theoretical condensed matter physics. Coleman is professor of physics at Rutgers University in New Jersey and at Royal Holloway, University of London.

Heavy fermion superconductors are a type of unconventional superconductor.

<span class="mw-page-title-main">Samarium hexaboride</span> Chemical compound

Samarium hexaboride (SmB6) is an intermediate-valence compound where samarium is present both as Sm2+ and Sm3+ ions at the ratio 3:7. It is a Kondo insulator having a metallic surface state.

Bismuth antimonides, Bismuth-antimonys, or Bismuth-antimony alloys, (Bi1−xSbx) are binary alloys of bismuth and antimony in various ratios.

YbBiPt is an intermetallic material which at low temperatures exhibits an extremely high value of specific heat, which is a characteristic of heavy-fermion behavior. YbBiPt has a noncentrosymmetric cubic crystal structure; in particular it belongs to the ternary half-Heusler compounds.

Suchitra Sebastian is a condensed matter physicist at Cavendish Laboratory, University of Cambridge. She is known for her discoveries of exotic quantum phenomena that emerge in complex materials. In particular, she is known for the discovery of unconventional insulating materials which display simultaneous conduction-like behaviour. In 2022 she was awarded the New Horizons in Physics Prize by the Breakthrough Foundation. She was named as one of thirty Exceptional Young Scientists by the World Economic Forum in 2013, one of The Next Big Names in Physics by the Financial Times in 2013, and spoke at the World Economic Forum at Davos in 2016.

The term Dirac matter refers to a class of condensed matter systems which can be effectively described by the Dirac equation. Even though the Dirac equation itself was formulated for fermions, the quasi-particles present within Dirac matter can be of any statistics. As a consequence, Dirac matter can be distinguished in fermionic, bosonic or anyonic Dirac matter. Prominent examples of Dirac matter are graphene and other Dirac semimetals, topological insulators, Weyl semimetals, various high-temperature superconductors with -wave pairing and liquid helium-3. The effective theory of such systems is classified by a specific choice of the Dirac mass, the Dirac velocity, the gamma matrices and the space-time curvature. The universal treatment of the class of Dirac matter in terms of an effective theory leads to a common features with respect to the density of states, the heat capacity and impurity scattering.

Samarium compounds are compounds formed by the lanthanide metal samarium (Sm). In these compounds, samarium generally exhibits the +3 oxidation state, such as SmCl3, Sm(NO3)3 and Sm(C2O4)3. Compounds with samarium in the +2 oxidation state are also known, for example SmI2.

References

  1. Dzero, Maxim; Xia, Jing; Galitski, Victor; Coleman, Piers (2016-03-10). "Topological Kondo Insulators". Annual Review of Condensed Matter Physics. 7 (1): 249–280. arXiv: 1506.05635 . Bibcode:2016ARCMP...7..249D. doi:10.1146/annurev-conmatphys-031214-014749. ISSN   1947-5454. S2CID   15794370.
  2. Menth, A.; Buehler, E.; Geballe, T. H. (17 February 1969). "Magnetic and Semiconducting Properties of SmB6". Physical Review Letters. 22 (7). American Physical Society (APS): 295–297. Bibcode:1969PhRvL..22..295M. doi:10.1103/physrevlett.22.295. ISSN   0031-9007.
  3. Kondo Insulators, G. Aeppli, Z. Fisk, 1992, Comments Cond. Mat. Phys. 16, 155-170
  4. Hasan, M. Zahid; Xu, Su-Yang; Neupane, Madhab (2015), "Topological Insulators, Topological Dirac semimetals, Topological Crystalline Insulators, and Topological Kondo Insulators", Topological Insulators, John Wiley & Sons, Ltd, pp. 55–100, doi:10.1002/9783527681594.ch4, ISBN   978-3-527-68159-4