Lautenthalite | |
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General | |
Category | Mineral |
Formula (repeating unit) | PbCu4(SO4)2(OH)6 · 3H2O |
IMA symbol | Lth [1] |
Strunz classification | 07.DE.70 |
Dana classification | 31.06.01.02 |
Crystal system | Monoclinic |
Crystal class | Prismatic H-M symbol: (2/m) |
Space group | P21/b |
Unit cell | 2,799.47 |
Identification | |
Color | Blue green, green, greenish blue |
Twinning | Polysynthetic on {100} |
Cleavage | Good on {001} and {010}, distinct |
Mohs scale hardness | 2.5 |
Luster | Vitreous |
Streak | White |
Diaphaneity | Transparent |
Specific gravity | 3.84 |
Density | 3.84 |
Optical properties | Biaxial (−) |
Refractive index | nα = 1.659(2) nβ = 1.703(2) nγ = 1.732(2) |
Birefringence | 0.073 |
Pleochroism | Weak |
2V angle | 78° – 79° |
Dispersion | Strong, r < v |
Lautenthalite is a mineral that was named after its location, Lautenthal, Harz mountains, Germany. It can be found in several slag localities. It was approved by the IMA in 1993. It is a member of the devilline group, and it is the lead analogue of devilline and campigliaite. Without analytical methods, it is hard to distinguish the mineral from both. It shows pleochroic properties, which is an optical phenomenon. Depending on which angle the mineral is inspected, the color of it differs. On the x optical axis, the mineral could be seen in a pale blue color; on the y and z axis, the mineral's color changes to blue. It has tabular crystals and sheaflike or irregular aggregates. [2] Lautenthalite is associated with wroewolfeite, which it tends to overgrow. It is also associated with anglesite, devilline–serpierite, galena, linarite, brochantite and schulenbergite. [3] It forms small singular crystals with a size of up to 0.5 × 0.3 × 0.03 mm. [4]
Lautenthalite forms during the oxidation of copper, lead and zinc sulphides. [3] It mostly consists of oxygen (33.60%), copper (31.40%) and lead (25.59%), but also contains sulfur (7.92%) and hydrogen (1.49%). [5]
Bournonite, wheel ore or berthonite (German: antimonbleikupferblende) is a sulfosalt mineral species, trithioantimoniate of lead and copper with the formula PbCuSbS3.
Leadhillite is a lead sulfate carbonate hydroxide mineral, often associated with anglesite. It has the formula Pb4SO4(CO3)2(OH)2. Leadhillite crystallises in the monoclinic system, but develops pseudo-hexagonal forms due to crystal twinning. It forms transparent to translucent variably coloured crystals with an adamantine lustre. It is quite soft with a Mohs hardness of 2.5 and a relatively high specific gravity of 6.26 to 6.55.
Linarite is a somewhat rare, crystalline mineral that is known among mineral collectors for its unusually intense, pure blue color. It is formed by the oxidation of galena and chalcopyrite and other copper sulfides. It is a combined copper lead sulfate hydroxide with formula PbCuSO4(OH)2. Linarite occurs as monoclinic prismatic to tabular crystals and irregular masses. It is easily confused with azurite, but does not react with dilute hydrochloric acid as azurite does. It has a Mohs hardness of 2.5 and a specific gravity of 5.3 – 5.5.
Clausthalite is a lead selenide mineral, PbSe. It forms a solid solution series with galena PbS.
Campigliaite is a copper and manganese sulfate mineral with a chemical formula of Cu4Mn(SO4)2(OH)6·4H2O. It has a chemical formula and also a crystal structure similar to niedermayrite, with Cd(II) cation replacing by Mn(II). The formation of campigliaite is related to the oxidation of sulfide minerals to form sulfate solutions with ilvaite associated with the presence of manganese. Campigliaite is a rare secondary mineral formed when metallic sulfide skarn deposits are oxidized. While there are several related associations, there is no abundant source for this mineral due to its rare process of formation. Based on its crystallographic data and chemical formula, campigliaite is placed in the devillite group and considered the manganese analogue of devillite. Campigliaite belongs to the copper oxysalt minerals as well followed by the subgroup M=M-T sheets. The infinite sheet structures that campigliaite has are characterized by strongly bonded polyhedral sheets, which are linked in the third dimension by weaker hydrogen bonds.
Plancheite is a hydrated copper silicate mineral with the formula Cu8Si8O22(OH)4•(H2O). It is closely related to shattuckite in structure and appearance, and the two minerals are often confused.
Lavendulan is an uncommon copper arsenate mineral, known for its characteristic intense electric blue colour. It belongs to the lavendulan group, which has four members:
Marrite (mar'-ite) is a mineral with the chemical formula PbAgAsS3. It is the arsenic equivalent of freieslebenite (PbAgSbS3), but also displays close polyhedral characteristics with sicherite and diaphorite. Marrite was named in honor of geologist John Edward Marr (1857–1933) of Cambridge, England.
Devilline is a sulfate mineral with the chemical formula CaCu4(SO4)2(OH)6·3H2O. The name originates from the French chemist's name, Henri Etienne Sainte-Claire Deville (1818–1881).
Xilingolite is a lead sulfide mineral with formula Pb3Bi2S6. It has a hardness of 3, a metallic luster, and usually exhibits a lead-grey color. It is a dimorph of lillianite, exhibiting increased Pb-Bi order and decreased symmetry.
Tsumcorite is a rare hydrated lead arsenate mineral that was discovered in 1971, and reported by Geier, Kautz and Muller. It was named after the TSUMeb CORporation mine at Tsumeb, in Namibia, in recognition of the Corporation's support for mineralogical investigations of the orebody at its Mineral Research Laboratory.
Demesmaekerite is a rare uranium selenite mineral with the chemical formula: Pb2Cu5(UO2)2(SeO3)6(OH)6·2H2O.
Diaboleite is a blue-colored mineral with formula Pb2CuCl2(OH)4. It was discovered in England in 1923 and named diaboleite, from the Greek word διά and boleite, meaning "distinct from boleite". The mineral has since been found in a number of countries.
Köttigite is a rare hydrated zinc arsenate which was discovered in 1849 and named by James Dwight Dana in 1850 in honour of Otto Friedrich Köttig (1824–1892), a German chemist from Schneeberg, Saxony, who made the first chemical analysis of the mineral. It has the formula Zn3(AsO4)2·8H2O and it is a dimorph of metaköttigite, which means that the two minerals have the same formula, but a different structure: köttigite is monoclinic and metaköttigite is triclinic. There are several minerals with similar formulae but with other cations in place of the zinc. Iron forms parasymplesite Fe2+3(AsO4)2·8H2O; cobalt forms the distinctively coloured pinkish purple mineral erythrite Co3(AsO4)2·8H2O and nickel forms annabergite Ni3(AsO4)2·8H2O. Köttigite forms series with all three of these minerals and they are all members of the vivianite group.
Serpierite (Ca(Cu,Zn)4(SO4)2(OH)6·3H2O) is a rare, sky-blue coloured hydrated sulfate mineral, often found as a post-mining product. It is a member of the devilline group, which has members aldridgeite (Cd,Ca)(Cu,Zn)4(SO4)2(OH)6·3H2O, campigliaite Cu4Mn2+(SO4)2(OH)6·4H2O, devilline CaCu4(SO4)2(OH)6·3H2O, kobyashevite Cu5(SO4)2(OH)6·4H2O, lautenthalite PbCu4(SO4)2(OH)6·3H2O and an unnamed dimorph of devilline. It is the calcium analogue of aldridgeite and it is dimorphous with orthoserpierite CaCu4(SO4)2(OH)6·3H2O.
Ganophyllite is a phyllosilicate mineral. It was named by Axel Hamberg in 1890 from the Greek words for leaf (φύλλον) and luster (γανωμα); the latter one was chosen due to the lustrous cleavages. The mineral was approved by the IMA in 1959, and it is a grandfathered mineral, meaning its name is still believed to refer to an existing species until this day. Tamaite is the calcium analogue, while eggletonite is the natrium analogue of said mineral.
Hendricksite is a member of the trioctahedral micas group. The mineral was named by Clifford Frondel and Jun Ito in honor of Sterling Brown Hendricks, who studied micas. It was approved in 1966 by the IMA.
Vandenbrandeite is a mineral named after a belgian geologist, Pierre Van den Brande, who discovered an ore deposit. It was named in 1932, and has been a valid mineral ever since then.
Miguelromeroite is a mineral named for Miguel Romero Sanchez by Anthony Robert Kampf. The mineral, first described in 2008 was named in 2009, the same year it got approved by the International Mineralogical Association.
Mawbyite is a lead iron zinc arsenate that was named in honor of Maurice Alan Edgar Mawby. It has been approved by the IMA in 1988, and was published just a year after being described by Pring. Mawbyite is a member of the tsumcorite group, the monoclinic dimorph of carminite. It was first believed to be tsumcorite; however, crystal-structure determination showed iron and zinc occupying the same crystallographic site instead, and through the analysis it turned out mawbyite is isostructural with tsumcorite, meaning the two share a similar formula. More accurately, mawbyite appears to be the ferric analogue of the aforementioned mineral. The relationship between helmutwinklerite – which shares a similar formula with tsumcorite's – and mawbyite had been suggested, but due to lack of data it remains unclear. A full crystal-structure analysis is required in order to understand the relationship between their structures.
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