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The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula XY(Si,Al)2O6, where X represents calcium (Ca), sodium (Na), iron or magnesium (Mg) and more rarely zinc, manganese or lithium, and Y represents ions of smaller size, such as chromium (Cr), aluminium (Al), magnesium (Mg), cobalt (Co), manganese (Mn), scandium (Sc), titanium (Ti), vanadium (V) or even iron. Although aluminium substitutes extensively for silicon in silicates such as feldspars and amphiboles, the substitution occurs only to a limited extent in most pyroxenes. They share a common structure consisting of single chains of silica tetrahedra. Pyroxenes that crystallize in the monoclinic system are known as clinopyroxenes and those that crystallize in the orthorhombic system are known as orthopyroxenes.
A chondrule is a round grain found in a chondrite. Chondrules form as molten or partially molten droplets in space before being accreted to their parent asteroids. Because chondrites represent one of the oldest solid materials within the Solar System and are believed to be the building blocks of the planetary system, it follows that an understanding of the formation of chondrules is important to understand the initial development of the planetary system.
A chondrite is a stony (non-metallic) meteorite that has not been modified, by either melting or differentiation of the parent body. They are formed when various types of dust and small grains in the early Solar System accreted to form primitive asteroids. Some such bodies that are captured in the planet's gravity well become the most common type of meteorite by arriving on a trajectory toward the planet's surface. Estimates for their contribution to the total meteorite population vary between 85.7% and 86.2%.
Wollastonite is a calcium inosilicate mineral (CaSiO3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or dolomite is subjected to high temperature and pressure, which sometimes occurs in the presence of silica-bearing fluids as in skarns or in contact with metamorphic rocks. Associated minerals include garnets, vesuvianite, diopside, tremolite, epidote, plagioclase feldspar, pyroxene and calcite. It is named after the English chemist and mineralogist William Hyde Wollaston (1766–1828).
Diallage is an inosilicate, meaning it is a chain silicate, and is a part of the pyroxene group. Diallage is a junction between augite and diopside, just like fassaite. It was named in 1801 by René Just Haüy. Its name derives from the Greek word diallaghé, as its composition differs from that of the other minerals in the pyroxene group. It is a fairly common mineral, and is cheap.
Hedenbergite, CaFeSi2O6, is the iron rich end member of the pyroxene group having a monoclinic crystal system. The mineral is extremely rarely found as a pure substance, and usually has to be synthesized in a lab. It was named in 1819 after M.A. Ludwig Hedenberg, who was the first to define hedenbergite as a mineral. Contact metamorphic rocks high in iron are the primary geologic setting for hedenbergite. This mineral is unique because it can be found in chondrites and skarns (calc–silicate metamorphic rocks). Since it is a member of the pyroxene family, there is a great deal of interest in its importance to general geologic processes.
Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is (Ca,Na)2(Al,Mg,Fe2+)[(Al,Si)SiO7]. Discovered in 1793 near Rome, it has a yellowish, greenish-brown color. The name derives from the Greek words meli (μέλι) "honey" and lithos (λίθους) "stone".The name refers to a group of minerals (melilite group) with chemically similar composition, nearly always minerals in åkermanite-gehlenite series.
The LL chondrites are a group of stony meteorites, the least abundant group of the ordinary chondrites, accounting for about 10–11% of observed ordinary-chondrite falls and 8–9% of all meteorite falls. The ordinary chondrites are thought to have originated from three parent asteroids, with the fragments making up the H chondrite, L chondrite and LL chondrite groups respectively. The composition of the Chelyabinsk meteorite is that of a LL chondrite meteorite. The material makeup of Itokawa, the asteroid visited by the Hayabusa spacecraft which landed on it and brought particles back to Earth also proved to be type LL chondrite.
The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the thermodynamic properties of its assemblage can be applied to solving other solid solution series from a variety of amphibole minerals.
The Allende meteorite is the largest carbonaceous chondrite ever found on Earth. The fireball was witnessed at 01:05 on February 8, 1969, falling over the Mexican state of Chihuahua. After it broke up in the atmosphere, an extensive search for pieces was conducted and over 2 tonnes were recovered. The availability of large quantities of samples of the scientifically important chondrite class has enabled numerous investigations by many scientists; it is often described as "the best-studied meteorite in history." The Allende meteorite has abundant, large calcium–aluminum-rich inclusions (CAI), which are among the oldest objects formed in the Solar System.
Akimotoite is a rare silicate mineral in the ilmenite group of minerals, with the chemical formula (Mg,Fe)SiO3. It is polymorphous with pyroxene and with bridgmanite, a natural silicate perovskite that is the most abundant mineral in Earth's silicate mantle. Akimotoite has a vitreous luster, is colorless, and has a white or colorless streak. It crystallizes in the trigonal crystal system in space group R3. It is the silicon analogue of geikielite (MgTiO3).
Malayaite is a calcium tin silicate mineral with formula CaSnOSiO4. It is a member of the titanite group.
Krotite is a natural mineral composed of calcium, aluminium and oxygen, with the molecular formula CaAl2O4. It is the low-pressure dimorph of CaAl2O4, of which the high-pressure dimorph is named dmitryivanovite.
Dmitryivanovite is a natural mineral composed of calcium, aluminium and oxygen, with the molecular formula CaAl2O4. It was reported in 2009 in a calcium-aluminium-rich inclusion in the carbonaceous chondrite meteorite 470 (NWA470) CH3, which landed in North Africa. The mineral name was chosen to honor Dmitriy A. Ivanov (1962–1986), a geologist, mineralogist, and petrologist who died on a field expedition.
Lodranites are a small group of primitive achondrite meteorites that consists of meteoric iron and silicate minerals. Olivine and pyroxene make up most of the silicate minerals. Like all primitive achondrites lodranites share similarities with chondrites and achondrites.
Bicchulite has an ideal chemical formula of 2CaO•Al2O2•SiO2•H2O, which was formularized from the hydrothermal synthesis of synthetic gehlenite. Also, bicchulite was sighted in the mines of Japan with related minerals. This sodalite-type structured bicchulite has an uncommon ratio of aluminium to silicon, causing difficulties deciphering the structure. Because of bicchulite's structure it has a powdery texture, which leads to complications in obtaining information on the mineral's physical properties. Despite this problem, the color, specific gravity, and crystal size of bicchulite are known. Although bicchulite was only discovered about 40 years ago, technology has been rapidly advancing, allowing more accurate results to be made from experiments done today.
Davisite is an exceedingly rare mineral of the pyroxene group, with formula CaScAlSiO6. It is the scandium-dominant member. It stands for scandium-analogue of other pyroxene-group members, esseneite, grossmanite and kushiroite. Davisite is one of scarce minerals containing essential scandium.
Grossmanite is a very rare mineral of the pyroxene group, with formula CaTi3+AlSiO6. It is the titanium-dominant member. Grossmanite is unique in being a mineral with trivalent titanium, a feature shared with tistarite, Ti2O3. Titanium in minerals is almost exclusively tetravalent. Grossmanite stands for titanium-analogue of davisite, esseneite and kushiroite – other members of the pyroxene group. Both grossmanite and tistarite come from the famous Allende meteorite.
Esseneite is a relative rare mineral of the pyroxene group, with formula CaFeAlSiO6. It is the ferric-iron-dominant member. Esseneite is an iron-analogue of other pyroxene-group members, davisite, grossmanite, and kushiroite. It is a metamorphic mineral forming in pyrometamorphic rocks called paralavas, which are formed due to fusing on sedimentary rocks usually in result of coal fires. Esseneite is found in both natural and anthropogenic coal-fire sites.
Ikuo Kushiro MJA is a Japanese petrologist, known for his research in experimental petrology. His experiments on peridotites contributed significantly to the understanding of the formation of magma under mid-ocean ridges and island arcs.
References
- ↑ Kimura, M., Mikouchi, T., Suzuki, A., Miyahara, M., Ohtani, E., and El Goresy, A., 2009, Kushiroite, CaAlAlSiO6: A new mineral of the pyroxene group from the ALH 85085 CH chondrite, and its genetic significance in refractory inclusions. American Mineralogist 94(10), 1479-1482.
- ↑ "Kushiroite: Kushiroite mineral information and data". Mindat.org. Retrieved 2016-03-02.
- ↑ Okamura, F.P.; Ghose, S.; Ohashi, H. (1974). "Structure and crystal chemistry of calcium Tschermak's pyroxene, CaAlAlSiO6". American Mineralogist. 59: 549–557. Retrieved 30 December 2020.
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