Laser dye

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Close-up of a table-top dye laser using Rhodamine 6G as active medium. Coherent 899 dye laser.jpg
Close-up of a table-top dye laser using Rhodamine 6G as active medium.
Molecular structure of Rhodamine 6G, perhaps the best known laser dye. Rhodamine 6G.svg
Molecular structure of Rhodamine 6G, perhaps the best known laser dye.

A Laser dye is a dye used as laser medium in a dye laser. [1] [2]

Contents

Laser dyes include the coumarins and the rhodamines. Coumarin dyes emit in the green region of the spectrum, whereas rhodamine dyes are used for emission in the yellow-red. The color emitted by the laser dyes depend upon the surrounding medium i.e.the medium in which they are dissolved. However, there are dozens of laser dyes that can be used to span continuously the emission spectrum from the near ultraviolet to the near infrared. [3] [4]

Laser dyes are also used to dope solid-state matrices, such as poly(methyl methacrylate) (PMMA), and ORMOSILs, to provide gain media for solid state dye lasers. [3]

Examples

See also

Related Research Articles

<span class="mw-page-title-main">Laser</span> Device which emits light via optical amplification

A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word laser is an anacronym that originated as an acronym for light amplification by stimulated emission of radiation. The first laser was built in 1960 by Theodore Maiman at Hughes Research Laboratories, based on theoretical work by Charles H. Townes and Arthur Leonard Schawlow.

<span class="mw-page-title-main">Laser construction</span>

A laser is constructed from three principal parts:

<span class="mw-page-title-main">Dye laser</span> Equipment using an organic dye to emit coherent light

A dye laser is a laser that uses an organic dye as the lasing medium, usually as a liquid solution. Compared to gases and most solid state lasing media, a dye can usually be used for a much wider range of wavelengths, often spanning 50 to 100 nanometers or more. The wide bandwidth makes them particularly suitable for tunable lasers and pulsed lasers. The dye rhodamine 6G, for example, can be tuned from 635 nm (orangish-red) to 560 nm (greenish-yellow), and produce pulses as short as 16 femtoseconds. Moreover, the dye can be replaced by another type in order to generate an even broader range of wavelengths with the same laser, from the near-infrared to the near-ultraviolet, although this usually requires replacing other optical components in the laser as well, such as dielectric mirrors or pump lasers.

<span class="mw-page-title-main">Fluorophore</span> Agents that emit light after excitation by light

A fluorophore is a fluorescent chemical compound that can re-emit light upon light excitation. Fluorophores typically contain several combined aromatic groups, or planar or cyclic molecules with several π bonds.

<span class="mw-page-title-main">Excimer laser</span> Type of ultraviolet laser important in chip manufacturing and eye surgery

An excimer laser, sometimes more correctly called an exciplex laser, is a form of ultraviolet laser which is commonly used in the production of microelectronic devices, semiconductor based integrated circuits or "chips", eye surgery, and micromachining. Since 1960s excimer lasers are widely used in high-resolution photolithography machines, one of the critical technologies required for microelectronic chip manufacturing.

<span class="mw-page-title-main">Rhodamine</span> Family of derivatives of xanthene used as dyes, indicators and fluorescent tracers

Rhodamine is a family of related dyes, a subset of the triarylmethane dyes. They are derivatives of xanthene. Important members of the rhodamine family are Rhodamine 6G, Rhodamine 123, and Rhodamine B. They are mainly used to dye paper and inks, but they lack the lightfastness for fabric dyeing.

<span class="mw-page-title-main">Gas laser</span> Laser in which electricity is discharged through gas

A gas laser is a laser in which an electric current is discharged through a gas to produce coherent light. The gas laser was the first continuous-light laser and the first laser to operate on the principle of converting electrical energy to a laser light output. The first gas laser, the Helium–neon laser (HeNe), was co-invented by Iranian engineer and scientist Ali Javan and American physicist William R. Bennett, Jr., in 1960. It produced a coherent light beam in the infrared region of the spectrum at 1.15 micrometres.

<span class="mw-page-title-main">Tunable laser</span>

A tunable laser is a laser whose wavelength of operation can be altered in a controlled manner. While all laser gain media allow small shifts in output wavelength, only a few types of lasers allow continuous tuning over a significant wavelength range.

<span class="mw-page-title-main">Ion laser</span> Type of gas laser

An ion laser is a gas laser that uses an ionized gas as its lasing medium. Like other gas lasers, ion lasers feature a sealed cavity containing the laser medium and mirrors forming a Fabry–Pérot resonator. Unlike helium–neon lasers, the energy level transitions that contribute to laser action come from ions. Because of the large amount of energy required to excite the ionic transitions used in ion lasers, the required current is much greater, and as a result almost all except for the smallest ion lasers are water-cooled. A small air-cooled ion laser might produce, for example, 130 milliwatts of output light with a tube current of about 10 amperes and a voltage of 105 volts. Since one ampere times one volt is one watt, this is an electrical power input of about one kilowatt. Subtracting the (desirable) light output of 130 mW from power input, this leaves the large amount of waste heat of nearly one kW. This has to be dissipated by the cooling system. In other words, the power efficiency is very low.

<span class="mw-page-title-main">Rhodamine 6G</span> Chemical compound

Rhodamine 6G is a highly fluorescent rhodamine family dye. It is often used as a tracer dye within water to determine the rate and direction of flow and transport. Rhodamine dyes fluoresce and can thus be detected easily and inexpensively with instruments called fluorometers. Rhodamine dyes are used extensively in biotechnology applications such as fluorescence microscopy, flow cytometry, fluorescence correlation spectroscopy and ELISA.

<span class="mw-page-title-main">Laser pumping</span> Powering mechanism for lasers

Laser pumping is the act of energy transfer from an external source into the gain medium of a laser. The energy is absorbed in the medium, producing excited states in its atoms. When for a period of time the number of particles in one excited state exceeds the number of particles in the ground state or a less-excited state, population inversion is achieved. In this condition, the mechanism of stimulated emission can take place and the medium can act as a laser or an optical amplifier. The pump power must be higher than the lasing threshold of the laser.

Amplified spontaneous emission (ASE) or superluminescence is light, produced by spontaneous emission, that has been optically amplified by the process of stimulated emission in a gain medium. It is inherent in the field of random lasers.

The DyLight Fluor family of fluorescent dyes are produced by Dyomics in collaboration with Thermo Fisher Scientific. DyLight dyes are typically used in biotechnology and research applications as biomolecule, cell and tissue labels for fluorescence microscopy, cell biology or molecular biology.

<span class="mw-page-title-main">F. J. Duarte</span>

Francisco Javier "Frank" Duarte is a laser physicist and author/editor of several books on tunable lasers.

<span class="mw-page-title-main">Solid-state dye laser</span>

A solid-state dye laser (SSDL) is a solid-state lasers in which the gain medium is a laser dye-doped organic matrix such as poly(methyl methacrylate) (PMMA), rather than a liquid solution of the dye. These lasers are also referred to as solid-state organic lasers and solid-state dye-doped polymer lasers.

<span class="mw-page-title-main">Multiple-prism grating laser oscillator</span>

Multiple-prism grating laser oscillators, or MPG laser oscillators, use multiple-prism beam expansion to illuminate a diffraction grating mounted either in Littrow configuration or grazing-incidence configuration. Originally, these narrow-linewidth tunable dispersive oscillators were introduced as multiple-prism Littrow (MPL) grating oscillators, or hybrid multiple-prism near-grazing-incidence (HMPGI) grating cavities, in organic dye lasers. However, these designs were quickly adopted for other types of lasers such as gas lasers, diode lasers, and more recently fiber lasers.

<span class="mw-page-title-main">Organic laser</span> Laser that uses a carbon-based material as the gain medium

An organic laser is a laser which uses an organic material as the gain medium. The first organic laser was the liquid dye laser. These lasers use laser dye solutions as their gain media.

<span class="mw-page-title-main">Organic photonics</span>

Organic photonics includes the generation, emission, transmission, modulation, signal processing, switching, amplification, and detection/sensing of light, using organic optical materials.

<span class="mw-page-title-main">Coumarin derivatives</span>

Coumarin derivatives are derivatives of coumarin and are considered phenylpropanoids. Among the most important derivatives are the 4-hydroxycoumarins, which exhibit anticoagulant properties, a characteristic not present for coumarin itself.

References

  1. F. P. Schäfer (Ed.), Dye Lasers, 3rd Ed. (Springer-Verlag, Berlin, 1990).
  2. F. J. Duarte and L. W. Hillman (Eds.), Dye Laser Principles (Academic, New York, 1990).
  3. 1 2 3 F. J. Duarte, Tunable Laser Optics (Elsevier-Academic, New York, 2003) Appendix of Laser Dyes (includes more than 50 laser dyes)
  4. A. J. C. Kuehne and M. C. Gather, Organic Lasers: Recent Developments on Materials, Device Geometries, and Fabrication Techniques, Chem. Rev.116, 12823-12864 (2016).
  5. S. C. Guggenheimer, A. B. Petersen. High Power Operation of a CW Ultraviolet Dye Laser. "Prior to 1988, only one laser dye, polyphenyl 1, had been shown to operate CW at wavelengths less than 400 nm."