Lautenthalite

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Lautenthalite
Lautenthalite LL26.jpg
General
Category Minerals
Formula PbCu4(SO4)2(OH)6 · 3H2O
IMA symbol Lth [1]
Strunz classification 07.DE.70
Dana classification 31.06.01.02
Crystal system Monoclinic
Crystal class Prismatic
H-M symbol: (2/m)
Space group P21/b
Unit cell 2,799.47
Identification
ColorBlue green, green, greenish blue
Twinning Polysynthetic on {100}
Cleavage Good on {001} and {010}, distinct
Mohs scale hardness2.5
Luster Vitreous
Streak White
Diaphaneity Transparent
Specific gravity 3.84
Density 3.84
Optical propertiesBiaxial (−)
Refractive index nα = 1.659(2)
nβ = 1.703(2)
nγ = 1.732(2)
Birefringence 0.073
Pleochroism Weak
2V angle 78° – 79°
Dispersion Strong, r < v

Lautenthalite is a mineral that was named after its location, Lautenthal, Harz mountains, Germany. It can be found in several slag localities. It was approved by the IMA in 1993. It is a member of the devilline group, and it is the lead analogue of devilline and campigliaite. Without analytical methods, it is hard to distinguish the mineral from both. It shows pleochroic properties, which is an optical phenomenon. Depending on which angle the mineral is inspected, the color of it differs. On the x optical axis, the mineral could be seen in a pale blue color; on the y and z axis, the mineral's color changes to blue. It has tabular crystals and sheaflike or irregular aggregates. [2] Lautenthalite is associated with wroewolfeite, which it tends to overgrow. It is also associated with anglesite, devilline–serpierite, galena, linarite, brochantite and schulenbergite. [3] It forms small singular crystals with a size of up to 0.5 × 0.3 × 0.03 mm. [4]

Chemical properties

Lautenthalite forms during the oxidation of copper, lead and zinc sulphides. [3] It mostly consists of oxygen (33.60%), copper (31.40%) and lead (25.59%), but also contains sulfur (7.92%) and hydrogen (1.49%). [5]

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Lautenthalite". www.mindat.org. Retrieved 2021-08-08.
  3. 1 2 "Mineral Database". National Museum Wales. Retrieved 2021-08-08.
  4. Medenbach, O.; Gebert, W. (1993). "Lautenthalite, PbCu4[(OH)6/(SO4)2].3H2O, the Pb analogue of devillite. A new mineral from the Harz mountains, Germany". Neues Jahrbuch für Mineralogie - Monatshefte: 401–407. S2CID   99443180.
  5. "Lautenthalite Mineral Data". webmineral.com. Retrieved 2021-08-08.